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La spectroscopie de Résonance Paramagnétique Electronique (RPE), c’est-à-dire l’étude de la structure électronique des centres paramagnétiques, est de plus en plus utilisée pour des applications qui vont bien au-delà de celles imaginées initialement par les physiciens. La RPE permet d’obtenir des informations sur l’évolution de propriétés dans le temps (datation) et dans l’espace (traçage). Avec plus d’investissement, elle rend possible l’identification d’une molécule et la détermination de niveaux d’énergie. Cela concerne la physique, la chimie mais aussi les sciences de la Terre et de l’univers, celles de l’environnement, de la vie et de la santé. Cet ouvrage collectif présente une grande variété d’applications. Certaines ne nécessitent pas un bagage théorique important pour être comprises. Pour d’autres, il est possible de se référer à l’ouvrage "La spectroscopie de RPE - Fondements" dans la même collection ou à certains compléments de fin de chapitre. Des annexes sur des méthodes ou techniques sont proposées de façon indépendante en fin d’ouvrage. Enfin, pour chaque application, des références sont proposées à ceux qui veulent approfondir. L’ouvrage est accessible à des étudiants de master 1 de physique, de chimie, de chimie physique, de biophysique et de biochimie. Il sera utile aux professionnels qui utilisent la technique de spectroscopie RPE, aux chercheurs mais aussi aux enseignants du supérieur et des classes préparatoires qui pourront ainsi élargir leurs connaissances de façon très concrète et illustrée. Chaque application est présentée, expliquée par les meilleurs spécialistes de la question, soit une trentaine d’auteurs principaux, coordonnés par Patrick Bertrand qui a repris, avec le soutien de Grenoble Sciences, l’ensemble des productions pour assurer une cohérence et une uniformité de lecture.
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Although originally invented and employed by physicists, electron paramagnetic resonance (EPR) spectroscopy has proven to be a very efficient technique for studying a wide range of phenomena in many fields, such as chemistry, biochemistry, geology, archaeology, medicine, biotechnology, and environmental sciences. Acknowledging that not all studies require the same level of understanding of this technique, this book thus provides a practical treatise clearly oriented toward applications, which should be useful to students and researchers of various levels and disciplines. In this book, the principles of continuous wave EPR spectroscopy are progressively, but rigorously, introduced, with emphasis on interpretation of the collected spectra. Each chapter is followed by a section highlighting important points for applications, together with exercises solved at the end of the book. A glossary defines the main terms used in the book, and particular topics, whose knowledge is not required for understanding the main text, are developed in appendices for more inquisitive readers.
Spectroscopy. --- Microscopy. --- Atomic structure . --- Molecular structure . --- Magnetism. --- Magnetic materials. --- Crystallography. --- Physical chemistry. --- Materials science. --- Spectroscopy and Microscopy. --- Atomic/Molecular Structure and Spectra. --- Magnetism, Magnetic Materials. --- Crystallography and Scattering Methods. --- Physical Chemistry. --- Characterization and Evaluation of Materials. --- Material science --- Physical sciences --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Leptology --- Mineralogy --- Materials --- Mathematical physics --- Physics --- Electricity --- Magnetics --- Structure, Molecular --- Chemical structure --- Structural bioinformatics --- Structure, Atomic --- Atomic theory --- Analysis, Microscopic --- Light microscopy --- Micrographic analysis --- Microscope and microscopy --- Microscopic analysis --- Optical microscopy --- Optics --- Analysis, Spectrum --- Spectra --- Spectrochemical analysis --- Spectrochemistry --- Spectroscopy --- Chemistry, Analytic --- Interferometry --- Radiation --- Wave-motion, Theory of --- Absorption spectra --- Light --- Spectroscope --- Qualitative --- Electron paramagnetic resonance spectroscopy. --- Electron spin resonance spectroscopy --- EPR spectroscopy --- ESR spectroscopy --- Spectrum analysis --- Spectrometry --- Analytical chemistry
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This book shows how the fundamentals of electron paramagnetic resonance (EPR) spectroscopy are practically implemented and illustrates the diversity of current applications. The technique is used at various levels, and applications are presented in order of increasing difficulty, with reference to theoretically obtained results. This book features a diverse array of application examples, from fields such as ionizing radiation dosimetry, neurodegenerative diseases, structural transitions in proteins, and the origins of terrestrial life. The final chapter of this book highlights the principles and applications of the technique of ferromagnetic resonance spectroscopy, followed by a brief introduction to advanced EPR techniques such as electron spin echo envelope modulation (ESEEM), hyperfine sub-level correlation (HYSCORE), pulsed electron-electron double resonance (PELDOR), and continuous wave electron nuclear double resonance (ENDOR) experiments.
Spectroscopy. --- Microscopy. --- Atomic structure . --- Molecular structure . --- Magnetism. --- Magnetic materials. --- Crystallography. --- Physical chemistry. --- Materials science. --- Spectroscopy and Microscopy. --- Atomic/Molecular Structure and Spectra. --- Magnetism, Magnetic Materials. --- Crystallography and Scattering Methods. --- Physical Chemistry. --- Characterization and Evaluation of Materials. --- Material science --- Physical sciences --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Leptology --- Mineralogy --- Materials --- Mathematical physics --- Physics --- Electricity --- Magnetics --- Structure, Molecular --- Chemical structure --- Structural bioinformatics --- Structure, Atomic --- Atomic theory --- Analysis, Microscopic --- Light microscopy --- Micrographic analysis --- Microscope and microscopy --- Microscopic analysis --- Optical microscopy --- Optics --- Analysis, Spectrum --- Spectra --- Spectrochemical analysis --- Spectrochemistry --- Spectroscopy --- Chemistry, Analytic --- Interferometry --- Radiation --- Wave-motion, Theory of --- Absorption spectra --- Light --- Spectroscope --- Qualitative --- Spectrometry --- Analytical chemistry
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Although originally invented and employed by physicists, electron paramagnetic resonance (EPR) spectroscopy has proven to be a very efficient technique for studying a wide range of phenomena in many fields, such as chemistry, biochemistry, geology, archaeology, medicine, biotechnology, and environmental sciences. Acknowledging that not all studies require the same level of understanding of this technique, this book thus provides a practical treatise clearly oriented toward applications, which should be useful to students and researchers of various levels and disciplines. In this book, the principles of continuous wave EPR spectroscopy are progressively, but rigorously, introduced, with emphasis on interpretation of the collected spectra. Each chapter is followed by a section highlighting important points for applications, together with exercises solved at the end of the book. A glossary defines the main terms used in the book, and particular topics, whose knowledge is not required for understanding the main text, are developed in appendices for more inquisitive readers.
Optics. Quantum optics --- Electromagnetism. Ferromagnetism --- Physicochemistry --- Chemical structure --- Theoretical spectroscopy. Spectroscopic techniques --- Chemical and physical crystallography --- Molecular biology --- Materials sciences --- moleculaire structuur --- kristallografie --- materiaalkennis --- spectroscopie --- microscopie --- magnetisme --- fysicochemie --- atoomstructuur
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This book shows how the fundamentals of electron paramagnetic resonance (EPR) spectroscopy are practically implemented and illustrates the diversity of current applications. The technique is used at various levels, and applications are presented in order of increasing difficulty, with reference to theoretically obtained results. This book features a diverse array of application examples, from fields such as ionizing radiation dosimetry, neurodegenerative diseases, structural transitions in proteins, and the origins of terrestrial life. The final chapter of this book highlights the principles and applications of the technique of ferromagnetic resonance spectroscopy, followed by a brief introduction to advanced EPR techniques such as electron spin echo envelope modulation (ESEEM), hyperfine sub-level correlation (HYSCORE), pulsed electron-electron double resonance (PELDOR), and continuous wave electron nuclear double resonance (ENDOR) experiments.
Optics. Quantum optics --- Electromagnetism. Ferromagnetism --- Physicochemistry --- Chemical structure --- Theoretical spectroscopy. Spectroscopic techniques --- Chemical and physical crystallography --- Molecular biology --- Materials sciences --- moleculaire structuur --- kristallografie --- materiaalkennis --- spectroscopie --- microscopie --- magnetisme --- fysicochemie --- atoomstructuur
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La transition énergétique est un enjeu stratégique et technologique incontournable pour préserver l'avenir de notre planète ! Objet de toutes les attentions, elle n'en demeure pas moins complexe pour le grand public, trop souvent démuni face aux choix stratégiques de nos dirigeants et aux explications techniques des spécialistes. Seriez-vous, en effet, capables d'expliquer simplement ce qu'est le nucléaire durable, une pompe à chaleur, une énergie intermittente ou une empreinte carbone ? Ce livre a pour but d'expliciter le sens des mots et des expressions couramment utilisés dans ce domaine. Une centaine d'entrées ont été sélectionnées et chacune fait l'objet d'un texte court d'une ou deux pages, qui s'appuie, si nécessaire, sur un schéma simple. 100 mots essentiels pour comprendre la transition énergétique et agir durablement pour la planète !
Transition énergétique --- Environnement --- Énergies renouvelables. --- Terminologie. --- Protection.
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Performance --- Hydroelectric micropower generation --- Benefit cost analysis --- Evaluation. --- Hydroelectric micropower generation --- Benefit cost analysis
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Rentabilite --- Calcul economique --- Energie hydraulique --- Micro-centrales --- Rentabilite --- Calcul economique --- Energie hydraulique --- Micro-centrales
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