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Handbook of battery materials
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ISBN: 3527294694 Year: 1999 Publisher: Weinheim Wiley-VCH

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On the electricity excited by the mere contact of conducting substances of different kinds.
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ISBN: 8820327627 Year: 1999 Publisher: Milano Hoepli

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Book
Progress in the development of lightweight nickel electrode for nickel-hydrogen cell
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Year: 1999 Publisher: Cleveland, Ohio : National Aeronautics and Space Administration, Glenn Research Center,

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Electrochemical supercapacitors : scientific fundamentals and technological applications
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ISBN: 0306457369 9781475730609 1475730608 1475730586 9780306457364 Year: 1999 Publisher: New York : Plenum Press,

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The first model for the distribution of ions near the surface of a metal electrode was devised by Helmholtz in 1874. He envisaged two parallel sheets of charges of opposite sign located one on the metal surface and the other on the solution side, a few nanometers away, exactly as in the case of a parallel plate capacitor. The rigidity of such a model was allowed for by Gouy and Chapman inde­ pendently, by considering that ions in solution are subject to thermal motion so that their distribution from the metal surface turns out diffuse. Stern recognized that ions in solution do not behave as point charges as in the Gouy-Chapman treatment, and let the center of the ion charges reside at some distance from the metal surface while the distribution was still governed by the Gouy-Chapman view. Finally, in 1947, D. C. Grahame transferred the knowledge of the struc­ ture of electrolyte solutions into the model of a metal/solution interface, by en­ visaging different planes of closest approach to the electrode surface depending on whether an ion is solvated or interacts directly with the solid wall. Thus, the Gouy-Chapman-Stern-Grahame model of the so-called electrical double layer was born, a model that is still qualitatively accepted, although theoreti­ cians have introduced a number of new parameters of which people were not aware 50 years ago.


Periodical
Electrochemistry communications
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ISSN: 13882481 18731902 Year: 1999 Publisher: Philadelphia Elsevier Inc.


Periodical
Proceedings of a conference held at Ohio Aerospace Institute and sponsored by NASA Glenn Research Center.
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ISSN: 23752769 Year: 1999 Publisher: Cleveland, Ohio : National Aeronautics and Space Administration, Glenn Research Center

Principles of exercise testing and interpretation, including pathophysiology and clinical applications
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ISBN: 0683306464 9780683306460 Year: 1999 Publisher: Philadelphia (Pa.): Lippincott Williams and Wilkins

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Keywords

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