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1994 (2)

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Reaction dynamics in clusters and condensed phases
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ISBN: 9780792325826 0792325826 Year: 1994 Publisher: Dordrecht: Kluwer,

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Abstract

Symmetry and topology in chemical reactivity
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ISBN: 9814317160 9789814317160 9810215428 9789810215422 Year: 1994 Publisher: Singapore ; River Edge, N.J. : World Scientific,

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Abstract

This well-illustrated book develops, using only the ideas of basic quantum chemistry (e.g. perturbation and symmetry theory), a fundamental conceptual and theoretical framework for chemical reactivity. By feeding the role of symmetry and chemical group topology directly into the development, the analysis generates and explains the successful features of simpler reactivity theories (e.g. frontier orbital theory, the isolobal concept, PMO theory, the Woodward-Hoffmann rules), as well as defines their limitations. The unifying construct is that of a group-resolved correlation diagram, which is sh

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