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First published in 2002, from an original 1964 edition, in the Crystallization of Polymers, 2nd edition Leo Mandelkern provides a self-contained treatment of polymer crystallization. All classes of macromolecules are included and the approach is through the basic disciplines of chemistry and physics. The book discusses the thermodynamics and physical properties that accompany the morphological and structural changes that occur when a collection of molecules of very high molecular weight are transformed from one state to another. Volume 1 is a presentation of the equilibrium concepts that serve as a basis for the subsequent volumes. In this volume the author shows that knowledge of the equilibrium requirements is vital to understanding all aspects of the polymer crystallization process, and the final state that eventually evolves. This book will be an invaluable reference work for all chemists, physicists and materials scientists who work in the area of polymer crystallization.
Polymers. --- Crystallization. --- Crystalline polymers. --- Chemistry --- Chemistry, Physical and theoretical --- Separation (Technology) --- Polymere --- Polymeride --- Polymers and polymerization --- Macromolecules --- Crystal polymers --- Crystallographically ordered polymers --- Polymer crystals --- Crystals --- Polymers --- Crystallization --- Crystalline polymers --- Polymères --- Cristallisation --- Polymères cristallins
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The main topics discussed in this book are the formation of the macromolecular condensed state from isolated long chain macromolecules in dilute solution, the salient physical behavior of the polymeric amorphous state, the liquid crystalline state of rigid chain polymers, the crystallization process and the single chain condensed state, all based on experimental results. The role of intersegmental cohesion and the difference between the single chain condensed state and the interpenetrated multichain condensed state are emphasized. In addition, the book introduces and discusses some new physica
Polymer liquid crystals. --- Crystalline polymers. --- Crystal polymers --- Crystallographically ordered polymers --- Polymer crystals --- Crystals --- Polymers --- Crystals, Polymer liquid --- Liquid crystal polymers --- Liquid crystalline polymers --- Liquid crystals, Polymer --- Polymeric liquid crystals --- Liquid crystals
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