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'Chemical Structure and Reactivity' depicts the subject as a seamless discipline, showing how inorganic, organic and physical concepts can be blended together to achieve the common goal of understanding chemical systems. The book includes in-text examples and extensive end-of-chapter questions to encourage learning.
Chemical structure --- Reactivity (Chemistry) --- Chemical structure. --- Reactivity (Chemistry). --- Chemical reaction, Conditions and laws of --- Chemical reactions --- Structure, Chemical --- Chemistry, Physical and theoretical --- Matter --- Constitution
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Modern energetic materials include explosives, blasting powders, pyrotechnic m- tures and rocket propellants [1, 2]. The study of high-temperature decomposition of condensed phases of propellants and their components (liquid, solid and hybrid) is currently of special importance for the development of space-system engineering [3, 4]. To better understand the burning mechanisms (stationary, nonstationary, - steady) of composite solid propellants and their components, information about the macrokinetics of their high-temperature decomposition is required [5]. To be able to evaluate the ignition parameters and conditions of safe handling of heat-affected explosives, one needs to know the kinetic constants of their high-temperature - composition. The development of new composite solid propellants characterized by high performance characteristics (high burning rates, high thermal stability, stability to intrachamber perturbations, and other aspects) is not possible without quanti- tive data on the high-temperature decomposition of composite solid propellants and their components [6]. The same reasons have resulted in signi?cant theoretical and practical interest in the high-temperature decomposition of components of hybrid propellants. It is known that hybrid propellants have not been used very widely due to the low bu- ing (pyrolysis) rates of the polymer blocks in the combustion chambers of hybrid rocket engines. To increase the burning rates it is necessary to obtain information about their relationships to the corresponding kinetic and thermophysical prop- ties of the fuels.
Chemical kinetics --- Combustion. --- High temperature chemistry. --- Effect of temperature on. --- Chemical reaction, Conditions and laws of --- Temperature --- Thermochemistry --- Heat --- Smoke --- Chemicals --- Engineering. --- Chemistry, Physical organic. --- Materials. --- Thermodynamics. --- Safety in Chemistry, Dangerous Goods. --- Engineering Thermodynamics, Heat and Mass Transfer. --- Physical Chemistry. --- Materials Science, general. --- Structural Materials. --- Safety measures. --- Construction --- Industrial arts --- Technology --- Chemistry, Physical and theoretical --- Dynamics --- Mechanics --- Physics --- Heat-engines --- Quantum theory --- Engineering --- Engineering materials --- Industrial materials --- Engineering design --- Manufacturing processes --- Chemistry, Physical organic --- Chemistry, Organic --- Materials --- Chemistry. --- Heat engineering. --- Heat transfer. --- Mass transfer. --- Physical chemistry. --- Materials science. --- Structural materials. --- Architectural materials --- Architecture --- Building --- Building supplies --- Buildings --- Construction materials --- Structural materials --- Material science --- Physical sciences --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Mass transport (Physics) --- Thermodynamics --- Transport theory --- Heat transfer --- Thermal transfer --- Transmission of heat --- Energy transfer --- Mechanical engineering
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