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The subject of dioxygen activation and homogeneous catalytic oxidation by metal complexes has been in the focus of attention over the last 20 years. The widespread interest is illustrated by its recurring presence among the sessions and subject areas of important international conferences on various aspects of bioinorganic and coordination chemistry as well as catalysis. The most prominent examples are ICCC, ICBIC, EUROBIC, ISHC, and of course the ADHOC series of meetings focusing on the subject itself. Similarly, the number of original and review papers devoted to various aspects of dioxygen activation are on the rise. This trend is due obviously to the relevance of catalytic oxidation to biological processes such as dioxygen transport, and the action of oxygenase and oxidase enzymes related to metabolism. The structural and functional modeling of metalloenzymes, particularly of those containing iron and copper, by means of low-molecular complexes of iron, copper, ruthenium, cobalt, manganese, etc., have provided a wealth of indirect information helping to understand how the active centers of metalloenzymes may operate. The knowledge gained from the study of metalloenzyme models is also applicable in the design of transition metal complexes as catalytsts for specific reactions. This approach has come to be known as biomimetic or bioinspired catalysis and continues to be a fruitful and expanding area of research.
Catalysis --- Oxygen --- Metal complexes --- Chemistry --- Physical Sciences & Mathematics --- Physical & Theoretical Chemistry --- Catalysis. --- Physical chemistry. --- Inorganic chemistry. --- Biochemistry. --- Physical Chemistry. --- Inorganic Chemistry. --- Biochemistry, general. --- Activation (Chemistry) --- Chemistry, Physical and theoretical --- Surface chemistry --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Biological chemistry --- Chemical composition of organisms --- Organisms --- Physiological chemistry --- Biology --- Medical sciences --- Inorganic chemistry --- Inorganic compounds --- Composition
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According to R.H. Crabtree, Metal Dihydrogen and sigma-Bond Complexes is described as `the definitive account of twentieth-century work in the area of sigma complexation'. It covers not only Kubas' discovery of dihydrogen coordination and the study of its structure and general properties but also discusses both the theoretical beliefs and experimental results of bonding and activation of dihydrogen on metal centers and the coordination and activation of C-H, B-H, X-H, and X-Y bonds, giving an overview of `one of the hottest areas in chemistry'.
Metal complexes. --- Hydrogen. --- Chemical bonds. --- Chemistry, Organic. --- Chemistry, Physical organic. --- Chemistry, inorganic. --- Chemical engineering. --- Organometallic Chemistry. --- Physical Chemistry. --- Inorganic Chemistry. --- Industrial Chemistry/Chemical Engineering. --- Organometallic chemistry . --- Physical chemistry. --- Inorganic chemistry. --- Chemistry, Industrial --- Engineering, Chemical --- Industrial chemistry --- Engineering --- Chemistry, Technical --- Metallurgy --- Inorganic chemistry --- Chemistry --- Inorganic compounds --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry, Organometallic --- Metallo-organic chemistry --- Chemistry, Organic --- Nonmetals
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