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This book highlights recent progress in the chemistry of radicals. Developments include the growing use of lasers to generate radicals, the application of lasers to provide state, angular, polarization, energy and real-time resolution in kinetics and dynamics experiments, the development of theories for handling the reactions of radicals, and the simulation of the reaction dynamics of increasingly larger systems for direct comparison to experimental results. The book emphasizes the increasing interaction between experimental dynamics, kinetics and theory. It is appropriate for chemistry graduates.

Chemical kinetics. --- Radicals (Chemistry). --- Reactivity (Chemistry). --- Chemical reaction, Conditions and laws of --- Chemical reactions --- Chemical radicals --- Functional groups --- Chemical reaction, Kinetics of --- Chemical reaction, Rate of --- Chemical reaction, Velocity of --- Chemical reaction rate --- Chemical reaction velocity --- Kinetics, Chemical --- Rate of chemical reaction --- Reaction rate (Chemistry) --- Velocity of chemical reaction --- Chemical affinity --- Reactivity (Chemistry) --- Radicals (Chemistry)

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541.124 --- 541.5 --- Chemical kinetics --- #WSCH:AAS1 --- #KVIV:BB --- #WSCH:MODS --- Chemical reaction, Kinetics of --- Chemical reaction, Rate of --- Chemical reaction, Velocity of --- Chemical reaction rate --- Chemical reaction velocity --- Kinetics, Chemical --- Rate of chemical reaction --- Reaction rate (Chemistry) --- Velocity of chemical reaction --- Chemical affinity --- Reactivity (Chemistry) --- Limits of reactions --- Valencies. Bonds. Affinity --- 541.5 Valencies. Bonds. Affinity --- 541.124 Chemical dynamics in general. Reaction mechanism in general --- 541.124 Limits of reactions --- Chemical dynamics in general. Reaction mechanism in general --- Molecular dynamics. --- Cluster compounds --- Energy level excitation --- Ionization, photo --- Photoelectron spectroscopy --- Photolysis --- Photolysis, flash --- Photosynthesis --- Surface (chemistry and physics) --- Van der waals complexes

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Reaction kinetics is central to the study of chemistry. Kinetic studies can provide both an insight into the detailed molecular mechanisms of elementary reactions and practical information which can be used to unravel complex chemical problems such as the formation of the ozone hole. This modern, accessible text begins with an introduction to the importance and relevance of chemical kinetics, and then describes and explains the experimental and theoretical studies of elementary reactions. The applications of kinetics to complex phenomena such as chain reactions and photochemistry are then described, emphasizing how these systems are built up of individual elementary reactions. Examples from the fields of chain reactions, atmospheric chemistry, explosions, oscillating reactions, and photochemistry are then explored in greater detail. Worked examples and problems throughout the text allow students to obtain a detailed understanding of the field. Boxed inserts explain advanced topics more clearly.

Thermodynamics --- Organic chemistry --- fysicochemie --- organische chemie --- Organic reaction mechanisms and kinetics --- reactiekinetiek --- Physicochemistry --- Chemical thermodynamics --- thermodynamica --- organic chemistry --- Chemical kinetics --- #WSCH:AAS1 --- 541.124 --- 541.124 Chemical dynamics in general. Reaction mechanism in general --- 541.124 Limits of reactions --- Chemical dynamics in general. Reaction mechanism in general --- Limits of reactions --- Chemical reaction, Kinetics of --- Chemical reaction, Rate of --- Chemical reaction, Velocity of --- Chemical reaction rate --- Chemical reaction velocity --- Kinetics, Chemical --- Rate of chemical reaction --- Reaction rate (Chemistry) --- Velocity of chemical reaction --- Chemical affinity --- Reactivity (Chemistry) --- Chemical kinetics. --- 544.41 --- 544.431.2 --- 544.52 --- chemische reacties --- fotochemie --- fysische chemie --- kinetica --- laboratoriumchemie --- reactiesnelheid --- Reaction kinetics