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The interest in what were known at first as Friedel-Crafts polymerisations started in the 1930s and grew rapidly from the 1940s under the influence of the US Synthetic Rubber Programme and from the 1950s as a result of the Ziegler-Natta and related polymer developments. From 1944 Professor Plesch has spent most of his academic life, studying the nature of what were later called cationic and, more recently still, cationoid polymerisations. The change of generic title reflects the growing insight into these reactions, much of which is due to Professor Plesch and his research group. Because of hi
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There are examples aplenty in the macroscopic world that demonstrate the form of objects directing their functions and properties. On the other hand, the fabrication of extremely small objects having precisely defined structures has only recently become an attractive challenge, which is now opening the door to nanoscience and nanotechnology.In the field of synthetic polymer chemistry, a number of critical breakthroughs have been achieved during the first decade of this century to produce an important class of polymers having a variety of cyclic and multicyclic topologies. These developments no
Cyclopolymerization. --- Topology. --- Analysis situs --- Position analysis --- Rubber-sheet geometry --- Geometry --- Polyhedra --- Set theory --- Algebras, Linear --- Cyclocopolymerization --- Ring closure and formation in polymerization --- Addition polymerization --- Ring formation (Chemistry)
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Gas Phase Combustion
Chemical thermodynamics --- fysicochemie --- Combustion --- Addition polymerization --- Chemical kinetics --- Chemical reaction [Rate of ] --- Chemical kinetics. --- Aromatic compounds. --- Inorganic compounds. --- Nonmetals. --- Chemical reactions. --- Cinétique chimique. --- Composés aromatiques. --- Réactions chimiques. --- Esters. --- Hydrolysis. --- Hydrolyse. --- Complex compounds. --- Organometallic compounds. --- Salts --- Composés complexes. --- Composés organométalliques. --- Sels --- Reactivity. --- Réactivité (chimie) --- Chemistry, Inorganic. --- Chimie inorganique. --- Composés inorganiques. --- Non-métaux. --- Decomposition (Chemistry) --- Organic compounds. --- Isomerization. --- Composés organiques. --- Décomposition (chimie) --- Isomérisation. --- Cinétique chimique. --- Composés aromatiques. --- Réactions chimiques. --- Décomposition (chimie) --- Composés organométalliques. --- Composés complexes. --- Réactivité (chimie) --- Composés inorganiques. --- Non-métaux. --- Composés organiques. --- Isomérisation. --- Combustion. --- Thermochemistry.
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This book addresses primarily the chemist and engineer in industrial research and process development, where competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such scale-up should be based on ""fundamental"" kinetics, that is, mathematics that reflect the elementary steps of which the reactions consist. The book forges fundamental kinetics into a practical tool by presenting new effective methods for elucidation of mechanisms and reduction of mathematical complexity without unacceptable sacrifice in accuracy.
Chemical kinetics. --- Decomposition (Chemistry) --- Chemistry, Inorganic. --- Organometallic compounds. --- Cinétique chimique. --- Chimie inorganique. --- Décomposition (chimie) --- Composés organométalliques. --- Excited state chemistry. --- Chimie des états excités. --- Esters. --- Hydrolysis. --- Hydrolyse. --- Aromatic compounds. --- Inorganic compounds. --- Nonmetals. --- Chemical reactions. --- Composés aromatiques. --- Réactions chimiques. --- Composés inorganiques. --- Non-métaux. --- Complex compounds. --- Salts --- Composés complexes. --- Sels --- Reactivity. --- Réactivité (chimie) --- Organic compounds. --- Isomerization. --- Composés organiques. --- Isomérisation. --- Electrodes --- Chemical reactions --- Electrochemistry --- Addition polymerization --- Chemical kinetics --- 541.135.5 --- chemische reactie --- elektrode --- kinetica --- 541.135.5 Electrodes and diaphragms, e.g. --- Electrodes and diaphragms, e.g. --- Addition polymerization. --- Chemical reaction, Kinetics of --- Chemical reaction, Rate of --- Chemical reaction, Velocity of --- Chemical reaction rate --- Chemical reaction velocity --- Kinetics, Chemical --- Rate of chemical reaction --- Reaction rate (Chemistry) --- Velocity of chemical reaction --- Chemical affinity --- Reactivity (Chemistry) --- Anionic polymerization --- Cationic polymerization --- Chain addition polymerization --- Chain-growth polymerization --- Free-radical polymerization --- Ionic polymerization --- Polymerization --- Reactions, Chemical --- Chemical processes --- Electric resistors --- Chemistry, Physical and theoretical --- 530.145 --- 530.145 Quantum theory --- Quantum theory --- 678.02:66.095.2 --- 678.02:66.095.2 Manufacturing processes and operations-:-Chemical technology. Chemical and related industries--?.095.2 --- Manufacturing processes and operations-:-Chemical technology. Chemical and related industries--?.095.2 --- 541.183 --- Surface chemistry --- Catalysis --- Corrosion and anti-corrosives --- Solid-liquid interfaces --- Liquid-solid interfaces --- Interfaces (Physical sciences) --- Anti-corrosive paint --- Atmospheric corrosion --- Metal corrosion --- Metals --- Rust --- Rustless coatings --- Chemical inhibitors --- Chemistry, Technical --- Fouling --- Materials --- Weathering --- Paint --- Protective coatings --- Waterproofing --- Activation (Chemistry) --- Chemistry, Surface --- Interfaces, Chemistry of --- Surface phenomena --- Surfaces (Chemistry) --- Capillarity --- Surface energy --- Surface tension --- Surfaces (Physics) --- 541.183 Contact systems. Adsorption. Surface chemistry --- Contact systems. Adsorption. Surface chemistry --- Corrosion --- Deterioration --- Surfaces --- Chemical reaction [Rate of ] --- Diffusion. --- Gases --- Liquids --- Physics --- Separation (Technology) --- Solution (Chemistry) --- Solutions, Solid --- Matter --- Packed towers --- Semiconductor doping --- Diffusion --- Properties --- Electrodes. --- Electrochemistry. --- 541.124 --- 539.219.3 --- Charge exchange. --- Tunneling (Physics) --- Penetration probability --- Quantum mechanical tunneling --- Tunnel effect --- Electric conductivity --- Solids --- Electron transfer --- Exchange, Charge --- Transfer, Electron --- Charge transfer --- Collisions (Nuclear physics) --- Chemical reaction, Conditions and laws of --- 539.219.3 Diffusion. Autodiffusion --- Diffusion. Autodiffusion --- 541.124 Chemical dynamics in general. Reaction mechanism in general --- 541.124 Limits of reactions --- Chemical dynamics in general. Reaction mechanism in general --- Limits of reactions --- Electrochemical analysis. --- Voltammetry. --- Voltametry --- Electrochemical analysis --- Analysis, Electrochemical --- Analysis, Electrolytic --- Electroanalysis --- Electrolytic analysis --- Analytical chemistry --- Quantitative
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This book has been written by a group of mathematicians and chemists whose common interest is in the complex dynamics of catalytic reactions. Based on developments in mathematical chemistry, a general theory is described that allows the investigation of the relationships between the kinetic characteristics of complex reactions and their detailed reaction mechanism. Furthermore, a comprehensive analysis is made of some typical mechanism of catalytic reactions, in particular for the oxidation of carbon monoxide on platinum metals. In fact, the book presents three kinetics: (a)
Addition polymerization. --- Addition reactions. --- Aliphatic compounds. --- Aromatic compounds. --- Carboxylic acids. --- Catalysis. --- Catastrophes (Mathematics). --- Chemical kinetics --- Chemical kinetics. --- Chemical reaction, Conditions and laws of. --- Chemical reactions. --- Chemistry --- Chemistry, Inorganic. --- Combustion. --- Corrosion and anti-corrosives. --- Decomposition (Chemistry). --- Diffusion. --- Electrochemistry. --- Electrodes. --- Elimination reactions. --- Energy transfer. --- Free radicals (Chemistry). --- Isomerism. --- Kinetics. --- Lipids. --- Organometallic compounds. --- Oxidation. --- Photochemistry. --- Polymerization. --- Polymers --- Polymers. --- Proton transfer reactions. --- Radiochemistry. --- Solid state chemistry. --- Solid-liquid interfaces. --- Substitution reactions. --- Surface chemistry. --- Mathematical models. --- physical. --- Deterioration. --- Cinétique chimique. --- Réactions chimiques. --- Chemical thermodynamics --- fysicochemie --- POLYMERIZATION --- Free radicals (Chemistry) --- Hydrocarbons --- Displacement reactions --- Replacement reactions --- Chemical reactions --- Reactions, Chemical --- Chemical processes --- Chemistry, Solid state --- Chemistry, Physical and theoretical --- Polymerization --- 541.64 --- 66.095.26 --- 541.64 Macromolecular chemistry. Polymerization products. Polycondensation products. Polyaddition products --- Macromolecular chemistry. Polymerization products. Polycondensation products. Polyaddition products --- 66.095.26 Polymerization --- Polymerisation --- Polymers and polymerization --- Synthesis of polymers --- Radicals (Chemistry) --- Free radical reactions --- Synthesis --- Thermochemistry. --- Thermodynamics --- Heat --- Thermochemistry --- Smoke --- Electrochemistry --- Electrodes --- 541.135.5 --- 541.138 --- 541.138 Electrochemical reactions --- Electrochemical reactions --- 541.135.5 Electrodes and diaphragms, e.g. --- Electrodes and diaphragms, e.g. --- Electric resistors --- 541.12 --- 541.12 Chemical mechanics --- Chemical mechanics --- Chemical reaction, Kinetics of --- Chemical reaction, Rate of --- Chemical reaction, Velocity of --- Chemical reaction rate --- Chemical reaction velocity --- Kinetics, Chemical --- Rate of chemical reaction --- Reaction rate (Chemistry) --- Velocity of chemical reaction --- Chemical affinity --- Reactivity (Chemistry) --- 541.128 --- 541.128 Catalysis. Acceleration and retardation of reactions by catalysts. Autocatalysis. Spontaneous combustion --- Catalysis. Acceleration and retardation of reactions by catalysts. Autocatalysis. Spontaneous combustion --- Dynamics. --- Dynamical systems --- Kinetics --- Mathematics --- Mechanics, Analytic --- Force and energy --- Mechanics --- Physics --- Statics --- Solid state chemistry --- 541.124-16 --- 541.124-16 Chemical dynamics in general. Reaction mechanism in general--?-16 --- 541.124-16 Limits of reactions--?-16 --- Chemical dynamics in general. Reaction mechanism in general--?-16 --- Limits of reactions--?-16 --- Catastrophes (Mathematics) --- Chemical reaction, Conditions and laws of --- #KVIV:BB --- #WSCH:MODS --- 515.16 --- 541.12.03 --- 541.12.03 Physical properties and constants. Mechanical and physical effects --- Physical properties and constants. Mechanical and physical effects --- 515.16 Topology of manifolds --- Topology of manifolds --- Conditions and laws of chemical reaction --- Reaction, Conditions and laws of (Chemistry) --- Physical laws --- Differentiable mappings --- Manifolds (Mathematics) --- Singularities (Mathematics) --- Electrodes. Cinétique. --- Elektroden. Kinetica. --- Chemical reaction [Rate of ] --- Low temperature research --- Cinétique chimique --- Chemistry, Technical. --- Chemical technology --- Industrial chemistry --- Technical chemistry --- Technology --- Chemical engineering --- Carboxylic Acids --- Chemistry, Physical --- 66.095.1 --- 541.124 --- 66.09 --- 541.124 Chemical dynamics in general. Reaction mechanism in general --- 541.124 Limits of reactions --- Chemical dynamics in general. Reaction mechanism in general --- Limits of reactions --- 66.095.1 Acylation. Esterification. Preparation of acid amides --- Acylation. Esterification. Preparation of acid amides --- Physical Chemistry --- Chemistries, Physical --- Physical Chemistries --- Carboxylic Acid --- Acid, Carboxylic --- Acids, Carboxylic --- 66.09 Specific chemical processes. Synthesis. Decomposition, addition and substitution processes. Catalysis --- Specific chemical processes. Synthesis. Decomposition, addition and substitution processes. Catalysis --- Oxidation --- Autoxidation --- Activation (Chemistry) --- Surface chemistry --- Graphic methods. --- Chemistry, Surface --- Interfaces, Chemistry of --- Surface phenomena --- Surfaces (Chemistry) --- Capillarity --- Surface energy --- Surface tension --- Surfaces (Physics) --- Esters. --- Organic compounds --- Combustion --- Physical. --- Cinétique chimique. --- Réactions chimiques.
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