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Offering a comprehensive introduction to equilibrium electrochemistry, this primer deals with electrode potentials and their applications. It builds on a knowledge of elementary thermodynamics, informs the reader of the origin of electrode potentials, and shows how these are used to deduce a wealth of chemically important information such as equilibrium constants, free energy, enthalpy and entropy changes of chemical reactions, activity coefficients, and the selective sensing of ions. The emphasis throughout is on understanding the foundations of this discipline and how it may be used to study problems of chemical interest. The authors have minimized the mathematical aspects of the subject without any sacrifices in clarity.
fysicochemie --- Electrochemistry --- Electrodes --- 544.6 --- activiteitscoëfficiënt --- elektrochemie --- fysische chemie --- migratie van ionen --- Electrochemistry. --- Electrodes. --- Electric resistors --- Chemistry, Physical and theoretical
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The power of electrochemical measurements in respect of thermodynamics, kinetics and analysis is widely recognized but the subject can be unpredictable to the novice even if they have a strong physical and chemical background, especially if they wish to pursue quantitative measurements. Accordingly, some significant experiments are perhaps wisely never attempted while the literature is sadly replete with flawed attempts at rigorous voltammetry. This textbook considers how to go about designing, explaining and interpreting experiments centered around various forms of voltammetry (cyclic, microelectrode, hydrodynamic, and so on). The reader is assumed to have a knowledge to Masters level of physical chemistry but no exposure to electrochemistry in general, or voltammetry in particular. While the book is designed to 'stand alone', references to important research papers are given to provide an entry into the literature. The book gives clear introductions to the theories of electron transfer and of diffusion in its early chapters. These are developed to interpret voltammetric experiments at macro-electrodes before considering microelectrode behavior. A subsequent chapter introduces convection and describes hydrodynamic electrodes. Later chapters describe the voltammetric measurement of homogeneous kinetics, the study of adsorption on electrodes and the use of voltammetry for electroanalysis.
Thermodynamics --- kwantitatieve analyse (chemie) --- Electrochemistry --- fysicochemie --- voltametrie --- Electrochemical analysis --- elektrochemie --- Physicochemistry --- thermodynamica --- Voltammetry --- Voltamétrie --- Electrochimie --- Voltamétrie --- Voltammetry - Textbooks
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"There is a wealth of voltammetric data from a range of systems, with numerous diagrams showing actual voltammograms, greatly helpful to a reader new to the field, with underpinning mathematical equations and supportive mechanistic explanation. This is a most useful and instructive book."--Chemistry & Industry --Back Cover. In comparison to the first edition, two new chapters -- transport via migration and nanoelectrochemistry -- are added. Minor changes and updates are also made throughout the textbook to facilitate enhanced understanding and greater clarity of exposition. --Back Cover. The power of electrochemical measurements in respect of thermodynamics, kinetics and analysis is widely recognized but the subject can be unpredictable to the novice even if they have a strong physical and chemical background, especially if they wish to pursue the study of quantitative measurements further. Accordingly, some significant experiments are perhaps wisely never attempted while the literature is sadly replete with flawed attempts at rigorous voltammetry. -- Back Cover. This textbook considers how to go about designing, explaining and interpreting experiments centered around various forms of voltammetry (cyclic, microelectrode, hydrodynamic, etc.). The reader is assumed to have attained a knowledge equivalent to Master's level of physical chemistry but no exposure to electrochemistry in general, or voltammetry in particular. While the book is designed to "stand alone", references to important research papers are given to provide an introductory entry into the literature. -- Back Cover.
Voltammetry --- Monograph --- Voltammetry. --- Voltamétrie
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Aiming to offer an accessible introduction to one of the most difficult for beginners areas of chemistry, this primer covers a wide range of material in a succinct, easy-to-understand format. The first two chapters cover the structure of atoms, ions, and molecules. The next few chapters discuss such important issues as chemical reactivity, kinetics, and equilibria, while the final chapter deals with more advanced subject matter, drawing on imaginative examples from the outside world. Aware of the fact that beginners are easily intimidated by complex mathematical formulas, the authors have striven to keep quantitative aspects to a mininmum throughout.
541.1 --- Chemistry, Physical and theoretical --- #WSCH:FYS3 --- 544 --- 544.3 --- 544.4 --- atoomstructuur --- chemisch evenwicht --- chemische kinetica --- chemische thermodynamica --- fysische chemie --- ionen --- molecuulstructuren --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- chemische kynetica. Katalyse --- Chemistry, Physical and theoretical. --- 541.1 Physical chemistry
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"The power of electrochemical measurements in respect of thermodynamics, kinetics and analysis is widely recognised but the subject can be unpredictable to the novice even if they have a strong physical and chemical background, and most especially if they wish to pursue quantitative measurements. Accordingly, some significant experiments are perhaps wisely never attempted while the literature is sadly replete with flawed attempts at rigorous voltammetry. This textbook considers how to implement designing, explaining and interpreting experiments centred on various forms of voltammetry (cyclic, microelectrode, hydrodynamic, etc.). The reader is assumed to have knowledge of physical chemistry equivalent to Master's level but no exposure to electrochemistry, or voltammetry in particular. While the book is designed to stand alone, references to important research papers are given to provide an introductory entry into the literature. In this fourth edition, important parts of the text have been re-written for optimal clarity, recognising that many readers will not have English as a first language. Updates to the text have been made and new, additional material included, expanding the text whilst retaining the overall concise, to-the-point approach which has proved popular with the readers of the previous editions."--
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Voltammetry --- Electrochemistry --- Voltamétrie --- Electrochimie --- Textbooks --- Manuels d'enseignement supérieur --- Basic Sciences. Chemistry --- Physical Chemistry --- Electrochemistry. --- Voltamétrie --- Manuels d'enseignement supérieur
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Star Trek - La Nouvelle Génération dépeint une société utopique dans laquelle l'économie n'est plus fondée sur l'argent et qui a su éliminer la famine et la misère grâce à la surabondance. Nourriture et biens matériels peuvent être matérialisés en transformant l'énergie en matière grâce à la technologie de la réplication. L'argent n'étant plus le moteur animant l'humanité, celle-ci se tourne vers la constante quête d'amélioration du soi cherchant à accroître ses connaissances scientifiques ainsi que sa connaissance des civilisations passées et présentes de la galaxie. Episode 9: La Bataille: Bok, un commandant Ferengi, offre à Picard l'épave du Stargazer supposé perdu. Le commandant Picard commence à souffrir d'atroces maux de tête tandis que ses souvenirs de l'ancienne bataille se brouillent... Episode 10: Dans la peau de Q: Q fait sa réapparition pour offrir des pouvoirs identiques aux siens à Picard qui refuse, puis à Riker qui hésite. Pendant ce temps, l'Entreprise D doit secourir les survivants d'une colonie sur la planète Sigma III... Episode 11: Haven: Lwaxana Troi, la mère de Deanna, arrive sur l'Entreprise D avec un mari et des beaux-parents pour sa fille. Mais le fiancé de Deanna est amoureux depuis toujours d'une autre femme qui lui apparaît en rêve... Episode 12: Le Long Adieu: À la suite d'un incident avec le holodeck, Picard, Data et le Dr Crusher sont retenus par un dangereux gangster dans une simulation qui devient beaucoup trop réelle à leur goût. Cette simulation, créée par Picard, est fondée sur le personnage de Dixon Hill, un détective privé de Chicago pendant la prohibition...
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