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Chemistry from First Principles is written for any chemist who requires a fundamental understanding of the complexities of chemistry. It provides a clear interpretation of chemical theory from first principles. This book examines the appearance of matter in its most primitive form, from the vacuum and the diversity that results from the fusion of elementary units in the genesis of atomic matter; considers the empirical rules of chemical affinity that regulate the synthesis and properties of molecular matter; analyzes the compatibility of the theories of chemistry with the quantum and relativity theories of physics; formulates a consistent theory, based on clear physical pictures and manageable mathematics, to account for chemical concepts such as the structure and stability of atoms and molecules, the periodicity of nuclides and elements, valence states, activation and chemical reactivity, electronegativity and general covalency, the exclusion principle, electronic energy, orbital angular momentum and spin in relation to molecular shape, torsional rigidity, chirality and molecular modeling; explains the self-similarity between space-time, nuclear structure, covalent assembly, biological growth, planetary systems and galactic conformation. Chemistry from First Principles is an essential guide for students of chemistry who lack the knowledge in higher mathematics considered necessary to grasp the basic principles of chemical theory, teachers of chemistry who are forced to preach concepts which they poorly understand, and any scientist who is seeking a true understanding of chemistry through logical concepts.
Chemistry, Analytic. --- Chemistry, Physical and theoretical. --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Analysis, Chemical --- Analytical chemistry --- Chemical analysis --- Metallurgical analysis --- Mineralogy, Determinative --- Chemistry. --- Chemistry, Physical organic. --- Quantum theory. --- Theoretical and Computational Chemistry. --- Applied and Technical Physics. --- Math. Applications in Chemistry. --- Physical Chemistry. --- Quantum Physics. --- Mathematics. --- Quantum dynamics --- Quantum mechanics --- Quantum physics --- Physics --- Mechanics --- Thermodynamics --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Physical sciences --- Chemistry, Physical. --- Chimie. --- Physics. --- Chemometrics. --- Physical chemistry. --- Quantum physics. --- Chemistry, Analytic --- Natural philosophy --- Philosophy, Natural --- Dynamics --- Mathematics --- Measurement --- Statistical methods
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This volume, written by a highly cited author, presents the history of quantum theory together with open questions and remaining problems in terms of the plausibility of quantum chemistry and physics. It also provides insights into the theory of matter-wave mechanics. The content is aimed at students and lecturers in chemistry, physics and the philosophy of science.
Chemistry. --- Chemistry, Physical and theoretical. --- Chemistry --- Philosophy and science. --- Cosmology. --- Theoretical and Computational Chemistry. --- Philosophy of Science. --- History of Chemistry. --- History. --- Quantum chemistry. --- Chemistry, Quantum --- Chemistry, Physical and theoretical --- Quantum theory --- Excited state chemistry --- Science --- Chemistry-History. --- Philosophy. --- Normal science --- Philosophy of science --- Physical sciences --- Chemistry—History. --- Astronomy --- Deism --- Metaphysics --- Science and philosophy --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry
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Mathematics --- Quantum mechanics. Quantumfield theory --- Physicochemistry --- Chemistry --- Computer. Automation --- quantumfysica --- chemie --- informatica --- wiskunde --- fysicochemie
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The quantum and relativity theories of physics are considered to underpin all of science in an absolute sense. This monograph argues against this proposition primarily on the basis of the two theories' incompatibility and of some untenable philosophical implications of the quantum model. Elementary matter is assumed in both theories to occur as zero-dimensional point particles. In relativity theory this requires the space-like region of the underlying Minkowski space-time to be rejected as unphysical, despite its precise mathematical characterization. In quantum theory it leads to an incomprehensible interpretation of the wave nature of matter in terms of a probability function and the equally obscure concept of wave-particle duality. The most worrisome aspect about quantum mechanics as a theory of chemistry is its total inability, despite unsubstantiated claims to the contrary, to account for the fundamental concepts of electron spin, molecular structure, and the periodic table of the elements. A remedy of all these defects by reformulation of both theories as nonlinear wave models in four-dimensional space-time is described.
Mathematical physics --- Theory of relativity. Unified field theory --- Chemistry --- Geophysics --- Computer. Automation --- zwaartekracht --- theoretische fysica --- chemie --- informatica --- relativiteitstheorie
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This volume, written by a highly cited author, presents the history of quantum theory together with open questions and remaining problems in terms of the plausibility of quantum chemistry and physics. It also provides insights into the theory of matter-wave mechanics. The content is aimed at students and lecturers in chemistry, physics and the philosophy of science.
Philosophy of science --- Cosmology --- Chemistry --- Computer. Automation --- History --- chemie --- geschiedenis --- informatica --- wetenschapsfilosofie --- kosmologie
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J.C.A. Boeyens and P. Comba Chemistry by Number Theory J.C.A. Boeyens Chemistry in Four Dimensions C.J.H. Schutte Is the Rydberg-Ritz relationship valid? J.C.A. Boeyens Calculation of Atomic Structure J.C.A. Boeyens Covalent Interaction P. Comba and J.C.A. Boeyens Molecular Shape J.C.A. Boeyens and D. C. Levendis All is Number.
Chemistry --- Physical Sciences & Mathematics --- Inorganic Chemistry --- Chemistry. --- Inorganic chemistry. --- Chemometrics. --- Chemistry, Physical and theoretical. --- Inorganic Chemistry. --- Math. Applications in Chemistry. --- Theoretical and Computational Chemistry. --- Electronic structure. --- Number theory. --- Number study --- Numbers, Theory of --- Algebra --- Structure, Electronic --- Atomic structure --- Energy-band theory of solids --- Chemistry, inorganic. --- Mathematics. --- Inorganic chemistry --- Inorganic compounds --- Physical sciences --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry, Analytic --- Analytical chemistry --- Mathematics --- Measurement --- Statistical methods
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Chemistry from First Principles is written for any chemist who requires a fundamental understanding of the complexities of chemistry. It provides a clear interpretation of chemical theory from first principles. This book examines the appearance of matter in its most primitive form, from the vacuum and the diversity that results from the fusion of elementary units in the genesis of atomic matter; considers the empirical rules of chemical affinity that regulate the synthesis and properties of molecular matter; analyzes the compatibility of the theories of chemistry with the quantum and relativity theories of physics; formulates a consistent theory, based on clear physical pictures and manageable mathematics, to account for chemical concepts such as the structure and stability of atoms and molecules, the periodicity of nuclides and elements, valence states, activation and chemical reactivity, electronegativity and general covalency, the exclusion principle, electronic energy, orbital angular momentum and spin in relation to molecular shape, torsional rigidity, chirality and molecular modeling; explains the self-similarity between space-time, nuclear structure, covalent assembly, biological growth, planetary systems and galactic conformation. Chemistry from First Principles is an essential guide for students of chemistry who lack the knowledge in higher mathematics considered necessary to grasp the basic principles of chemical theory, teachers of chemistry who are forced to preach concepts which they poorly understand, and any scientist who is seeking a true understanding of chemistry through logical concepts.
Mathematics --- Quantum mechanics. Quantumfield theory --- Physicochemistry --- Chemistry --- Computer. Automation --- quantumfysica --- chemie --- informatica --- wiskunde --- fysicochemie
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The composition of the most remote objects brought into view by the Hubble telescope can no longer be reconciled with the nucleogenesis of standard cosmology and the alternative explanation, in terms of the Î-Cold-Dark-Matter model, has no recognizable chemical basis. A more rational scheme, based on the chemistry and periodicity of atomic matter, opens up an exciting new interpretation of the cosmos in terms of projective geometry and general relativity. The target readership includes scientists, as well as non-scientists - everybody with a scientific or philosophical interest in cosmology and, especially those cosmologists and mathematicians with the ability to recast the crude ideas presented here into appropriate mathematical models.
Theory of relativity. Unified field theory --- Chemistry --- Geophysics --- Computer. Automation --- zwaartekracht --- chemie --- informatica --- relativiteitstheorie
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Physicochemistry --- Chemical structure --- Analytical chemistry --- Chemical and physical crystallography --- Electrical engineering --- Computer. Automation --- kristallografie --- nanotechniek --- analytische chemie --- chemie --- informatica --- fysicochemie --- atoomstructuur
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