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2024 (4)

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Dissertation
Application of synthetic wastewater as substrate for production of extracellular polymeric substances in bioreactors for their use as bio-flocculants
Authors: --- --- ---
Year: 2024 Publisher: Liège Université de Liège (ULiège)

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An effective wastewater treatment not only crucial for the protection of the environment but also for public health. This study proposes innovative methods for producing extracellular polymeric substances, by using synthetic wastewater composed of two different carbon sources, glycerol and volatile fatty acids. Bioreactors were inoculated with mixed microbial cultures using aerobic sludge from wastewater treatment plant and employed to evaluate and compared the production yields, obtained characteristics and their performance as natural flocculants. Previous studies have demonstrated that glycerol produces EPS suitable for bio-flocculation, while volatile fatty acids have not been extensively studied. This thesis aims to address this gap. The obtained results indicate that using synthetic wastewater and mixed microbial cultures can effectively produce EPS suitable for use as natural flocculants. Fresh EPS from the bioreactor fed with volatile fatty acids showed better flocculation performance, while downstream freeze-drying process enhanced the flocculation efficiency of glycerol-derived EPS. Despite achieving the primary objectives, variability in production yields and EPS characteristics overtime was observed and attributed to differences in operational conditions. Overall, this research highlights the potential of using waste streams from biodiesel and pulp industries for sustainable EPS production, contributing to water quality improvement and resource management. While significant progress has been made, further research is needed to optimize EPS production, understand the role of the presence of cations within EPS structure, and expand their applications.


Dissertation
Determining greenhouse gas emissions hotspots and potential abatement strategies: the rice sector in India and the cacao beans sector in Ivory Coast
Authors: --- --- ---
Year: 2024 Publisher: Liège Université de Liège (ULiège)

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The urgency to mitigate greenhouse gas (GHG) emissions, particularly in the agricultural sector, has become paramount in the wake of escalating climate change. This urgency is underscored by the Paris Agreement's ambitious goal of limiting the temperature rise to 1.5°C above pre-industrial levels. Agriculture, Forestry, and Other Land Use (AFOLU) sectors, accountable for 22% of total global emissions, have been identified as significant contributors. This paper addresses the imperative need for strategic and comprehensive actions within agriculture to align with the 1.5°C pathway.
Focusing on two critical crops essential to the modern diet – rice and cocoa – this master's thesis aims to assess GHG emissions comprehensively, identify principal sources of emissions, and propose agricultural interventions with high GHG abatement potential. The research considers India as a major rice producer and exporter and Ivory Coast as the largest cacao bean producer and exporter globally.
Challenges in achieving emission reduction targets include the immense scale and heterogeneity of agricultural production systems. Each production system, influenced by factors such as geography, type of production, and farming practices, exhibits different emission sources and magnitudes. Moreover, farmers lack adequate incentives to adopt novel methods and technologies crucial for climate change mitigation.
The results reveal that direct emissions dominate in rice cultivation, primarily methane and nitrous oxide emissions from flooded paddy rice fields. In contrast, land use changes due to massive deforestation to accommodate growing demand for cacao accounts for most of the emissions in this agricultural sector. The paper identifies interventions such as alternate wetting and drying in rice cultivation and agroforestry in cacao production as effective strategies for climate mitigation.
However, significant knowledge gaps exist regarding the applicability, costs, and barriers to implementing these interventions. Enhanced research and development efforts are necessary to address these gaps and foster adoption by farmers. Transparent methodologies and accurate estimations of GHG abatement are crucial for guiding strategies toward achieving net-zero emissions by 2050 and aligning with the goals of the Paris Agreement.
In conclusion, while challenges remain, agriculture holds the potential to achieve net-zero emissions with sufficient support, motivation, and concerted efforts across stakeholders. Enhanced research, development, and adoption of sustainable practices are essential for realizing this potential and mitigating the impacts of climate change on global food security.


Dissertation
Comparative Life Cycle Assessment of an Atomic Oxygen Cleaning Device and Alternative Cleaning Strategies for Silk and Oil Paintings Preservation
Authors: --- --- --- ---
Year: 2024 Publisher: Liège Université de Liège (ULiège)

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This thesis evaluates the environmental impacts of the novel atomic oxygen cleaning device, developed in the frame of the MOXY project, in comparison to common methods used in cultural heritage conservation. Through a Life Cycle Assessment, the methods suitable for the removal of soot contamination from textile and oil painting mock-ups are compared. Results indicate that AO cleaning has a higher environmental impact compared to dry cleaning and aqueous cleaning with low volumes solvent. However, AO cleaning stands out as a more ecologically friendly alternative when compared with aqueous cleaning methods that require larger volumes of solvent and cotton ball application. Among the studied contactless cleaning methods, AO cleaning emerged can be considered to be a more sustainable choice across a majority of the environmental impact categories. The results highlight the potential of the MOXY device as a sustainable alternative, promoting greener practices in the conservation field. Cette thèse évalue les impacts environnementaux du nouveau dispositif de nettoyage à l'oxygène atomique, développé dans le cadre du projet MOXY, en comparaison avec les méthodes couramment utilisées dans la conservation du patrimoine culturel. À travers une analyse du cycle de vie, les méthodes appropriées pour l'élimination des contaminations par la suie sur des maquettes textiles et des peintures à l'huile sont comparées. Les résultats indiquent que le nettoyage à l'oxygène atomique a un impact environnemental plus élevé par rapport au nettoyage à sec et au nettoyage aqueux avec des volumes de solvant faibles. Cependant, le nettoyage à l'oxygène atomique se distingue comme une alternative plus écologique par rapport aux méthodes de nettoyage aqueuses nécessitant des volumes plus importants de solvant et l'utilisation de boules de coton. Parmi les méthodes de nettoyage sans contact étudiées, le nettoyage à l'oxygène atomique peut être considéré comme un choix plus durable dans la majorité des catégories d'impact environnemental. Les résultats mettent en évidence le potentiel du dispositif MOXY en tant qu'alternative durable, promouvant des pratiques plus écologiques dans le domaine de la conservation.


Dissertation
The impact of eco-design practices on the carbon footprint of furniture: the case of a French furniture retailer
Authors: --- --- --- --- --- et al.
Year: 2024 Publisher: Liège Université de Liège (ULiège)

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BUT, France’s second-largest home equipment retailer, aims to reach carbon neutrality by 2050. Realizing 93% of its total carbon emissions come from the products sold, BUT developed a semi-qualitative eco-scoring system to classify products by their eco-design level. So far, around one-third of products have been graded. Products with good eco-scores are then labeled as ‘eco-designed’. BUT wants to valorize this initiative in its carbon footprint report. The goal of this study is thus to assess the carbon footprint benefits of eco-designing six key furniture categories with the highest carbon footprints: mattress, bookshelf, kitchen box, fabric sofa, chest of drawers, and bed frames. The carbon footprint of eco-designed products is compared to the carbon footprint of non eco-designed products, following ISO 14067 guidelines about quantifying carbon footprint. A cradle-to-gate approach was chosen, covering raw material extraction to manufacturing. Inventories were built using data from eco-scoring grids, including material masses, recycled material share, wood supply and manufacturing energy inputs. This study is innovative in that it is based on representative quantitative data from 2,020 references, covering about 1,000,000 products sold. However, it focuses only on carbon footprint and uses moderate-quality data.

Results are consistent with literature for inventories, impacts per furniture piece, impacts per kg of furniture piece, and life cycle stage hotspots. The study shows a clear decrease in carbon footprint for three categories with eco-design, averaging a 20% reduction. This reduction is attributed to a higher share of recycled materials and sustainable wood, shorter wood supply chains, and cleaner energy sources for manufacturing. However, results are contrasting for the three other categories, as the eco-scoring system 1) does not take into account mass and energy efficiency per functional unit 2) does not rank materials based on their carbon footprint (a wood-based product has no advantage over a glass product for instance) 3) includes other impact categories without proper weighting. Sensitivity analyses on metal composition, impacts of recycled materials, and carbon storage in sustainable wood validated the main hypotheses.

To effectively achieve its decarbonizing objectives, BUT should consider several key actions. First, enhancing the quantitative nature of the eco-score computation would address the limitations of the current system and align it more with the principles of life cycle assessment. Additionally, digitizing the data collection process would enhance efficiency. Harmonizing the eco-scoring system with counterparts at a European level is essential to streamline data acquisition processes and enhance consumer decision-making. Moreover, BUT should deepen its involvement in the design phase to gain a more profound understanding of the industrial processes in furniture manufacturing, ultimately enabling the creation of truly eco-designed products. Last but not least, a more careful consideration of the fair distribution of the decarbonizing costs along the value chain should be undertaken.

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