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Ligands. --- Metal ions. --- Molecular sieves.

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"This is presented in a concise yet comprehensive manner to those wanting to know more about the technique in general as opposed to advanced sample specific procedures/applications".

Secondary ion mass spectrometry. --- Spectrométrie de masse des ions secondaires --- Spectrométrie de masse des ions secondaires.

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Metal ions play key roles in biology. Many are essential for catalysis, for electron transfer and for the fixation, sensing, and metabolism of gases. Others compete with those essential metal ions or have toxic or pharmacological effects.This book is structured around the periodic table and focuses on the control of metal ions in cells. It addresses the molecular aspects of binding, transport and storage that ensure balanced levels of the essential elements. Organisms have also developed mechanisms to deal with the non-essential metal ions. However, through new uses and manufacturing processes, organisms are increasingly exposed to changing levels of both essential and non-essential ions in new chemical forms. They may not have developed defenses against some of these forms (such as nanoparticles).Many diseases such as cancer, diabetes and neurodegeneration are associated with metal ion imbalance. There may be a deficiency of the essential metals, overload of either essential or non-essential metals or perturbation of the overall natural balance.This book is the first to comprehensively survey the molecular nature of the overall natural balance of metal ions in nutrition, toxicology and pharmacology. It is written as an introduction to research for students and researchers in academia and industry and begins with a chapter by Professor R J P Williams FRS.

Metals in the body --- Cell physiology --- Metal ions

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There have been many demonstrations, particularly for magnetic impurity ions in crystals, that spin-Hamiltonians are able to account for a wide range of experimental results in terms of much smaller numbers of parameters. Yet they were originally derived from crystal field theory, which contains a logical flaw; electrons on the magnetic ions are distinguished from those on the ligands. Thus there is a challenge: to replace crystal field theory with one of equal or greater predictive power that is based on a surer footing. The theory developed in this book begins with a generic Hamiltonian, one that is common to most molecular and solid state problems and that does not violate the symmetry requirements imposed on electrons and nuclei. Using a version of degenerate perturbation theory due to Bloch and the introduction of Wannier functions, projection operators, and unitary transformations, Stevens shows that it is possible to replace crystal field theory as a basis for the spin-Hamiltonians of single magnetic ions and pairs and lattices of magnetic ions, even when the nuclei have vibrational motion.The power of the method is further demonstrated by showing that it can be extended to include lattice vibration and conduction by electron hopping such as probably occurs in high-Tc superconductors. Thus Stevens shows how an apparently successful ad hoc method of the past can be replaced by a much more soundly based one that not only incorporates all the previous successes but appears to open the way to extensions far outside the scope of the previously available methods. So far only some of these have been explored. The book should therefore be of great interest to all physicists and chemists concerned with understanding the special properties of molecules and solids that are imposed by the presence of magnetic ions.Originally published in 1997.The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These editions preserve the original texts of these important books while presenting them in durable paperback and hardcover editions. The goal of the Princeton Legacy Library is to vastly increase access to the rich scholarly heritage found in the thousands of books published by Princeton University Press since its founding in 1905.

Crystal field theory. --- Hamiltonian systems. --- Magnetic ions. --- SCIENCE / Physics / General. --- Ions --- Nuclear magnetism --- Hamiltonian dynamical systems --- Systems, Hamiltonian --- Differentiable dynamical systems --- Complex compounds --- Coordination compounds --- Transition metals

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Radiation shielding. --- Monte Carlo method. --- Extraterrestrial radiation. --- Light ions. --- Spacecraft design. --- Lunar exploration.