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Titanium dioxide is currently being used in many industrial products. It provides unique photocatalytic properties for water splitting and purification, bacterial inactivation, and organics degradation. It has also been widely used as the photoanode for dye-sensitized solar cells and coatings for self-cleaning surfaces, biomedical implants, and nanomedicine. This book covers various aspects of titanium dioxide nanomaterials including their unique one-dimensional, two-dimensional, mesoporous, and hierarchical nanostructures and their synthetic methods such as sol-gel, hydrothermal, anodic oxidation, and electrophoretic deposition, as well as its key applications in environmental and energy sectors. Through these 24 chapters written by experts from the international scientific community, readers will have access to a comprehensive overview of the recent research and development findings on the titanium dioxide nanomaterials.
Titanium dioxide. --- Anatase --- Brookite --- Octahedrite --- Titania (Chemical) --- Titanic acid anhydride --- Titanic oxide --- Titanium oxide --- Titanium white --- Oxides --- Titanium compounds --- Physical Sciences --- Engineering and Technology --- Materials Science --- Metals and Nonmetals
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Electric discharge lighting. --- Photocatalysis. --- Titanium dioxide --- Titanium dioxide films. --- Anatase --- Brookite --- Octahedrite --- Titania (Chemical) --- Titanic acid anhydride --- Titanic oxide --- Titanium oxide --- Titanium white --- Oxides --- Titanium compounds --- Catalysis --- Electric discharge lamps --- Electric discharges through gases --- Electric lighting --- Electric properties.
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During the past decade, research and development in the area of synthesis and applications of different nanostructured titanium dioxide have become tremendous. This book briefly describes properties, production, modification and applications of nanostructured titanium dioxide focusing in particular on photocatalytic activity. The physicochemical properties of nanostructured titanium dioxide are highlighted and the links between properties and applications are emphasized. The preparation of TiO2 nanomaterials, including nanoparticles, nanorods, nanowires, nanosheets, nanofibers, and nanotubes a
Nanostructured materials. --- Titanium dioxide. --- Anatase --- Brookite --- Octahedrite --- Titania (Chemical) --- Titanic acid anhydride --- Titanic oxide --- Titanium oxide --- Titanium white --- Oxides --- Titanium compounds --- Nanomaterials --- Nanometer materials --- Nanophase materials --- Nanostructure controlled materials --- Nanostructure materials --- Ultra-fine microstructure materials --- Microstructure --- Nanotechnology --- Nanostructured materials --- Titanium dioxide --- Nanotubes
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Semiconductor photocatalysts have attracted a great amount of multidiscipline research due to their high potential for solar-to-chemical-energy conversion applications, ranging from water and air purification to hydrogen and chemical fuel production. This unique diversity of photoinduced applications has spurred major research efforts on the rational design and development of photocatalytic materials with tailored structural, morphological, and optoelectronic properties in order to promote solar-light harvesting, easy photogenerated electron-hole recombination and the concomitant low quantum efficiency. This book presents a collection of original research articles on advanced photocatalytic materials, synthesized by novel fabrication approaches and/or innovative modifications that improve their performance in target photocatalytic applications such as water (cyanobacterial toxins, antibiotics, phenols, and dyes) and air (NOx and volatile organic compounds) pollutant degradation, hydrogen evolution, and hydrogen peroxide production by photoelectrochemical cells.
Technology: general issues --- anatase --- brookite --- C/N-TiO2 --- microcystin-LR --- photodegradation --- visible light --- TiO2 nanomaterials --- Au nanoparticles --- anodization --- photocatalytic degradation of antibiotics --- LC-MS/MS --- TiO2 --- photonic crystals --- graphene oxide nanocolloids --- reduced graphene oxide --- photocatalysis --- photocatalytic materials --- nanocomposites --- sulfate-modified BiVO4 --- methylene blue --- LED visible light --- photodecomposition --- anatase TiO2 nanocrystals --- high-energy facets --- photocatalytic activity --- photovoltaic performance --- photoactive cement --- TiO2/N --- NOx decomposition --- mechanical properties --- plasmonic photocatalysis --- silver-copper oxide --- VOCs remediation --- full-spectrum photoresponse --- carbon-doped titania --- carbon-modified titania --- graphene/titania --- vis-active photocatalyst --- antibacterial properties --- laser pyrolysis --- hydrogen peroxide --- CdS --- CdSe --- photoelectrocatalysis --- photocatalytic fuel cells --- photo fuel cells --- visible light activated titania --- heterojunction photocatalysts --- photonic crystal catalysts --- graphene-based photocatalysts --- water and air purification --- solar fuels --- anatase --- brookite --- C/N-TiO2 --- microcystin-LR --- photodegradation --- visible light --- TiO2 nanomaterials --- Au nanoparticles --- anodization --- photocatalytic degradation of antibiotics --- LC-MS/MS --- TiO2 --- photonic crystals --- graphene oxide nanocolloids --- reduced graphene oxide --- photocatalysis --- photocatalytic materials --- nanocomposites --- sulfate-modified BiVO4 --- methylene blue --- LED visible light --- photodecomposition --- anatase TiO2 nanocrystals --- high-energy facets --- photocatalytic activity --- photovoltaic performance --- photoactive cement --- TiO2/N --- NOx decomposition --- mechanical properties --- plasmonic photocatalysis --- silver-copper oxide --- VOCs remediation --- full-spectrum photoresponse --- carbon-doped titania --- carbon-modified titania --- graphene/titania --- vis-active photocatalyst --- antibacterial properties --- laser pyrolysis --- hydrogen peroxide --- CdS --- CdSe --- photoelectrocatalysis --- photocatalytic fuel cells --- photo fuel cells --- visible light activated titania --- heterojunction photocatalysts --- photonic crystal catalysts --- graphene-based photocatalysts --- water and air purification --- solar fuels
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Semiconductor photocatalysts have attracted a great amount of multidiscipline research due to their high potential for solar-to-chemical-energy conversion applications, ranging from water and air purification to hydrogen and chemical fuel production. This unique diversity of photoinduced applications has spurred major research efforts on the rational design and development of photocatalytic materials with tailored structural, morphological, and optoelectronic properties in order to promote solar-light harvesting, easy photogenerated electron-hole recombination and the concomitant low quantum efficiency. This book presents a collection of original research articles on advanced photocatalytic materials, synthesized by novel fabrication approaches and/or innovative modifications that improve their performance in target photocatalytic applications such as water (cyanobacterial toxins, antibiotics, phenols, and dyes) and air (NOx and volatile organic compounds) pollutant degradation, hydrogen evolution, and hydrogen peroxide production by photoelectrochemical cells.
Technology: general issues --- anatase --- brookite --- C/N-TiO2 --- microcystin-LR --- photodegradation --- visible light --- TiO2 nanomaterials --- Au nanoparticles --- anodization --- photocatalytic degradation of antibiotics --- LC-MS/MS --- TiO2 --- photonic crystals --- graphene oxide nanocolloids --- reduced graphene oxide --- photocatalysis --- photocatalytic materials --- nanocomposites --- sulfate-modified BiVO4 --- methylene blue --- LED visible light --- photodecomposition --- anatase TiO2 nanocrystals --- high-energy facets --- photocatalytic activity --- photovoltaic performance --- photoactive cement --- TiO2/N --- NOx decomposition --- mechanical properties --- plasmonic photocatalysis --- silver-copper oxide --- VOCs remediation --- full-spectrum photoresponse --- carbon-doped titania --- carbon-modified titania --- graphene/titania --- vis-active photocatalyst --- antibacterial properties --- laser pyrolysis --- hydrogen peroxide --- CdS --- CdSe --- photoelectrocatalysis --- photocatalytic fuel cells --- photo fuel cells --- visible light activated titania --- heterojunction photocatalysts --- photonic crystal catalysts --- graphene-based photocatalysts --- water and air purification --- solar fuels
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Semiconductor photocatalysts have attracted a great amount of multidiscipline research due to their high potential for solar-to-chemical-energy conversion applications, ranging from water and air purification to hydrogen and chemical fuel production. This unique diversity of photoinduced applications has spurred major research efforts on the rational design and development of photocatalytic materials with tailored structural, morphological, and optoelectronic properties in order to promote solar-light harvesting, easy photogenerated electron-hole recombination and the concomitant low quantum efficiency. This book presents a collection of original research articles on advanced photocatalytic materials, synthesized by novel fabrication approaches and/or innovative modifications that improve their performance in target photocatalytic applications such as water (cyanobacterial toxins, antibiotics, phenols, and dyes) and air (NOx and volatile organic compounds) pollutant degradation, hydrogen evolution, and hydrogen peroxide production by photoelectrochemical cells.
anatase --- brookite --- C/N-TiO2 --- microcystin-LR --- photodegradation --- visible light --- TiO2 nanomaterials --- Au nanoparticles --- anodization --- photocatalytic degradation of antibiotics --- LC-MS/MS --- TiO2 --- photonic crystals --- graphene oxide nanocolloids --- reduced graphene oxide --- photocatalysis --- photocatalytic materials --- nanocomposites --- sulfate-modified BiVO4 --- methylene blue --- LED visible light --- photodecomposition --- anatase TiO2 nanocrystals --- high-energy facets --- photocatalytic activity --- photovoltaic performance --- photoactive cement --- TiO2/N --- NOx decomposition --- mechanical properties --- plasmonic photocatalysis --- silver-copper oxide --- VOCs remediation --- full-spectrum photoresponse --- carbon-doped titania --- carbon-modified titania --- graphene/titania --- vis-active photocatalyst --- antibacterial properties --- laser pyrolysis --- hydrogen peroxide --- CdS --- CdSe --- photoelectrocatalysis --- photocatalytic fuel cells --- photo fuel cells --- visible light activated titania --- heterojunction photocatalysts --- photonic crystal catalysts --- graphene-based photocatalysts --- water and air purification --- solar fuels
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Pursuing a scalable production methodology for materials and advancing it from the laboratory to industry is beneficial to novel daily-life applications. From this perspective, chemical vapor deposition (CVD) offers a compromise between efficiency, controllability, tunability and excellent run-to-run repeatability in the coverage of monolayers on substrates. Hence, CVD meets all of the requirements for industrialization in basically all areas, including polymer coatings, metals, water-filtration systems, solar cells and so on. The Special Issue “Advances in Chemical Vapor Deposition” is dedicated to providing an overview of the latest experimental findings and identifying the growth parameters and characteristics of perovskites, TiO2, Al2O3, VO2 and V2O5 with desired qualities for potentially useful devices.
Technology: general issues --- APCVD --- VO2 --- processing parameters --- 2D --- chemical vapor deposition --- atomic layer deposition --- aluminum oxide --- aluminum tri-sec-butoxide --- thin film --- carbon nanotubes --- residual gas adsorption --- residual gas desorption --- field emission --- atmospheric pressure CVD --- low pressure CVD --- hybrid CVD --- aerosol assisted CVD --- pulsed CVD --- perovskite photovoltaic nanomaterials --- stabilization --- structural design --- performance optimization --- solar cells --- anatase single crystals --- process-induced nanostructures --- competitive growth --- pp-MOCVD --- vanadium pentoxide --- electrochromic --- spray pyrolysis --- ammonium metavanadate --- CVD --- electrochromism --- perovskite photovoltaic materials --- TiO2 --- Al2O3 --- V2O5 --- computational fluid dynamics --- APCVD --- VO2 --- processing parameters --- 2D --- chemical vapor deposition --- atomic layer deposition --- aluminum oxide --- aluminum tri-sec-butoxide --- thin film --- carbon nanotubes --- residual gas adsorption --- residual gas desorption --- field emission --- atmospheric pressure CVD --- low pressure CVD --- hybrid CVD --- aerosol assisted CVD --- pulsed CVD --- perovskite photovoltaic nanomaterials --- stabilization --- structural design --- performance optimization --- solar cells --- anatase single crystals --- process-induced nanostructures --- competitive growth --- pp-MOCVD --- vanadium pentoxide --- electrochromic --- spray pyrolysis --- ammonium metavanadate --- CVD --- electrochromism --- perovskite photovoltaic materials --- TiO2 --- Al2O3 --- V2O5 --- computational fluid dynamics
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The quality of water is not only a technological and scientific issue, but a social and economic problem, in both developed and developing countries. Besides local regulations, which differ between regions and need constant upgrades, significant scientific developments are required in both the detection and removal of water contaminants. This Issue focuses on some recent advancements in the photocatalytic removal of organic pollutants, which is one of the aspects of the problem that involves the need of advanced catalysts and implies significant advancements in the field of materials science and chemical engineering.
History of engineering & technology --- indigo carmine --- resin --- Dielectric Barrier Discharge --- adsorption --- regeneration --- anatase/brookite biphasic --- nitrogen-doping --- sol-gel method --- visible light photocatalysis --- degradation of dyes --- polyaniline --- titanium dioxide --- copper(II) oxide --- cobalt oxide(II,III) --- photocatalytic fuel cell --- graphitic carbon nitride --- Fe doping --- Z-scheme --- strontium aluminates --- dye photodecomposition --- hydrothermal reaction --- sol-gel method --- phosphorescence --- photocatalytic decomposition of rhodamine B --- MIL-53(Fe) --- Ni/Fe-MOF --- visible light irradiation --- indigo carmine --- resin --- Dielectric Barrier Discharge --- adsorption --- regeneration --- anatase/brookite biphasic --- nitrogen-doping --- sol-gel method --- visible light photocatalysis --- degradation of dyes --- polyaniline --- titanium dioxide --- copper(II) oxide --- cobalt oxide(II,III) --- photocatalytic fuel cell --- graphitic carbon nitride --- Fe doping --- Z-scheme --- strontium aluminates --- dye photodecomposition --- hydrothermal reaction --- sol-gel method --- phosphorescence --- photocatalytic decomposition of rhodamine B --- MIL-53(Fe) --- Ni/Fe-MOF --- visible light irradiation
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This outstanding thesis provides a wide-ranging overview of the growth of titanium dioxide thin films and its use in photo-electrochemicals such as water splitting. The context for water splitting is introduced with the theory of semiconductor-liquid junctions, which are dealt with in detail. In particular plasmonic enhancement of TiO2 by the addition of gold nanoparticles is considered in depth, including a thorough and critical review of the literature, which discusses the possible mechanisms that may be at work. Plasmonic enhancement is demonstrated with gold nanoparticles on Nb-doped TiO2. Finally, the use of temperature and pressure to control the phase and morphology of thin films grown by pulsed laser deposition is presented.
Engineering. --- Electrochemistry. --- Nanoscale science. --- Nanoscience. --- Nanostructures. --- Engineering --- Materials science. --- Materials Engineering. --- Characterization and Evaluation of Materials. --- Nanoscale Science and Technology. --- Materials. --- Titanium dioxide. --- Anatase --- Brookite --- Octahedrite --- Titania (Chemical) --- Titanic acid anhydride --- Titanic oxide --- Titanium oxide --- Titanium white --- Chemistry, Physical and theoretical --- Oxides --- Titanium compounds --- Surfaces (Physics). --- Chemistry. --- Physical sciences --- Physics --- Surface chemistry --- Surfaces (Technology) --- Engineering—Materials. --- Nanoscience --- Nano science --- Nanoscale science --- Nanosciences --- Science --- Material science
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This book studies the collision, coalescence and deposition of nanoparticles in stagnation flames. With the help of synthesis experiments, in-situ laser diagnostics and molecular dynamics simulations, it investigates the growth of nanoparticles in flames and their deposition in boundary layers at a macroscopic flow field scale, as well as particle and molecular scale issues such as the interaction force between particles, how the collision rate is enhanced by attractive forces, and how the nano-scale coalescence process is influenced by the high surface curvature – all of which are crucial to understanding nanoparticle transport phenomena at high temperatures. The book also reports on a novel in-situ laser diagnostics phenomenon called phase-selective laser-induced breakdown spectroscopy and related applications for tracing gas-to-particle transitions and measuring local particle volume fractions in nano-aerosols.
Engineering. --- Thermodynamics. --- Heat engineering. --- Heat transfer. --- Mass transfer. --- Nanotechnology. --- Engineering Thermodynamics, Heat and Mass Transfer. --- Nanotechnology and Microengineering. --- Titanium dioxide. --- Nanoparticles. --- Anatase --- Brookite --- Octahedrite --- Titania (Chemical) --- Titanic acid anhydride --- Titanic oxide --- Titanium oxide --- Titanium white --- Nanostructured materials --- Particles --- Oxides --- Titanium compounds --- Chemistry, Physical and theoretical --- Dynamics --- Mechanics --- Physics --- Heat --- Heat-engines --- Quantum theory --- Construction --- Industrial arts --- Technology --- Molecular technology --- Nanoscale technology --- High technology --- Mass transport (Physics) --- Thermodynamics --- Transport theory --- Heat transfer --- Thermal transfer --- Transmission of heat --- Energy transfer --- Mechanical engineering