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This thesis gives a thorough account of the development of iron-catalysed hydrosilylation, hydroboration and hydromagnesiation reactions. With extraordinary referencing and scientific argument, Mark Greenhalgh describes the development of methodologies which require only commercially available materials and non-specialised techniques. The intention of this approach is to ensure the science can be adopted widely by the chemical community. In addition to an insight into the processes involved in methodology development, Greenhalgh discusses and determines the relevant reaction mechanisms. This thesis provides not only the most thorough review of the area, but offers a level of insight well beyond that expected from a Ph.D. student. The work in this thesis has been published at the highest level, and the results and ideas have led to 3 industry-funded Ph.D. studentships and grant income in excess of £1 million. .
Chemistry. --- Organometallic chemistry. --- Chemical engineering. --- Catalysis. --- Organometallic Chemistry. --- Industrial Chemistry/Chemical Engineering. --- Alkenes. --- Iron catalysts. --- Alkynes. --- Alkines --- Ethene series --- Ethylene series --- Olefines --- Olefins --- Hydrocarbons --- Catalysts --- Chemistry, Organic. --- Chemistry, Industrial --- Engineering, Chemical --- Industrial chemistry --- Engineering --- Chemistry, Technical --- Metallurgy --- Activation (Chemistry) --- Chemistry, Physical and theoretical --- Surface chemistry --- Organic chemistry --- Chemistry --- Organometallic chemistry . --- Chemistry, Organometallic --- Metallo-organic chemistry --- Chemistry, Organic
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This thesis gives a thorough account of the development of iron-catalysed hydrosilylation, hydroboration and hydromagnesiation reactions. With extraordinary referencing and scientific argument, Mark Greenhalgh describes the development of methodologies which require only commercially available materials and non-specialised techniques. The intention of this approach is to ensure the science can be adopted widely by the chemical community. In addition to an insight into the processes involved in methodology development, Greenhalgh discusses and determines the relevant reaction mechanisms. This thesis provides not only the most thorough review of the area, but offers a level of insight well beyond that expected from a Ph.D. student. The work in this thesis has been published at the highest level, and the results and ideas have led to 3 industry-funded Ph.D. studentships and grant income in excess of £1 million. .
Chemical thermodynamics --- Descriptive organic chemistry --- Chemistry --- Enzymology --- Engineering sciences. Technology --- Chemical technology --- katalyse --- katalysatoren --- thermodynamica --- organometalische verbindingen --- BIT (biochemische ingenieurstechnieken) --- biochemie --- chemie --- biotechnologie --- ingenieurswetenschappen --- chemische technologie --- enzymen
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