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This dissertation by Karl Rönnby investigates the atomic layer deposition (ALD) and chemical vapor deposition (CVD) techniques for producing thin films of Group 13 nitrides, such as aluminum nitride (AlN), gallium nitride (GaN), and indium nitride (InN). The research focuses on the computational chemistry modeling of the gas phase decomposition and surface adsorption processes of various precursors. The study examines the reactivity and efficiency of these processes, highlighting the challenges and potential alternatives for sustainable and large-scale production of these materials for semiconductor applications.
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This dissertation by Janella Salamania explores the role of defects in titanium aluminum nitride (Ti-Al-N) based thin films, which are used as hard coatings to enhance the durability and effectiveness of cutting tools. The research focuses on the synthesis of Ti-Al-N films through physical vapor deposition techniques and examines how various defects such as vacancies, dislocations, and planar defects influence the growth, structure, stability, and mechanical properties of the films. The study employs high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM) and atomistic simulations to analyze the defect structures. Findings reveal that the presence of defects can alter metal-metal and metal-nitrogen bonds, influence strain and compositional fluctuations, and facilitate phase transformations. The work provides insights into defect-based engineering strategies for optimizing the performance of Ti-Al-N thin films.
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This dissertation by Tun-Wei Hsu focuses on understanding and controlling the influence of ions in plasma on film growth during thin film deposition processes using physical vapor deposition (PVD) techniques. It examines magnetron sputtering and cathodic arc evaporation, emphasizing low-mass ion subplantation and heavy-mass ion irradiation. The research explores the correlation between nitrogen pressure and plasma properties, the effect of ionized species on film properties, and the use of synchronized substrate bias to enhance coating performance. The study provides insights into advanced coating techniques to improve tool durability and performance in cutting applications.
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This thesis by Arun Haridas Choolakkal, presented at Linköping University, explores the development of a chemical vapor deposition (CVD) process for creating conformal boron carbide thin films. These films are particularly useful as neutron converter materials in solid-state neutron detectors. The research utilizes triethylboron (TEB) as a single-source CVD precursor, focusing initially on low reaction rate deposition. Experiments demonstrated highly conformal films at temperatures ≤450°C, with promising results for detector applications. The study further investigates enhancing step coverage at higher temperatures by introducing diffusion additives. The CVD process was validated on carbon nanotube membranes, confirming the potential for even deposition without inducing defects. This work is aimed at advancing materials science for improved detector performance, targeting researchers and professionals in physics and engineering.
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Volcanoes. --- Volcans. --- Sedimentation and deposition. --- Sédimentation (géologie)
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"Each chapter covering environments of deposition will be divided into two sections. The first section will cover the characteristics of the modern setting, outlining the principal processes of erosion, transport and deposition. This will primarily be a geomorphological approach to sedimentology and environments. The second section will consider the products of the depositional environments in terms of what is preserved in the sedimentary record. This will be a stratigraphic approach to the products of different depositional environments. This approach is proposed to help draw a distinction between features that are important products of sedimentary processes in modern landscapes and the sedimentary products that will be preserved in the rock record. As an example, upland glacial processes create important sedimentary features in modern landscapes but are in regions of net degradation and will not be preserved in the longer-term rock record. The principle of using modern environments to interpret the sedimentary record will also be explored in more detail in terms of the limitations of the approach. Changes in the forms and diversity of plants and animals through time have very strongly impacted on sedimentary processes and products in both continental and marine environments. The differences between icehouse and greenhouse periods in Earth history also need to be taken into account when considering sedimentary environments. In particular, our current view of depositional environments is through the prism of the recent ice ages and many aspects of the greenhouse world would have looked very different. A simple uniformitarian' approach must therefore be used with care. Previous editions of the book made mention of these issues, but there will be more prominence to how changes in the planet through time impact on sedimentology"--
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Trees --- Atmospheric deposition. --- Nitrogen cycle. --- Forests and forestry. --- Forest declines. --- Effect of atmospheric nitrogen dioxide on.
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Atmospheric deposition. --- Forest declines. --- Forests and forestry. --- Nitrogen cycle. --- Trees --- Effect of atmospheric nitrogen dioxide on.
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This two-volume set provides an extensive review of the abundant past and recent literature on the atmospheric chemistry in the Mediterranean region. The books document the experience gained on the atmospheric composition over the Mediterranean basin and close areas after almost six decades of studies, starting from early studies of radioactive aerosol fallouts and intense desert dust events in the 1960s, aerosol samples collected during oceanographic cruises in the early 1980s and including discoveries from subsequent surface monitoring stations, intensive campaigns, satellite climatologies, laboratory studies, as well as chemistry-transport and climate models. Through ten thematic sections, the authors examine the sources and fates of atmospheric pollutants over the Mediterranean basin and what we know about their major impacts on air quality and health, on the radiative budget and climate, on marine chemistry and biogeochemistry. This overview not only considers the full cycle of both aerosol and reactive gases including emissions, transport, transformation, and sinks, but also addresses the main impacts of the regional atmospheric chemistry. The volumes are an initiative from the ending ChArMEx project that has federated many studies on those topics in the past decade, and update the scientific knowledge by integrating the ChArMEx and non-ChArMEx literature. The books are contributed by a large pool of well-known authors from the respective fields, mainly from France and Greece, but also from fourteen other countries. All chapters have been peer-reviewed by international scientific experts in the corresponding domains. Volume 1 provides background information on the Mediterranean atmosphere and focuses on the synoptic and dynamic conditions affecting pollutant concentrations over the Mediterranean basin, aerosol concentrations and variability, and reactive gas concentrations and variability. The targeted audience is the academic community working on atmospheric chemistry and its impacts on climate, air quality and marine biogeochemistry, especially teams having a special interest in the Mediterranean region, which includes many countries and institutes worldwide.
Atmospheric chemistry. --- Atmospheric deposition. --- Air pollutant deposition --- Atmospheric fallout --- Atmospheric pollutant deposition --- Deposition of air pollutants --- Deposition of atmospheric pollutants --- Fallout, Atmospheric --- Sedimentation and deposition --- Air --- Atmospheric science --- Chemistry, Physical and theoretical --- Pollution --- Environmental chemistry. --- Pollution. --- Physical geography. --- Environment. --- Environmental Chemistry. --- Earth System Sciences. --- Environmental Sciences. --- Balance of nature --- Biology --- Bionomics --- Ecological processes --- Ecological science --- Ecological sciences --- Environment --- Environmental biology --- Oecology --- Environmental sciences --- Population biology --- Geography --- Chemical pollution --- Chemicals --- Contamination of environment --- Environmental pollution --- Contamination (Technology) --- Asbestos abatement --- Bioremediation --- Environmental engineering --- Environmental quality --- Factory and trade waste --- Hazardous waste site remediation --- Hazardous wastes --- In situ remediation --- Lead abatement --- Pollutants --- Refuse and refuse disposal --- Chemistry, Environmental --- Chemistry --- Ecology --- Environmental aspects
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This reprint contains articles published in the Special Issue entitled "Assessing Atmospheric Pollution and Its Impacts on the Human Health" in the journal Atmosphere. The research focuses on the evaluation of atmospheric pollution by statistical methods on the one hand, and on the other hand, on the evaluation of the relationship between the level of pollution and the extent of its effect on the population's health, especially on pulmonary diseases.
Air pollution. --- Lungs --- Diseases. --- Pulmonary diseases --- Air --- Air contaminants --- Air pollutants --- Air pollution --- Air pollution control --- Air toxics --- Airborne pollutants --- Atmosphere --- Contaminants, Air --- Control of air pollution --- Pollutants, Air --- Toxics, Air --- Pollution --- Air quality --- Atmospheric deposition --- Control
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