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In his thesis Fluorescence in Bio-inspired Nanotechnology, Jonas Hannestad describes the evolving field of DNA nanotechnology in a lucid and easily accessible way. A central theme in the thesis is how biological structures and mechanisms constitute a basis for the design of novel technologies. Hannestad discusses how self-assembled, nanometer-scale DNA constructs can be functionalized using fluorescent labeling. In particular, he highlights how applications are based on fluorescence resonance energy transfer (FRET). Another important contribution is the development of a lipid monolayer platform for the step-by-step assembly of DNA nanoconstructs. The work in the thesis is based on five peer-reviewed papers published in high-profile journals, all of which involve major contributions from the author.
Nanobiotechnology --- Fluorescence --- Chemistry --- Physical Sciences & Mathematics --- Physical & Theoretical Chemistry --- Fluorescence. --- Nanotechnology. --- Molecular technology --- Nanoscale technology --- Chemistry. --- Physical chemistry. --- Nanochemistry. --- Physical Chemistry. --- High technology --- Luminescence --- Radioactivity --- Chemistry, Physical organic. --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Nanoscale chemistry --- Chemistry, Analytic --- Nanoscience --- Analytical chemistry --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Nanobiotechnology.
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In this thesis, Till Cremer investigates the bulk properties of ionic liquids (IL), the IL/vacuum interface and the IL/solid interface. For these studies the author primarily uses angle-resolved X-ray photoelectron spectroscopy under ultrahigh vacuum conditions. ILs represent a class of materials with unique physico-chemical properties. Many applications take advantage of the extremely low vapor pressure of aprotic ILs to fabricate permanent, non-volatile liquid coatings on solid materials. The author focuses on issues related to thin IL coatings, in particular concerning new catalytic concepts such as the supported ionic liquid phase (SILP) and solid catalyst with ionic liquid layer (SCILL) systems. Till Cremer presents a number of fundamental contributions to the new field of "Ionic Liquid Surface and Interface Science". Highlights are his results concerning anion/cation-interactions and the growth of ultrathin layers of ionic liquids on various substrates in the context of supported ionic liquid catalysis. His results have significantly contributed to the present level of understanding in the field and accordingly he is author and coauthor of ten publications on the topic in high-ranked journals.
Mechanical engineering. --- Chemistry --- Physical Sciences & Mathematics --- Physical & Theoretical Chemistry --- Ionic solutions. --- Chemistry, Physical and theoretical. --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Solutions, Ionic --- Chemistry. --- Physical chemistry. --- Materials --- Thin films. --- Physical Chemistry. --- Theoretical and Computational Chemistry. --- Surfaces and Interfaces, Thin Films. --- Surfaces. --- Ions --- Solution (Chemistry) --- Chemistry, Physical organic. --- Surfaces (Physics). --- Physics --- Surface chemistry --- Surfaces (Technology) --- Physical sciences --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Materials—Surfaces. --- Films, Thin --- Solid film --- Solid state electronics --- Solids --- Coatings --- Thick films
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This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.
Chemistry --- Physical Sciences & Mathematics --- Physical & Theoretical Chemistry --- Silicates. --- Zeolites. --- Chemistry. --- Physical chemistry. --- Chemical engineering. --- Catalysis. --- Environmental chemistry. --- Environmental Chemistry. --- Industrial Chemistry/Chemical Engineering. --- Physical Chemistry. --- Silicate minerals --- Oxygen compounds --- Silicon compounds --- Chemistry, Physical organic. --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Chemistry, Industrial --- Engineering, Chemical --- Industrial chemistry --- Engineering --- Chemistry, Technical --- Metallurgy --- Chemistry, Environmental --- Ecology --- Activation (Chemistry) --- Surface chemistry --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Green chemistry.
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Topological Modelling of Nanostructures and Extended Systems completes and expands upon the previously published title within this series: The Mathematics and Topology of Fullerenes (Vol. 4, 2011) by gathering the latest research and advances in materials science at nanoscale. It introduces a new speculative area and novel concepts like topochemical reactions and colored reactive topological indices and provides a better understanding of the physical-chemical behaviors of extended systems. Moreover, a charming new family of space-filling fullerenic crystals is here analyzed for the first time. Particular attention is given to the fundamental influences exercised by long-range connectivity topological mechanisms on the chemical and physical properties of carbon nanostructures. Systems consisting in graphenic layers with structural and topological defects are investigated in their electronic and magnetic behaviors also in presence of metallic particles. More specifically, the book focuses on: · Electronic Properties of low dimensional nanostructures including negatively-curved carbon surfaces; Pariser-Parr-Pople model hamiltonian approach to graphene studies; ·Topochemistry and Toporeactivity of extended sp2-nanocarbons: PAH, fullerenes, nanoribbons, Moebius-like nanoribbons, nanotubes and grapheme; ·Novel class of crystal networks arising from spanning fullerenes; ·Nanostructures and eigenvectors of matrices and an extended treatise of topological invariants; ·Enumeration hetero-fullerenes by Polya theory. Topological Modelling of Nanostructures and Extended Systems represents a valuable resource to advances graduates and researchers working in mathematics, chemistry, physics and material science.
Chemistry --- Physical Sciences & Mathematics --- Physical & Theoretical Chemistry --- Nanostructures --- Nanoscience. --- Design and construction. --- Nano science --- Nanoscale science --- Nanosciences --- Chemistry. --- Physical chemistry. --- Chemistry, Physical and theoretical. --- Nanotechnology. --- Theoretical and Computational Chemistry. --- Physical Chemistry. --- Molecular technology --- Nanoscale technology --- High technology --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Physical sciences --- Science --- Nanoscience --- Physics --- Chemistry, Physical organic. --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Nanostructured materials --- Carbon --- Mathematical models.
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Emphasis is on a broad description of the general methods and processes for the synthesis, modification and characterization of macromolecules. These more fundamental chapters will be supplemented by selected and detailed experiments. In addition to the preparative aspects the book also gives the reader an impression on the relation of chemical constitution and morphology of Polymers to their properties, as well as on their application areas. Thus, an additional textbook will not be needed in order to understand the experiments. The 5th edition contains numerous changes: In recent years, so-called functional polymers which have special electrical, electronic, optical and biological properties, have gained more and more in interest. This textbook was therefore supplemented by recipes which describe the synthesis of these materials in a new chapter "Functional polymers". Together with new experiments in chapter 3,4 and 5 the book now contains more than 120 recipes that describe a wide range of macromolecules.
Free radical reactions. --- Polymerization. --- Polymers. --- Polymerization --- Chemistry --- Physical Sciences & Mathematics --- Organic Chemistry --- Polymers --- Analysis. --- Polymerisation --- Polymers and polymerization --- Synthesis of polymers --- Synthesis --- Chemistry. --- Organic chemistry. --- Physical chemistry. --- Amorphous substances. --- Complex fluids. --- Polymer Sciences. --- Organic Chemistry. --- Soft and Granular Matter, Complex Fluids and Microfluidics. --- Physical Chemistry. --- Chemical reactions --- Chemistry, Organic. --- Chemistry, Physical organic. --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Organic chemistry --- Polymere --- Polymeride --- Macromolecules --- Polymers . --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Complex liquids --- Fluids, Complex --- Amorphous substances --- Liquids --- Soft condensed matter
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This brief presents the main aspects of the response functions theory (RFT) for molecular solutes described within the framework of the Polarizable Continuum Model (PCM). PCM is a solvation model for a Quantum Mechanical molecular system in which the solvent is represented as a continuum distribution of matter. Particular attention is devoted (i) to the description of the basic features of the PCM model, and (ii) to the problems characterizing the study of the response function theory for molecules in solution with respect to the analogous theory on isolated molecules.
Chemistry, Physical and theoretical. --- Models, Theoretical. --- Solvation. --- Solvents -- Mathematical models. --- Physics --- Chemistry --- Physical Sciences & Mathematics --- Atomic Physics --- Physical & Theoretical Chemistry --- Condensed matter. --- Quantum theory. --- Quantum dynamics --- Quantum mechanics --- Quantum physics --- Condensed materials --- Condensed media --- Condensed phase --- Materials, Condensed --- Media, Condensed --- Phase, Condensed --- Chemistry. --- Physical chemistry. --- Theoretical and Computational Chemistry. --- Physical Chemistry. --- Condensed Matter Physics. --- Liquids --- Matter --- Solids --- Mechanics --- Thermodynamics --- Chemistry, Physical organic. --- Physical sciences --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Quantum chemistry. --- Molecular biology.
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Applied Photochemistry encompasses the major applications of the chemical effects resulting from light absorption by atoms and molecules in chemistry, physics, medicine and engineering, and contains contributions from specialists in these key areas. Particular emphasis is placed both on how photochemistry contributes to these disciplines and on what the current developments are. The book starts with a general description of the interaction between light and matter, which provides the general background to photochemistry for non-specialists. The following chapters develop the general synthetic and mechanistic aspects of photochemistry as applied to both organic and inorganic materials, together with types of materials which are useful as light absorbers, emitters, sensitisers, etc. for a wide variety of applications. A detailed discussion is presented on the photochemical processes occurring in the Earth’s atmosphere, including discussion of important current aspects such as ozone depletion. Two important distinct, but interconnected, applications of photochemistry are in photocatalytic treatment of wastes and in solar energy conversion. Semiconductor photochemistry plays an important role in these and is discussed with reference to both of these areas. Free radicals and reactive oxygen species are of major importance in many chemical, biological and medical applications of photochemistry, and are discussed in depth. The following chapters discuss the relevance of using light in medicine, both with various types of phototherapy and in medical diagnostics. The development of optical sensors and probes is closely related to diagnostics, but is also relevant to many other applications, and is discussed separately. Important aspects of applied photochemistry in electronics and imaging, through processes such as photolithography, are discussed and it is shown how this is allowing the increasing miniaturisation of semiconductor devices for a wide variety of electronics applications and the development of nanometer scale devices. The final two chapters provide the basic ideas necessary to set up a photochemical laboratory and to characterise excited states. This book is aimed at those in science, engineering and medicine who are interested in applying photochemistry in a broad spectrum of areas. Each chapter has the basic theories and methods for its particular applications and directs the reader to the current, important literature in the field, making Applied Photochemistry suitable for both the novice and the experienced photochemist.
Chemistry, Physical and theoretical. --- Chemistry. --- Photochemistry. --- Polymers and polymerization. --- Photochemistry --- Chemistry --- Physical Sciences & Mathematics --- Physical & Theoretical Chemistry --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Light --- Photolysis (Chemistry) --- Chemical action --- Physical chemistry. --- Environmental chemistry. --- Optical materials. --- Electronic materials. --- Physical Chemistry. --- Environmental Chemistry. --- Optical and Electronic Materials. --- Biomedicine general. --- Chemistry, Physical and theoretical --- Chemistry, Physical organic. --- Medicine. --- Clinical sciences --- Medical profession --- Human biology --- Life sciences --- Medical sciences --- Pathology --- Physicians --- Optics --- Materials --- Chemistry, Environmental --- Ecology --- Chemistry, Physical organic --- Chemistry, Organic --- Health Workforce --- Biomedicine, general. --- Electronic materials
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This is the first comprehensive overview of this topic. It serves as a single source for information about the properties, preparation, and uses of all relevant primary explosives. The first chapter provides background such as the basics of initiation and differences between requirements on primary explosives used in detonators and igniters. The authors then clarify the influence of physical characteristics on explosive properties, focusing on those properties required for primary explosives. Furthermore, the issue of sensitivity is discussed. All the chapters on particular groups of primary explosives are structured in the same way, including introduction, physical and chemical properties, explosive properties, preparation and documented use. The authors thoroughly verified all data and information. A unique feature of this book are original microscopic images of some explosives.
Chemistry, Organic. --- Chemistry, Physical organic. --- Chemistry. --- Explosives. --- Chemical & Materials Engineering --- Chemistry --- Engineering & Applied Sciences --- Physical Sciences & Mathematics --- Chemical Engineering --- Physical & Theoretical Chemistry --- Bombs. --- Aerial bombs --- Explosive chemicals --- Organic chemistry. --- Physical chemistry. --- Chemical engineering. --- Physical Chemistry. --- Industrial Chemistry/Chemical Engineering. --- Organic Chemistry. --- Ammunition --- Projectiles, Aerial --- Bombings --- Chemistry, Technical --- Blasting --- Organic chemistry --- Chemistry, Industrial --- Engineering, Chemical --- Industrial chemistry --- Engineering --- Metallurgy --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry
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Astrochemistry and Astrobiology is the debut volume in the new series Physical Chemistry in Action. Aimed at both the novice and experienced researcher, this volume outlines the physico-chemical principles which underpin efforts to understand astrochemistry and predict astrobiology. An introductory chapter includes fundamental aspects of physical chemistry required for understanding the field. Eight further chapters address specific topics, encompassing basic theory and models, up-to-date research and an outlook on future work. The last chapter examines each of the topics addressed from a different angle. Written and edited by international experts, this text is accessible for those entering the field of astrochemistry and astrobiology, whilst still providing new information and insights for experienced researchers.
Cosmochemistry -- Textbooks. --- Cosmochemistry. --- Cosmochemistry --- Exobiology --- Chemistry, Physical and theoretical --- Astronomy & Astrophysics --- Chemistry --- Physical Sciences & Mathematics --- Theoretical Astronomy --- Physical & Theoretical Chemistry --- Exobiology. --- Astrobiology --- Astrochemistry --- Cosmic chemistry --- Space chemistry --- Chemistry. --- Physical chemistry. --- Chemistry, Physical and theoretical. --- Astronomy. --- Astrophysics. --- Cosmology. --- Astrobiology. --- Physical Chemistry. --- Theoretical and Computational Chemistry. --- Astronomy, Astrophysics and Cosmology. --- Biology --- Habitable planets --- Life --- Space sciences --- Origin --- Chemistry, Physical organic. --- Physical sciences --- Chemistry, Physical organic --- Chemistry, Organic --- Astronomical physics --- Astronomy --- Cosmic physics --- Physics --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry
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Iptycenes Chemistry: From Synthesis to Applications provides a comprehensive overview of the development of iptycene chemistry in the past seventy years. This book covers: (1) the basic nomenclature and general properties of iptycenes and their derivatives; (2) the synthesis and functionalization reactions of triptycenes, pentiptycenes, higher iptycenes, heterotriptycenes, and homotriptycenes; (3) the methods for the preparation of iptycene-based polymers with different types; and (4) the applications of iptycenes and their derivatives in molecular machines, materials science, host-guest chemistry, self-assembly, coordination chemistry, physical organic chemistry, medicinal chemistry, and so on. Consequently, such a book is not only helpful to researchers working in iptycene chemistry, but can also facilitate future research in wide areas.
Chemistry, Organic. --- Chemistry. --- Chirality. --- Aromatic compounds --- Polymers --- Chemistry --- Physical Sciences & Mathematics --- Biochemistry --- Organic Chemistry --- Aromatic compounds. --- Polymers. --- Polymere --- Polymeride --- Polymers and polymerization --- Arenes --- Organic chemistry. --- Physical chemistry. --- Optical materials. --- Electronic materials. --- Organic Chemistry. --- Optical and Electronic Materials. --- Polymer Sciences. --- Physical Chemistry. --- Macromolecules --- Organic cyclic compounds --- Chemistry, Physical organic. --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Optics --- Materials --- Organic chemistry --- Polymers . --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Electronic materials
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