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Introducing the application of free energy correlations to elucidating the mechanisms of organic and bio-organic reactions, this book provides a new and illuminating way of approaching a potentially complex topic. The idea of how free energy correlations derive from polar substituent change is introduced, and common pitfalls encountered in the application of free energy relationships are described, along with the use of these anomalies in mechanistic studies. The concept of effective charge is described in detail, with examples of its application. Throughout, worked answers are provided for th

Linear free energy relationship. --- Correlation analysis (Chemistry) --- Correlation equation (Chemistry) --- Free energy relationship, Linear --- Chemical reaction, Conditions and laws of --- Gibbs' free energy --- Linear free energy relationship --- 541.124 --- 541.124 Chemical dynamics in general. Reaction mechanism in general --- 541.124 Limits of reactions --- Chemical dynamics in general. Reaction mechanism in general --- Limits of reactions

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Soccer. --- Sports sciences.