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For decades gas chromatography has been and will remain an irreplaceable analytical technique in many research areas for both quantitative analysis and qualitative characterization/identification, which is still supplementary with HPLC. This book highlights a few areas where significant advances have been reported recently and/or a revisit of basic concepts is deserved. It provides an overview of instrumental developments, frontline and modern research as well as practical industrial applications. The topics include GC-based metabolomics in biomedical, plant and microbial research, natural products as well as characterization of aging of synthetic materials and industrial monitoring, which are contributions of several experts from different disciplines. It also contains best hand-on practices of sample preparation (derivatization) and data processing in daily research. This book is recommended to both basic and experienced researchers in gas chromatography.
Mass spectrometry. --- Mass spectra --- Mass spectrograph --- Mass spectroscopy --- Mass spectrum analysis --- Mass (Physics) --- Nuclear spectroscopy --- Spectrum analysis --- Physical Sciences --- Engineering and Technology --- Chemistry --- Analytical Chemistry --- Physical Organic Chemistry
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The second edition of "The Chemistry of the Superheavy Elements" provides a complete coverage of the chemistry of a series of elements beginning with atomic number 104 – the transactinides or superheavy elements – including their nuclear properties and production in nuclear reactions at heavy-ion accelerators. The contributors to this work include many renowned scientists who, during the last decades, have made vast contributions towards understanding the physics and chemistry of these elusive elements, both experimentally and theoretically. The main emphasis here is on demonstrating the fascinating studies involved in probing the architecture of the Periodic Table at its uppermost end, where relativistic effects drastically influence chemical properties. All known chemical properties of these elements are described together with the experimental techniques applied to study these short-lived man-made elements one atom-at-a-time. The status of theoretical chemistry and of empirical models is presented as well as aspects of nuclear physics. In addition, one chapter outlines the meanderings in this field from a historical perspective and the search for superheavy elements in Nature.
Chemistry. --- Nuclear chemistry. --- Nuclear physics. --- Physical organic chemistry. --- Chemistry, Nuclear --- Chemistry, Physical organic --- Atomic nuclei --- Atoms, Nuclei of --- Nucleus of the atom --- Physical chemistry. --- Heavy ions. --- Hadrons. --- Nuclear Chemistry. --- Nuclear Physics, Heavy Ions, Hadrons. --- Physical Chemistry. --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Physical sciences --- Physics --- Chemistry, Physical organic. --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Ions --- Superheavy elements.
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Kinetic studies have traditionally being extremely useful in characterizing several physical and chemical phenomena in organic, inorganic and metallic systems. It provides valuable qualitative, quantitative and kinetic information on phase transformations, solid state precipitation, crystallization, oxidation and decomposition. Unfortunately, no single reference comprehensively presents nonisothermal kinetic analysis method for the study of complex processes, determining the actual mechanism and kinetic parameters. This book provides a new method for nonisothermal kinetics and its application in heterogeneous solid state processes. In the backdrop of limitations in existing methods, the book presents a brief review of the widely used isothermal and nonisothermal kinetic analysis methods.
Physical organic chemistry. --- Nanotechnology. --- Surfaces (Physics) --- Molecular technology --- Nanoscale technology --- Chemistry, Physical organic --- Materials science. --- Physical chemistry. --- Materials Science. --- Characterization and Evaluation of Materials. --- Physical Chemistry. --- Physics --- Surface chemistry --- Surfaces (Technology) --- Chemistry, Organic --- Chemistry, Physical and theoretical --- High technology --- Surfaces (Physics). --- Chemistry, Physical organic. --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Material science --- Physical sciences --- Chemical kinetics.
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After his first book on the topic "Specific Intermolecular Interactions of Organic Compounds", Baev extends in this book the development of the thermodynamic theory of specific intermolecular interactions to a wider spectrum of nitrogenated and bioorganic compounds: amino alcohols, amino acids, peptides and urea derivatives. The fundamentals of an unconventional approach to the theory of H-bonding and specific interactions are formulated based on a concept of pentacoordinated carbon atoms. New types of hydrogen bonds and specific interactions are substantiated and on the basis of the developed methodology their energies are determined. The new concept of the extra stabilizing effect of isomeric methyl groups on the structure and stability of nitrogenated organic molecules and bioorganic compounds is introduced and the destabilization action on specific interactions is outlined.
Physical organic chemistry. --- Bioorganic chemistry. --- Bio-organic chemistry --- Biological organic chemistry --- Chemistry, Physical organic --- Chemistry. --- Physical chemistry. --- Chemistry, Physical and theoretical. --- Theoretical and Computational Chemistry. --- Bioorganic Chemistry. --- Physical Chemistry. --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Biochemistry --- Chemistry, Physical organic. --- Physical sciences --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry
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This thesis introduces a series of novel, non-conjugated polyarylether hosts that are not subject to the triplet-energy limitations of traditional conjugated polymer hosts. As a result of this major breakthrough, the long-standing problem of triplet energy back transfer has now been overcome, making it possible to design high-efficiency electrophosphorescent polymers (PhPs), especially the blue and all-phosphorescent white ones. In addition, the author proposes a spiro-linked hyperbranched architecture for PhPs to inhibit the undesired triplet energy back transfer process in low triplet-energy hosts. The work in this thesis provides vital new insights into the design of PhPs and has led to several publications in high-profile journals.
Polymers. --- Polyarylethers. --- Organic electrochemistry. --- Polymere --- Polymeride --- Polymers and polymerization --- Macromolecules --- Electro-organic chemistry --- Electroorganic chemistry --- Electrochemistry --- Physical organic chemistry --- Aromatic polyethers --- Plastics --- Polyethers --- Optical materials. --- Surfaces (Physics). --- Polymer Sciences. --- Optical and Electronic Materials. --- Optics, Lasers, Photonics, Optical Devices. --- Characterization and Evaluation of Materials. --- Physics --- Surface chemistry --- Surfaces (Technology) --- Optics --- Materials --- Polymers . --- Electronic materials. --- Lasers. --- Photonics. --- Materials science. --- Material science --- Physical sciences --- New optics --- Light amplification by stimulated emission of radiation --- Masers, Optical --- Optical masers --- Light amplifiers --- Light sources --- Optoelectronic devices --- Nonlinear optics --- Optical parametric oscillators --- Electronic materials
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This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy. .
Physical organic chemistry. --- Chemistry. --- Spectrum analysis. --- Analysis, Spectrum --- Spectra --- Spectrochemical analysis --- Spectrochemistry --- Spectroscopy --- Chemistry, Physical organic --- Spectroscopy. --- Physical chemistry. --- Chemistry, Physical and theoretical. --- Atomic structure. --- Molecular structure. --- Spectra. --- Physical Chemistry. --- Atomic/Molecular Structure and Spectra. --- Theoretical and Computational Chemistry. --- Spectroscopy/Spectrometry. --- Physical sciences --- Chemistry, Analytic --- Interferometry --- Optics --- Radiation --- Wave-motion, Theory of --- Absorption spectra --- Light --- Spectroscope --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Qualitative --- Chemistry, Physical organic. --- Spectrometry --- Atomic structure . --- Molecular structure . --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Structure, Molecular --- Chemical structure --- Structural bioinformatics --- Structure, Atomic --- Atomic theory --- Analytical chemistry --- Chemical reactions. --- Hydrogen. --- Rydberg states.
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The Polymer Blends Handbook is a fundamental reference work on polymer blends, covering all aspects: science, engineering, technology and application. It will appeal to anyone working in the field of blends, researchers as well as engineers. The Handbook is designed to be the source of information on all aspects of polymer blends. To this end the Editors have put together an international group of highly respected contributors, each an expert in his chosen subjects.
Chemistry. --- Physical chemistry. --- Polymers. --- Chemical engineering. --- Amorphous substances. --- Complex fluids. --- Materials science. --- Polymer Sciences. --- Soft and Granular Matter, Complex Fluids and Microfluidics. --- Characterization and Evaluation of Materials. --- Physical Chemistry. --- Industrial Chemistry/Chemical Engineering. --- Chemistry, Industrial --- Engineering, Chemical --- Industrial chemistry --- Engineering --- Chemistry, Technical --- Metallurgy --- Polymere --- Polymeride --- Polymers and polymerization --- Macromolecules --- Physical sciences --- Material science --- Complex liquids --- Fluids, Complex --- Amorphous substances --- Liquids --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Soft condensed matter --- Surfaces (Physics). --- Chemistry, Physical organic. --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Physics --- Surface chemistry --- Surfaces (Technology) --- Physical organic chemistry. --- Polymers . --- Soft condensed matter. --- Materials --- Chemistry, Technical. --- Soft and Granular Matter. --- Characterization and Analytical Technique. --- Industrial Chemistry. --- Analysis. --- Chemical technology --- Technical chemistry --- Technology --- Chemical engineering --- Matter, Soft (Condensed matter) --- Matter, Soft condensed --- Soft matter (Condensed matter) --- Condensed matter --- Complex fluids
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