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The book compiles scientific articles describing advances in nanomaterial synthesis and their application in water remediation. The publications treat diverse problems such as dye degradation, heavy metal ion, as well as radioactive element capture and sequestration. There are 10 original research articles and one review article. The latter proposes graphene/CNT and Prussian blue nanocomposites for radioactive 137-cesium extraction from aqueous media. All reports thoroughly characterize the nanomaterials post-synthesis and describe their catalytic, photocatalytic, or ion exchange activities in contaminated water. The dyes studied in the collection are azo dyes, i.e. methylene blue and orange, rhodamine B, phenolic dyes viz. bromophenol blue, and other dyes with sulfonyl groups. Extraction of radioactive elements, including cationic 137Cs+ and anionic 125I?, is also investigated. The omnipresence of ZnO nanoparticles in everyday products and their effects in wastewater are also evaluated. Layered double hydroxide are capable of capturing Ag ions, which then has a catalytic effect on dye degradation. The nanomaterials considered are varied, viz., graphene, CNT, Prussian blue, nanoporous carbon, layered double hydroxides, magnetite, ferrites, organic powders, polymer membranes, bacteria, and inorganic nanomaterials such as MnO and Ag. The book targets an interdisciplinary readership.
LDHs --- magnetic photocatalyst --- n/a --- bioremediation --- membrane --- BiOCl --- BiVO4 --- degradation --- agglomeration --- solvent vapor annealing --- nanoporous carbon --- nanocomposite --- Prussian blue --- stability --- silver nanomaterials --- adsorption --- wastewater --- desalination --- ZnO nanoparticles --- film --- magnetic performance --- metal-organic frameworks --- 137Cs+ selectivity --- nanomixtures --- water remediation --- photocatalytic activity --- adsorption properties --- magnetic extraction --- RGO --- structural regularity --- photocatalytic mechanism --- wastewater treatment --- 137-Cesium --- photocatalyst --- magnetic nanoparticles --- graphene --- radioactive iodine --- carbon nanotubes --- doping modification --- electrospinning --- radioactive contamination --- Mn–Zn ferrite --- mixed wastewater --- manganese oxide --- host–guest interaction --- bromophenol blue --- Dy3+ --- organic pollutants --- dye --- beta-cyclodextrin polymer --- polydopamine --- interaction --- dye removal --- adsorption models --- RhB photodegradation --- hydrothermal method --- supercapacitor --- Mn-Zn ferrite --- host-guest interaction
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The use of solid catalysts for the upgrade of renewable sources gives the opportunity to combine the two main cores of green chemistry, that is, on the one hand, the set-up of sustainable processes and, on the other, the use of biomass-derived materials. Solid catalysts have taken on a leading role in traditional petrochemical processes and could represent a key tool in new biorefinery-driven technologies.
biorefinery --- lignin --- citronellal --- biofuel production --- calcination temperature --- carbohydrates --- biomass valorization --- liquid phase reductive depolymerization --- terpenoids --- heterogeneous catalysis --- propylene glycol --- transition metals --- transfer hydrogenation --- acidic clays --- phenolic and aromatic compounds --- biofuels --- aqueous phase --- supported metals --- hybrid materials --- amination --- heterogeneous and homogeneous catalysts --- CuZn catalysts --- catalytic materials --- terpenes --- Lewis acids --- surface functional groups --- value-added products --- carbon nanotubes --- ethylene glycol --- biochar-supported metal catalysts --- calcination atmosphere --- xylitol --- alditol --- HMF --- biomass --- metal–organic frameworks (MOFs) --- hydrothermal carbonization --- solid-acid catalyst --- NMR --- solid base catalyst --- catalytic transfer hydrogenation --- surface functionalization --- transesterification --- biomass conversion --- hydrogen donors --- hydrogenolysis --- octahydroacridines --- solid acids
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The use of solid catalysts for the upgrade of renewable sources gives the opportunity to combine the two main cores of green chemistry, that is, on the one hand, the set-up of sustainable processes and, on the other, the use of biomass-derived materials. Solid catalysts have taken on a leading role in traditional petrochemical processes and could represent a key tool in new biorefinery-driven technologies.
biorefinery --- lignin --- citronellal --- biofuel production --- calcination temperature --- carbohydrates --- biomass valorization --- liquid phase reductive depolymerization --- terpenoids --- heterogeneous catalysis --- propylene glycol --- transition metals --- transfer hydrogenation --- acidic clays --- phenolic and aromatic compounds --- biofuels --- aqueous phase --- supported metals --- hybrid materials --- amination --- heterogeneous and homogeneous catalysts --- CuZn catalysts --- catalytic materials --- terpenes --- Lewis acids --- surface functional groups --- value-added products --- carbon nanotubes --- ethylene glycol --- biochar-supported metal catalysts --- calcination atmosphere --- xylitol --- alditol --- HMF --- biomass --- metal–organic frameworks (MOFs) --- hydrothermal carbonization --- solid-acid catalyst --- NMR --- solid base catalyst --- catalytic transfer hydrogenation --- surface functionalization --- transesterification --- biomass conversion --- hydrogen donors --- hydrogenolysis --- octahydroacridines --- solid acids
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The use of solid catalysts for the upgrade of renewable sources gives the opportunity to combine the two main cores of green chemistry, that is, on the one hand, the set-up of sustainable processes and, on the other, the use of biomass-derived materials. Solid catalysts have taken on a leading role in traditional petrochemical processes and could represent a key tool in new biorefinery-driven technologies.
biorefinery --- lignin --- citronellal --- biofuel production --- calcination temperature --- carbohydrates --- biomass valorization --- liquid phase reductive depolymerization --- terpenoids --- heterogeneous catalysis --- propylene glycol --- transition metals --- transfer hydrogenation --- acidic clays --- phenolic and aromatic compounds --- biofuels --- aqueous phase --- supported metals --- hybrid materials --- amination --- heterogeneous and homogeneous catalysts --- CuZn catalysts --- catalytic materials --- terpenes --- Lewis acids --- surface functional groups --- value-added products --- carbon nanotubes --- ethylene glycol --- biochar-supported metal catalysts --- calcination atmosphere --- xylitol --- alditol --- HMF --- biomass --- metal–organic frameworks (MOFs) --- hydrothermal carbonization --- solid-acid catalyst --- NMR --- solid base catalyst --- catalytic transfer hydrogenation --- surface functionalization --- transesterification --- biomass conversion --- hydrogen donors --- hydrogenolysis --- octahydroacridines --- solid acids --- biorefinery --- lignin --- citronellal --- biofuel production --- calcination temperature --- carbohydrates --- biomass valorization --- liquid phase reductive depolymerization --- terpenoids --- heterogeneous catalysis --- propylene glycol --- transition metals --- transfer hydrogenation --- acidic clays --- phenolic and aromatic compounds --- biofuels --- aqueous phase --- supported metals --- hybrid materials --- amination --- heterogeneous and homogeneous catalysts --- CuZn catalysts --- catalytic materials --- terpenes --- Lewis acids --- surface functional groups --- value-added products --- carbon nanotubes --- ethylene glycol --- biochar-supported metal catalysts --- calcination atmosphere --- xylitol --- alditol --- HMF --- biomass --- metal–organic frameworks (MOFs) --- hydrothermal carbonization --- solid-acid catalyst --- NMR --- solid base catalyst --- catalytic transfer hydrogenation --- surface functionalization --- transesterification --- biomass conversion --- hydrogen donors --- hydrogenolysis --- octahydroacridines --- solid acids
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This book is a collection of 13 innovative papers describing the state of the art and the future perspectives in solid-phase extraction covering several analytical fields prior to the use of gas or liquid chromatographic analysis. New sorptive materials are presented including carbon nanohorn suprastructures on paper support, melamine sponge functionalized with urea–formaldehyde co-oligomers, chiral metal–organic frameworks, UiO-66-based metal–organic frameworks, and fabric phase sorptive media for various applications. Solid-phase extraction can be applied in several formats aside from the conventional cartridges or mini-column approach, e.g., online solid-phase extraction, dispersive solid-phase microextraction, and in-syringe micro-solid-phase extraction can be very helpful for analyte pre-concentration and sample clean-up. Polycyclic musks in aqueous samples, 8-Nitroguanine in DNA by chemical derivatization antibacterial diterpenes from the roots of salvia prattii, perfluoroalkyl substances (PFASs) in aater samples by bamboo charcoal-based SPE, parabens in environmental water samples, benzotriazoles as environmental pollutants, organochlorine pesticide residues in various fruit juices and water samples and synthetic peptide purification are among the applications cited in this collection. All these outstanding contributions highlight the necessity of this analytical step, present the advantages and disadvantages of each method and focus on the green analytical chemistry guidelines that have to be fulfilled in current analytical practices.
method validation --- nitrated DNA lesion --- benzotriazoles --- microextraction --- LC-MS/MS --- perfluoroalkyl acids --- antibacterial diterpenes --- in-house loaded SPE --- isotope-dilution --- polycyclic musks --- wastewater --- peptide --- HPLC-DAD --- chiral compounds --- derivatization --- extraction --- water --- enantiomeric excess --- sample preparation --- metal-organic frameworks --- solid-phase extraction --- FPSE --- melamine sponge --- preparative high-performance liquid chromatography --- GC–MS/MS --- solid phase peptide synthesis --- HPLC-PDA --- Salvia prattii --- in-syringe micro solid-phase extraction --- organochlorine pesticides --- hydrophilic solid-phase extraction --- response surface methodology --- IBD --- graphene --- sorptive phase --- paper --- liquid chromatography–tandem mass spectrometry --- carbon nanohorns --- gradient elution --- peroxynitrite --- bamboo charcoal --- gas chromatography-mass spectrometry --- environmental samples --- parabens --- solid phase extraction (SPE) --- preparative purification --- antidepressants --- online solid-phase extraction --- organic pollutants --- urea-formaldehyde co-oligomers --- personal care products --- dispersive solid-phase extraction --- fabric phase sorptive extraction --- analyte partitioning
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