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Chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors.
Chemistry. --- Inorganic chemistry. --- Physical chemistry. --- Chemistry, Physical and theoretical. --- Inorganic Chemistry. --- Physical Chemistry. --- Theoretical and Computational Chemistry. --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Inorganic chemistry --- Inorganic compounds --- Physical sciences --- Chemistry, inorganic. --- Chemistry, Physical organic. --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical
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Christopher B. Caputo and Douglas W. Stephan--Non-conventional Lewis Acids and Bases in Frustrated Lewis Pair Chemistry Andreas Phanopoulos, Nicholas J. Long, and Philip W. Miller--Triphosphine Ligands: Coordination Chemistry and Recent Catalytic Applications Robert H. Crabtree--Sigma Bonds as Ligand Donor Groups in Transition Metal Complexes Malcolm L.H. Green and Gerard Parkin--The Covalent Bond Classification Method and Its Application to Compounds That Feature 3-Center 2-Electron Bonds Ghenwa Bouhadir, Didier Bourissou--Coordination of Lewis Acids to Transition Metals:Z-Type Ligands.
Chemistry. --- Inorganic chemistry. --- Physical chemistry. --- Chemistry, Physical and theoretical. --- Inorganic Chemistry. --- Theoretical and Computational Chemistry. --- Physical Chemistry. --- Chemistry, inorganic. --- Chemistry, Physical organic. --- Physical sciences --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Inorganic chemistry --- Chemistry --- Inorganic compounds --- Chemistry, Inorganic. --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry
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The field of atomic clusters continues to attract great interest amongst physicists and chemists alike. This is in part due to their intrinsic properties and potential industrial applications. The first part of Binary Clusters is devoted to recent developments in experimental techniques, the second part covers a variety of theoretical approaches. Different theoretical methods based on group/graph theories and quantum chemical computational methods as well as various spectroscopy techniques (such as mass, laser, infrared, photoelectron etc.) are applied to the determination of the existence of geometrical and electronic structures, chemical bonding phenomena, and the thermodynamic stabilities of several classes of binary clusters. All chapters within this review volume have been contributed by experts in chemistry, physics, and material sciences based at the University of Leuven, Belgium. This book is aimed at professionals and students working in cluster science.
Chemistry. --- Inorganic chemistry. --- Physical chemistry. --- Chemistry, Physical and theoretical. --- Theoretical and Computational Chemistry. --- Physical Chemistry. --- Inorganic Chemistry. --- Microclusters. --- Microphysics. --- Atomic clusters --- Clusters, Atomic --- Clusters, Molecular --- Microcluster physics --- Molecular clusters --- Physical sciences --- Physics --- Atoms --- Microphysics --- Chemistry, Physical organic. --- Chemistry, inorganic. --- Inorganic chemistry --- Chemistry --- Inorganic compounds --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry
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This important book describes the basic principles of astrochemistry—an interdisciplinary field combining astronomy, physics, and chemistry—with particular emphasis on its physical and chemical background. Chemical processes in diffuse clouds, dense quiescent molecular clouds, star-forming regions, and protoplanetary disks are discussed. A brief introduction to molecular spectroscopy and observational techniques is also presented. These contents provide astronomers with a comprehensive understanding of how interstellar matter is evolved and brought into stars and planets, which is ultimately related to the origin of the solar system. The subject matter will also be understandable and useful for physical chemists who are interested in exotic chemical processes occurring in extreme physical conditions. The book is a valuable resource for all researchers beginning at the graduate level.
Physics. --- Physical chemistry. --- Planetology. --- Observations, Astronomical. --- Astronomy --- Astronomy, Observations and Techniques. --- Physical Chemistry. --- Observations. --- Astronomical observations --- Observations, Astronomical --- Chemistry, Physical organic. --- Planetary sciences --- Planetology --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Astronomy—Observations. --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry
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A text- and exercise book for physical chemistry students! This book deals with the fundamental aspects of physical chemistry taught at the undergraduate level in chemistry and the engineering sciences in a compact and practice-oriented form. Numerous problems and detailed solutions offer the possibility of an in-depth reflection of topics like chemical thermodynamics and kinetics, atomic structure and spectroscopy. Every chapter starts with a recapitulation of important background information, before leading over to representative exercises and problems. Detailed descriptions systematically present and explain the solutions to the problems, so that readers can carefully check their own solutions and get clear-cut introductions on how to approach similar problems systematically. The book addresses students at the (upper) undergraduate level, as well as tutors and teachers. It is a rich source of exercises for exam preparation and can be used alongside classical textbooks. Furthermore it can serve teachers and tutors for the conception of their lessons. Its well-thought-through presentation, structure and design make the book appeal to everybody who wants to succeed with the physical chemistry lessons and exercises. .
Chemistry. --- Spectroscopy. --- Physical chemistry. --- Electrochemistry. --- Thermodynamics. --- Physical Chemistry. --- Spectroscopy/Spectrometry. --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Analysis, Spectrum --- Spectra --- Spectrochemical analysis --- Spectrochemistry --- Spectroscopy --- Chemistry, Physical organic. --- Chemistry, Physical and theoretical --- Dynamics --- Mechanics --- Physics --- Heat --- Heat-engines --- Quantum theory --- Chemistry, Analytic --- Interferometry --- Optics --- Radiation --- Wave-motion, Theory of --- Absorption spectra --- Light --- Spectroscope --- Physical sciences --- Chemistry, Physical organic --- Chemistry, Organic --- Qualitative --- Spectrometry --- Examinations --- Chemistry --- Analytical chemistry
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Chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience.
Chemistry. --- Inorganic chemistry. --- Organometallic chemistry. --- Physical chemistry. --- Physical Chemistry. --- Organometallic Chemistry. --- Inorganic Chemistry. --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry, Organometallic --- Metallo-organic chemistry --- Inorganic chemistry --- Chemistry, Physical organic. --- Chemistry, Organic. --- Chemistry, inorganic. --- Organic chemistry --- Chemistry --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Inorganic compounds --- Chemical structure. --- Organometallic chemistry .
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The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
Chemistry. --- Physical chemistry. --- Nanotechnology. --- Optical materials. --- Electronic materials. --- Physical Chemistry. --- Optical and Electronic Materials. --- Nanotechnology and Microengineering. --- Photoluminescence. --- Electroluminescence. --- Destriau effect --- Light --- Luminescence --- Semiconductors --- Chemistry, Physical organic. --- Engineering. --- Construction --- Industrial arts --- Technology --- Optics --- Materials --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Molecular technology --- Nanoscale technology --- High technology --- Electronic materials --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry
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This book focuses on photoswitches. The objective of the book is to introduce researchers and graduate course students who are interested in "photon-working switches" not only to the fundamentals but also to the latest research being carried out in this field. Light can reach a target substrate without any physical contact to deliver energy. The energy can induce changes in the structure of the molecules included in the substrate so that its properties and functions are made switchable by light irradiation. When a substrate is able to revert to its original state, this system can be regarded as a "photon-working switch". The terms "photon-working switches" or "photoswitches" are almost equivalent in meaning to "photochromism"; however, they focus on the "switching of functions" of chemical species rather than their "reversible transformation". Most of the authors of this volume are members of PHENICS, an international research group on organic molecular photoswitches composed of research institutions from France, Japan, Russia, China and Germany. Since its inception in 2008, PHENICS has promoted active research to develop the field. This book commemorates the group's eighth year of collaborative research.
Chemistry. --- Physical chemistry. --- Polymers. --- Optical materials. --- Electronic materials. --- Physical Chemistry. --- Optical and Electronic Materials. --- Polymer Sciences. --- Photochromism. --- Photochemistry --- Chemistry, Physical organic. --- Polymere --- Polymeride --- Polymers and polymerization --- Macromolecules --- Optics --- Materials --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Polymers . --- Electronic materials --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry
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This book presents an overview of recent advances in our understanding of the genesis of diamonds and the associated phases. It is divided into three main parts, starting with an introduction to the analysis of diamond inclusions to infer the formation processes. In turn, the second part of the book presents high-pressure experimental studies in mantle diamond-parental mineral systems with representative multicomponent boundary compositions. The experimental syngenesis phase diagrams provided reveal the physicochemical mechanisms of diamond nucleation and substantiate the mantle-carbonatite concept of the genesis of diamonds and associated phases. Lastly, the book describes the genetic classification of diamond-hosted mineral inclusions and experimentally determined RE “mineral-parental melt” partition coefficients. The physicochemical experimental evidence presented shows the driving forces behind the fractional evolution of the mantle magmas and diamond-parental melts. Given the depth and breadth of its coverage, the book offers researchers essential new insights into the ways diamonds and associated minerals and rocks are naturally created.
Earth sciences. --- Physical chemistry. --- Geochemistry. --- Mineralogy. --- Earth Sciences. --- Physical Chemistry. --- Diamonds. --- Native element minerals --- Precious stones --- Chemistry, Physical organic. --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Physical geology --- Crystallography --- Minerals --- Chemical composition of the earth --- Chemical geology --- Geological chemistry --- Geology, Chemical --- Chemistry --- Earth sciences --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry
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This thesis demonstrates the novel magnetic functionalities in cyanido-bridged metal assemblies, and as such appeals to readers in the field of materials science. The utilization of octacyanidometalates as building blocks enables the observation of (i) photo-induced magnetization due to a light-induced spin-crossover in an iron octacyanidoniobate-based assembly, (ii) photo-induced magnetization with a two-step spin-crossover behavior in an iron octacyanidoniobate-based material, and (iii) the coexistence of super-ionic conductivity and metamagnetism in a manganese-octacyanoniobate system. These multi-functionalities are achieved by incorporating a spin-crossover moiety or a hydrogen-bonding network into a cyanido-bridged network structure with a strong magnetic interaction. In particular, in light-induced spin-crossover magnets, a magnetically non-ordered state can be altered to a magnetically ordered state by photo-irradiation, which is one of the attractive mechanisms for novel optical switching devices.
Chemistry. --- Inorganic chemistry. --- Physical chemistry. --- Magnetism. --- Magnetic materials. --- Optical materials. --- Electronic materials. --- Inorganic Chemistry. --- Magnetism, Magnetic Materials. --- Optical and Electronic Materials. --- Physical Chemistry. --- Chemistry, inorganic. --- Chemistry, Physical organic. --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Inorganic chemistry --- Chemistry --- Inorganic compounds --- Optics --- Materials --- Mathematical physics --- Physics --- Electricity --- Magnetics --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Electronic materials
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