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This work begins with the first principles of bonding, structure and solid state chemistry, and can be appreciated by non-specialists. The study is aided by carefully prepared problems with fully worked solutions. It provides a suite of computer programs devised especially for the book.

Solid state chemistry. --- Chemical structure. --- Chemical bonds.

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This book highlights major achievements made in the last five years concerning sustainable C(sp3)-H bond functionalization and offers a promising and emerging tool-kit for organic synthesis. The book is divided into three chapters demonstrating key advances in C(sp3)-H bond functionalization. Chapter 1 reviews transition-metal-catalyzed C(sp3)-H bond functionalization using different directing groups, while Chapter 2 addresses the new methods of transition-metal-catalyzed and metal-free C(sp3)-H bond functionalization without directing groups, in addition to briefly highlighting redox-neutral C(sp3)-H bond functionalization. In closing, Chapter 3 examines visible-light photoredox catalysis, an emerging and highly sustainable C(sp3)-H bond functionalization strategy. The book offers an intriguing and useful reference guide for a broad readership working and/or interested in the fields of organic, organometallic, and green chemistry.

Chemical engineering. --- Organic Chemistry --- Chemistry --- Physical Sciences & Mathematics --- Hydrocarbons. --- Chemical bonds. --- Bonds, Chemical --- Chemical structure --- Chemistry, Physical and theoretical --- Overlap integral --- Quantum chemistry --- Valence (Theoretical chemistry) --- Organic compounds --- Chemistry, Organic. --- Catalysis. --- Organometallic Chemistry. --- Industrial Chemistry/Chemical Engineering. --- Activation (Chemistry) --- Surface chemistry --- Organic chemistry --- Chemistry, Industrial --- Engineering, Chemical --- Industrial chemistry --- Engineering --- Chemistry, Technical --- Metallurgy --- Organometallic chemistry . --- Chemistry, Organometallic --- Metallo-organic chemistry --- Chemistry, Organic --- Organometallic chemistry.

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Arne Haaland and Mats Tilset--Lewis and Kossel’s Legacy: Structure and Bonding in Main-Group Compounds Paul L.A. Popelier--Quantum Chemical Topology M. Kohout--Electron Pairs in Position Space Sason Shaik, David Danovich, Benoit Braida, Wei Wu, and Philippe C. Hiberty--New Landscape of Electron-Pair Bonding: Covalent, Ionic, and Charge-Shift Bonds Bernard Silvi--The Relevance of the ELF Topological Approach to the Lewis, Kossel, and Langmuir Bond Model Andrés Falceto and Santiago Alvarez--Comparison of the Cr–Cr Quadruple and Quintuple Bonding Mechanisms.

Chemistry. --- Inorganic chemistry. --- Physical chemistry. --- Chemistry, Physical and theoretical. --- Inorganic Chemistry. --- Theoretical and Computational Chemistry. --- Physical Chemistry. --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Inorganic chemistry --- Chemistry, inorganic. --- Chemistry, Physical organic. --- Physical sciences --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Chemistry --- Inorganic compounds --- Chemical bonds. --- Bonds, Chemical --- Chemical structure --- Overlap integral --- Quantum chemistry --- Valence (Theoretical chemistry) --- Chemistry, Inorganic.

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In 1912, the Chemistry Nobel Prize was awarded for the discovery of the so-called Grignard reagents. Nowadays, many transition metal variants are developed to modify reactivity and selectivity of the C-C bond formation reaction. The Grignard reaction is one of the fundamental organometallic reactions, often used in alcohol syntheses. With transition metals like iron, cobalt and nickel or with noble metals like copper, silver and palladium, modern Grignard reagents can be designed in reactivity, selectivity and functional group tolerance. This book, written by international experts, presents an overview on timely Grignard chemistry involving transition metals.

Grignard reagents. --- Chemical tests and reagents. --- Transition metal catalysts. --- Chemical bonds. --- Bonds, Chemical --- Chemical structure --- Chemistry, Physical and theoretical --- Overlap integral --- Quantum chemistry --- Valence (Theoretical chemistry) --- Metal catalysts --- Chemical reagents --- Reagents, Chemical --- Indicators and test-papers --- Grignard reaction --- Chemical tests and reagents --- Organomagnesium compounds --- Grignard Reaction. --- Organic Chemistry. --- Reactivity. --- Transition Metals.

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This second edition was updated to include some of the recent developments, such as “increased-valence” structures for 3-electron-3-centre bonding, benzene, electron conduction and reaction mechanisms, spiral chain O4 polymers and recoupled-pair bonding. The author provides qualitative molecular orbital and valence-bond descriptions of the electronic structures for primarily electron-rich molecules, with strong emphasis given to the valence-bond approach that uses “increased-valence” structures. He describes how “long-bond” Lewis structures as well as standard Lewis structures are incorporated into “increased-valence” structures for electron-rich molecules. “Increased-valence” structures involve more electrons in bonding than do their component Lewis structures, and are used to provide interpretations for molecular electronic structure, bond properties and reactivities. Attention is also given to Pauling “3-electron bonds”, which are usually diatomic components of “increased-valence” structures for electron-rich molecules.

Physical & Theoretical Chemistry --- Chemistry --- Physical Sciences & Mathematics --- Chemical bonds. --- Bonds, Chemical --- Chemical structure --- Chemistry, Physical and theoretical --- Overlap integral --- Quantum chemistry --- Valence (Theoretical chemistry) --- Chemistry. --- Chemistry, Organic. --- Theoretical and Computational Chemistry. --- Atomic/Molecular Structure and Spectra. --- Organic Chemistry. --- Organic chemistry --- Physical sciences --- Chemistry, Physical and theoretical. --- Atomic structure  . --- Molecular structure . --- Organic chemistry. --- Structure, Molecular --- Structural bioinformatics --- Structure, Atomic --- Atomic theory --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry