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Transition metal complexes. --- Metal complexes --- Transition metal compounds
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This text provides a general background as a course module in the area of inorganic reaction mechanisms, suitable for advanced undergraduate and postgraduate study and/or research. The topic has important research applications in the metallurgical industry and is of interest in the science of biochemistry, biology, organic, inorganic and bioinorganic chemistry. In addition to coverage of substitution reactions in four-, five- and six-coordinate complexes, the book contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the
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Spectral Methods in Transition Metal Complexes provides a conceptual understanding on how to interpret the optical UV-vis, vibrational EPR, and NMR spectroscopy of transition metal complexes. Metal complexes have broad applications across chemistry in the areas of drug discovery, such as anticancer drugs, sensors, special materials for specific requirements, and catalysis, so a thorough knowledge in preparation and characterization of metal complexes, while niche, is critical. Accessible to both the seasoned researcher and the graduate student alike, this book provides readers with a single source of content that addresses spectral methods in transition metal complexes.
Transition metal complexes --- Spectra. --- Métaux de transition --- Complexes --- Spectres. --- Metal complexes --- Transition metal compounds
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Hydrocarbons --- Catalytic cracking. --- Transition metal complexes. --- Catalysis. --- Oxidation.
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Nucleic Acids: A Natural Target for Newly Designed Metal Chelate Based Drugs discusses how human diseases are becoming more costly to treat, along with updates on the resistance offered by disease-causing agents. The abundance of drugs in the market has provided great relief to patients, but side effects can destroy the immune system of the body. Patients need to boost their immune system, and at the same time cover expenses incurred to cure disease. Thus, a paradigm shift is needed to design a drug molecule with low cost and easy availability. Metal complexes can be a great example of such a shift, as metal ions are components of biological molecules and can achieve good binding capability to specific targets while not allowing them to damage healthy cell system. Therefore, in this book, a comprehensive compilation of recent data is provided, including the structural elucidation of metal complexes by advanced techniques and the binding pattern of metal complexes with specific targets.
Nucleic acids. --- Metal complexes --- Nucleic Acids --- Coordination Complexes --- Therapeutic use. --- therapeutic use
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Starting with the most elementary ideas of molecular orbital theory and leading the reader to an understanding of the electronic structure, geometry and reactivity of transition metal complexes, this work provides students with a theoretical method of analysis which relies on some simple ideas (symmetry and overlap).
Transition metal complexes. --- Metal complexes. --- Complex compounds --- Metal complexes --- Transition metal compounds --- Transition metal complexes --- 539.194 --- 544.14 --- 661.78 --- 661.78 Organometallic compounds --- Organometallic compounds --- 539.194 Internal mechanics of molecules. Energy relationships. Vibration and rotation in molecules. Electronic levels. Bonds. Resonance energies, potentials. Nuclear coupling. Polarizability etc. --- Internal mechanics of molecules. Energy relationships. Vibration and rotation in molecules. Electronic levels. Bonds. Resonance energies, potentials. Nuclear coupling. Polarizability etc. --- Bonding, chemical
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Intermetallic science is closely related to physics, chemistry, metallurgy, materials science & technology, and engineering. This book emphasizes the chemical aspects of this science, and therefore the mutual reactivity of metals and the characteristics of intermetallic compounds. Topics included are: . Phase diagrams of alloy systems. Many intermetallic systems form several compounds, generally not obeying common simple stoichiometric rules, which are often homogeneous in a certain range of compositions. The stability and extension of these phases are conveniently presented through phase diagrams. . Selected aspects of intermetallics structural chemistry, with emphasis on the solid state. The general structural characteristics of intermetallic phases are considered, with attention to nomenclature and to alternative and complementary methods of presenting crystal-chemical data. A brief account is given of derivative and degenerate structures, modular aspects of crystal structures, and of a few special groups of alloys such as quasicrystals and amorphous alloys. A number of selected structural prototypes with typical features, their possible grouping in structural "familieso and their distribution among different types of alloys are provided. . Intermetallic reactivity trends in the Periodic Table. Attention is given to a few selected elemental parameters such as electron configuration and valence electron number and to their changes along the Table, which act as reference factors of the intermetallic behaviour. As an example, the relationships are considered between crystal structure and the number of valence electrons per atom (or per formula) in various classes of compounds or solid solution phases. . Alloying behaviour systematics of intermetallic systems with a description of the intermetallic reactivity of each element, or group of elements, in the order of their position in the Periodic Table. For each pair of metallic elements, their capability to form intermediate phases is summarised by maps and schemes. . A description of small scale preparation methods of intermetallics. A number of interesting and significant peculiarities are, e.g., those related to their high melting points, insolubility in common solvents, etc. Systematic treatment of alloying behaviour Wide overview of intermetallic chemistry Illustrated, with many examples
Alloys. --- Metal complexes. --- Chemistry, Metallurgic. --- Alloys --- Metal complexes --- Chemistry, Metallurgic --- Chemistry --- Chemical & Materials Engineering --- Physical Sciences & Mathematics --- Engineering & Applied Sciences --- Materials Science --- Inorganic Chemistry --- Analytical Chemistry --- Metallurgic chemistry --- Chemistry, Technical --- Complex compounds --- Metallic alloys --- Metallic composites --- Metals --- Phase rule and equilibrium --- Amalgamation --- Microalloying
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