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Geology --- Geophysics --- Hydrology --- Marine sciences --- Geomorphology --- minerals --- Moon phases --- Solar energy --- Earth --- world
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A classical metastable state possesses a local free energy minimum at infinite sizes, but not a global one. This concept is phase size independent. We have studied a number of experimental results and proposed a new concept that there exists a wide range of metastable states in polymers on different length scales where their metastability is critically determined by the phase size and dimensionality. Metastable states are also observed in phase transformations that are kinetically impeded on the pathway to thermodynamic equilibrium. This was illustrated in structural and morphological investig
Polymères --- Transitions de phases --- Etats métastables (physique) --- Polymers --- Phase transformations (Statistical physics) --- Nonequilibrium thermodynamics --- Transformations de phase (Physique statistique) --- Thermodynamique irréversible --- Polymers. --- Nonequilibrium thermodynamics. --- Irreversible thermodynamics --- Non-equilibrium thermodynamics --- Thermodynamics of the steady state --- Irreversible processes --- Thermodynamics --- Phase changes (Statistical physics) --- Phase transitions (Statistical physics) --- Phase rule and equilibrium --- Statistical physics --- Polymere --- Polymeride --- Polymers and polymerization --- Macromolecules
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