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This book describes for the first time in a modern text the fundamental principles on which solid state chemistry is based. In this sense it differs from other books on the subject, which tend to concentrate only on a description of materials. Topics include solid (ceramic) electrolytes, glasses, polymer electrolytes, intercalation electrodes, interfaces and applications. The different nature of ionic conductivity in ceramic, glassy and polymer electrolytes is described, as are the thermodynamics and kinetics of intercalation reactions. The interface between solid electrolytes and electrodes is discussed and contrasted with more conventional liquid state electrochemistry. The text provides an essential foundation for postgraduates and others entering the field for the first time and will also be of value in advanced undergraduate courses.
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Solid state chemistry today is a frontier area of mainstream chemistry, and plays a vital role in the development of materials. The present work, consisting of a selection of Prof. C N R Rao's papers, covers most of the important aspects of solid state chemistry and provides the flavor of the subject, showing how the subject has evolved over the years. The book is up-to-date, and will be useful to students, teachers, beginning researchers and practitioners in solid state chemistry as well as in the broader area of materials science.
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Crystallography. --- Organic solid state chemistry. --- Self-organizing systems.
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Chemical thermodynamics --- fysicochemie --- Chemical kinetics --- Solid state chemistry --- Chemistry, Solid state --- Chemistry, Physical and theoretical --- Chemical reaction, Kinetics of --- Chemical reaction, Rate of --- Chemical reaction, Velocity of --- Chemical reaction rate --- Chemical reaction velocity --- Kinetics, Chemical --- Rate of chemical reaction --- Reaction rate (Chemistry) --- Velocity of chemical reaction --- Chemical affinity --- Reactivity (Chemistry) --- Chemical kinetics. --- Solid state chemistry.
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In Chemical Bonding in Solids, renowned chemist Jeremy K. Burdett offers a clear and much-needed synthesis of chemical bonding theory and solid state structural considerations. Over the past fifteen years, the delocalized orbital model favored by molecular chemists--the model of choice for understanding a plethora of organic, inorganic, and organometallic chemistry phenomena--has been effectively used for infinite solid-state arrays. In addition, other concepts originating from molecular chemistry--including overlap population analysis, topological aspects of the Hamiltonian matrix, and eigenvalue and eigenvector forms--have been increasingly added to the physicist's arsenal. Focusing on insights proffered by both chemists and physicists, this book documents cutting-edge approaches to the computation of the electronic band structures of materials, attempts to understand their origin, the use of results to make predictions concerning the properties of such materials, and the extraction of general ideas concerning structure and bonding. Copiously illustrated and extremely well-written, Chemical Bonding in Solids is the ideal introduction for graduate students and for researchers interested in applying the latest theoretical ideas to applied efforts in synthesizing and characterizing important new materials.
541.57 --- 548.12 --- #WSCH:AAS2 --- Bonds --- Theory of symmetry. Theory of original forms in general --- Solid state chemistry. --- 548.12 Theory of symmetry. Theory of original forms in general --- 541.57 Bonds --- Solid state chemistry --- Chemistry, Solid state --- Chemistry, Physical and theoretical
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