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Physical organic chemistry --- Physicochemistry --- fysicochemie --- Organic chemistry --- Chimie organique physique --- Periodicals --- Périodiques --- Chemistry, Physical organic --- Chemistry --- General and Others
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The problem of superconductors has been a central issue in Solid State Physics since 1987. After the discovery of superconductivity (HTSC) in doped perovskites, it was realized that the HTSC appears in an unknown complex electronic phase of c- densed matter. In the early years, all theories of HTSC were focused on the physics of a homogeneous 2D metal with large electron–electron correlations or on a 2D polaron gas. Only after 1990, a novel paradigm started to grow where this 2D metallic phase is described as an inhomogeneous metal. This was the outcome of several experimental evidences of phase separation at low doping. Since 1992, a series of conferences on phase separation were organized to allow scientists to get together to discuss the phase separation and related issues. Following the discovery by the Rome group in 1992 that “the charges move freely mainly in one direction like the water running in the grooves in the corrugated iron foil,” a new scenario to understand superconductivity in the superconductors was open. Because the charges move like rivers, the physics of these materials shifts toward the physics of novel mesoscopic heterostructures and complex electronic solids. Therefore, understanding the striped phases in the perovskites not only provides an opportunity to understand the anomalous metallic state of cuprate superconductors, but also suggests a way to design new materials of technological importance. Indeed, the stripes are becoming a field of general scientific interest.
High temperature superconductors. --- High temperature superconductivity. --- Surfaces (Physics). --- Chemistry, Physical organic. --- Mechanics. --- Characterization and Evaluation of Materials. --- Physical Chemistry. --- Classical Mechanics. --- Classical mechanics --- Newtonian mechanics --- Physics --- Dynamics --- Quantum theory --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Surface chemistry --- Surfaces (Technology) --- Materials science. --- Physical chemistry. --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Material science --- Physical sciences
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hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the “noble gases of organic chemistry” and, if so, the first representative of their family – methane – may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning – the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300–500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process – but not from a chemist viewpoint.
Alkanes. --- Activation (Chemistry) --- Metal complexes. --- Catalysis. --- Chemistry, Physical organic. --- Chemistry, inorganic. --- Chemistry, Organic. --- Physical Chemistry. --- Inorganic Chemistry. --- Organic Chemistry. --- Physical chemistry. --- Inorganic chemistry. --- Organic chemistry. --- Organic chemistry --- Chemistry --- Inorganic chemistry --- Inorganic compounds --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry
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This book is meant to provide a window on the rapidly growing body of theoretical studies of condensed phase chemistry. A brief perusal of physical chemistry journals in the early to mid 1980’s will find a large number of theor- ical papers devoted to 3-body gas phase chemical reaction dynamics. The recent history of theoretical chemistry has seen an explosion of progress in the devel- ment of methods to study similar properties of systems with Avogadro’s number of particles. While the physical properties of condensed phase systems have long been principle targets of statistical mechanics, microscopic dynamic theories that start from detailed interaction potentials and build to first principles predictions of properties are now maturing at an extraordinary rate. The techniques in use range from classical studies of new Generalized Langevin Equations, semicl- sical studies for non-adiabatic chemical reactions in condensed phase, mixed quantum classical studies of biological systems, to fully quantum studies of m- els of condensed phase environments. These techniques have become sufficiently sophisticated, that theoretical prediction of behavior in actual condensed phase environments is now possible. and in some cases, theory is driving development in experiment. The authors and chapters in this book have been chosen to represent a wide variety in the current approaches to the theoretical chemistry of condensed phase systems. I have attempted a number of groupings of the chapters, but the - versity of the work always seems to frustrate entirely consistent grouping.
Chemistry, Physical and theoretical. --- Condensed matter. --- Chemistry, Physical organic. --- Physical Chemistry. --- Condensed Matter Physics. --- Physical chemistry. --- Condensed materials --- Condensed media --- Condensed phase --- Materials, Condensed --- Media, Condensed --- Phase, Condensed --- Liquids --- Matter --- Solids --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry
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Catalysts are central in modern industrial chemistry and there is an urgent need to develop new catalysts. Such a rapid pace of development brings with it a new set of challenges at all levels of research, from synthesis and characterization to testing and modelling. This book reviews the current status of combinatorial catalysis, scientific catalyst design techniques, methods for preparing inorganic combinatorial libraries, experimental design methods, data processing, system modelling an simulation, and catalyst testing. The individual contributions reveal the development of high throughput catalyst design and test methods and identify the main challenges in the field, including new catalyst preparation techniques, rapid performance evaluation, and new microreactor configurations. Readership: All those working in catalytic process analysis and development. The extensive review of catalysis principles is especially relevant for postgraduate students seeking to pursue studies in catalysis.
Catalysis --- Catalysts --- Combinatorial chemistry --- Design --- Congresses --- Chemistry, Physical organic. --- Chemical engineering. --- Chemistry. --- Physical Chemistry. --- Industrial Chemistry/Chemical Engineering. --- Computer Applications in Chemistry. --- Physical sciences --- Chemistry, Industrial --- Engineering, Chemical --- Industrial chemistry --- Engineering --- Chemistry, Technical --- Metallurgy --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Physical chemistry. --- Chemoinformatics. --- Chemical informatics --- Chemiinformatics --- Chemoinformatics --- Chemistry informatics --- Chemistry --- Information science --- Computational chemistry --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Data processing --- Catalyseurs --- Catalyse --- Chimie combinatoire --- Conception
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Chemistry --- Physical Sciences & Mathematics --- Physical & Theoretical Chemistry --- Transition metal complexes --- Ligands --- Coordination compounds --- Metal complexes --- Transition metal compounds --- Conferences - Meetings --- Congresses --- Chemistry, Physical organic. --- Surfaces (Physics). --- Biochemistry. --- Physical Chemistry. --- Surfaces and Interfaces, Thin Films. --- Biochemistry, general. --- Biological chemistry --- Chemical composition of organisms --- Organisms --- Physiological chemistry --- Biology --- Medical sciences --- Physics --- Surface chemistry --- Surfaces (Technology) --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Composition --- Physical chemistry. --- Materials—Surfaces. --- Thin films. --- Films, Thin --- Solid film --- Solid state electronics --- Solids --- Coatings --- Thick films --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry
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In the last decade there have been numerous advances in the area of rhodium-catalyzed hydroformylation, such as highly selective catalysts of industrial importance, new insights into mechanisms of the reaction, very selective asymmetric catalysts, in situ characterization and application to organic synthesis. The views on hydroformylation which still prevail in the current textbooks have become obsolete in several respects. Therefore, it was felt timely to collect these advances in a book. The book contains a series of chapters discussing several rhodium systems arranged according to ligand type, including asymmetric ligands, a chapter on applications in organic chemistry, a chapter on modern processes and separations, and a chapter on catalyst preparation and laboratory techniques. This book concentrates on highlights, rather than a concise review mentioning all articles in just one line. The book aims at an audience of advanced students, experts in the field, and scientists from related fields. The didactic approach also makes it useful as a guide for an advanced course.
Hydroformylation. --- Rhodium catalysts. --- Chemistry, inorganic. --- Chemistry, Physical organic. --- Chemical engineering. --- Chemistry, Organic. --- Inorganic Chemistry. --- Physical Chemistry. --- Industrial Chemistry/Chemical Engineering. --- Organic Chemistry. --- Inorganic chemistry. --- Physical chemistry. --- Organic chemistry. --- Organic chemistry --- Chemistry --- Chemistry, Industrial --- Engineering, Chemical --- Industrial chemistry --- Engineering --- Chemistry, Technical --- Metallurgy --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Inorganic chemistry --- Inorganic compounds --- Platinum group catalysts --- Formylation --- Hydroxylation
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The aim of this book is to provide the reader with a modern presentation of ionic solutions at interfaces, for physical chemists, chemists and theoretically oriented experimentalists in this field. The discussion is mainly on the structural and thermodynamic properties, in relation to presently available statistical mechanical models. Some dynamic properties are also presented, at a more phenomenological level. The initial chapters are devoted to the presentation of some basic concepts for bulk properties: hydrodynamic interactions, electrostatics, van der Waals forces and thermodynamics of ionic solutions in the framework of a particular model: the mean spherical approximation (MSA). Specific features of interfaces are then discussed: experimental techniques such as in-situ X-ray diffraction, STM and AFM microscopy are described. Ions at liquid/air, liquid/metal and liquid/liquid interfaces are considered from the experimental and theoretical viewpoint. Lastly some dynamic (transport) properties are included, namely the self-diffusion and conductance of small colloids (polyelectrolytes and micelles) and the kinetics of solute transfer at free liquid/liquid interfaces.
Electrolytes. --- Interfaces (Physical sciences) --- Chemistry, Physical organic. --- Surfaces (Physics). --- Physical Chemistry. --- Surfaces and Interfaces, Thin Films. --- Physical chemistry. --- Materials—Surfaces. --- Thin films. --- Materials --- Surfaces. --- Films, Thin --- Solid film --- Solid state electronics --- Solids --- Surfaces (Technology) --- Coatings --- Thick films --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Surface chemistry --- Surfaces (Physics)
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The electron density of a non-degenerate ground state system determines essentially all physical properties of the system. This statement of the Hohenberg–Kohn theorem of Density Functional Theory plays an exceptionally important role among all the fundamental relations of Molecular Physics. In particular, the electron density distribution and the dynamic properties of this density determine both the local and global reactivities of molecules. High resolution experimental electron densities are increasingly becoming available for more and more molecules, including macromolecules such as proteins. Furthermore, many of the early difficulties with the determination of electron densities in the vicinity of light nuclei have been overcome. These electron densities provide detailed information that gives important insight into the fundamentals of molecular structure and a better understanding of chemical reactions. The results of electron density analysis are used in a variety of applied fields, such as pharmaceutical drug discovery and biotechnology. If the functional form of a molecular electron density is known, then various molecular properties affecting reactivity can be determined by quantum chemical computational techniques or alternative approximate methods.
Density functionals. --- Reactivity (Chemistry) --- Chemistry, Physical organic. --- Chemistry. --- Crystallography. --- Physical Chemistry. --- Theoretical and Computational Chemistry. --- Crystallography and Scattering Methods. --- Atomic, Molecular, Optical and Plasma Physics. --- Physical chemistry. --- Chemistry, Physical and theoretical. --- Atoms. --- Physics. --- Natural philosophy --- Philosophy, Natural --- Physical sciences --- Dynamics --- Chemistry, Physical and theoretical --- Matter --- Stereochemistry --- Leptology --- Mineralogy --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Constitution
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In the future, our energy systems will need to be renewable and sustainable, efficient and cost-effective, convenient and safe. Hydrogen has been proposed as the perfect fuel for this future energy system. The availability of a reliable and cost-effective supply, safe and efficient storage, and convenient end use of hydrogen will be essential for a transition to a Hydrogen Economy. Research is being conducted throughout the world for the development of safe, cost-effective hydrogen production, storage, and end-use technologies that support and foster this transition. This book is a collection of important research and analysis papers on hydrogen production, storage, and end-use technologies that were presented at the American Chemical Society National Meeting in New Orleans, Louisiana, USA, in August 1999.
Hydrogen as fuel --- Renewable energy sources. --- Chemistry, Physical organic. --- Surfaces (Physics). --- Environmental sciences. --- Chemical engineering. --- Renewable and Green Energy. --- Physical Chemistry. --- Characterization and Evaluation of Materials. --- Environment, general. --- Industrial Chemistry/Chemical Engineering. --- Renewable energy resources. --- Physical chemistry. --- Materials science. --- Environment. --- Ecology. --- Chemistry, Industrial --- Engineering, Chemical --- Industrial chemistry --- Engineering --- Chemistry, Technical --- Metallurgy --- Material science --- Physical sciences --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry
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