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In this work we studied the synthesis, dispersion and wet deposition of molybdenum-tungsten hybrid oxide as novel plasmonic electrochromic materials. We successfully synthesized these hybrid materials using a one step solvothermal route. The recovered powders were characterized in terms of their morphology, crystallinity, optic properties, and behavior under annealing conditions. Then, the powders were dispersed in usual low toxic solvents to be used as "electrochromic inks" for the ensuing deposition. The stability of the dispersions was evaluated both qualitativelly and quantitatively, with and without addition of stabilizing agents. The best results were obtained using either a dispersing agent (PEG 140k in ethanol and PEI in water) or in the case of heavily loaded suspensions (150 mg/mL), taking advantage of the interparticle steric hindrace. 10 mg/mL dispersions with PEG in ethanol and 150 mg/mL surfactant-free dispersion in ethanol were used as active "inks" for spin coating and bar casting respectively. We managed to produce active films using both techniques, however, the superior quality of the deposited film using bar casting led to improved electrochromic properties
Plasmonic --- Electrochromic --- Molybdenum-tungsten hybrid oxide --- LSPR --- smart windows --- Physique, chimie, mathématiques & sciences de la terre > Chimie
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This master thesis focuses on thin film solar cells based on Transparent Conductor Oxide (TCO) that are able to generate an electric current while maintaining their transparency to visible light for photovoltaic and UV detectors applications. The studied heterostructure is based on Nickel Oxide (NiO), which is a new interesting material that exhibit an p-type behaviour, and Zinc Oxide (ZnO), a well-known n-type material subjected to many scientific researches in many fields. Moreover, dip-coating deposition technique is used in this master thesis to synthesised the heterojunction. This fabrication process is a soft chemical deposition technique where sol-gel solutions are used as precursors for the deposition. All the depositions are performed on a transparent glass substrate coated by a Fluorine Tin Oxide (FTO) thin film that plays the role of an ohmic back contact. Gold pads are deposited by sputtering on the top of the NiO (p-type side) to form the top contacts. The resulting heterostructure is characterised by different methods and the obtained I-V curves are compared to a simple analytical model.
Photoelectrical --- Photovoltaic --- Solar cell --- TCO --- Sputtering --- PN junction --- Semiconductor --- Transparent oxide --- NiO --- ZnO --- Dip-coating --- Heterojunction --- Analytical model --- Experimental --- FTO --- gas sensor --- Rectifying --- Diode --- J-V curves --- I-V curves --- Ingénierie, informatique & technologie > Multidisciplinaire, généralités & autres --- Physique, chimie, mathématiques & sciences de la terre > Physique
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