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Nanostructures. --- Magnets. --- Magnetic materials --- Magnetics --- Magnetism --- Solenoids --- Nanoscience --- Physics
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Molecular magnetism is explored as an alternative to conventional solid-state magnetism as the basis for ultrahigh-density memory materials with extremely fast processing speeds. In particular single-molecule magnets (SMM) are in the focus of current research, both because of their intrinsic magnetization properties, as well as because of their potential use in molecular spintronic devices. SMMs are fascinating objects on the example of which one can explain many concepts.Single-Molecule Magnets: Molecular Architectures and Building Blocks for Spintronics starts with a general introduction to single-molecule magnets (SMM), which helps readers to understand the evolution of the field and its future. The following chapters deal with the current synthetic methods leading to SMMs, their magnetic properties and their characterization by methods such as high-field electron paramagnetic resonance, paramagnetic nuclear magnetic resonance, and magnetic circular dichroism. The book closes with an overview of radical-bridged SMMs, which have shown application potential as building blocks for high-density memories.
Molecules --- Magnets. --- Molécules --- Aimants. --- Magnetic properties. --- Propriétés magnétiques.
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Development of new techniques for the non-destructive characterization of superconducting materials becomes challenging. Several magnetometry techniques exist but do not accommodate sizable samples. Other magnetometers are designed for the characterization of large samples in a non-destructive way but require specific working conditions. In this master thesis we designed and realized a new magnetic torque measurement system able to characterize magnetic samples of approximately 1 cm$^3$ at both room and cryogenic temperatures. This device can be used for torque magnetometry with an intermediate sensitivity between miniature torque magnetometers designed to work at cryogenic temperature and commercial torquemeters poorly adapted to extreme conditions. The torque sensing system is based on four piezoresistive strain gauges glued on a cylindrical transmission shaft. The measurement system was first calibrated at room temperature using a small coil fed with a DC current. Then the system was tested on three different magnetic samples in order to measure their magnetic moment under crossed fields conditions: a neodymium permanent magnet, a bulk superconducting sample and a stack of superconducting tapes. The results were shown to be in a good agreement with those observed from literature. In particular, the demagnetization effect was highlighted under these crossed fields conditions. Such conditions can be encountered for instance in rotating machines applications.
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