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Diese Arbeit befasst sich mit der Untersuchung der katalytischen Partialoxidation (CPOX) höherer Kohlenwasserstoffe an mit Rhodium beschichteten Wabenkörpern. Die Reaktion ermöglicht die autotherme Generierung von Wasserstoff aus Kraftstoffen wie Benzin und Diesel zur Versorgung von Brennstoffzellen aus bestehenden Versorgungsnetzen.

Kohlenwasserstoffe --- Rhodium --- Partialoxidation --- Fuel Processing --- Wasserstoff

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This book collects articles published in a Special Issue of Molecules entitled "Organic Synthesis via Transition Metal-Catalysis". Transition metal catalysis is a powerful methodology for the direct synthesis of functionalized, high value-added molecules by the assembly of simple units in one step, and is acquiring increasing importance in modern organic synthesis. The book presents seven papers overall, two reviews and five original research articles, dealing with Pd-catalyzed arylation, Rh-catalyzed synthesis of organosulfur compounds, Rh-catalyzed reductive hydroformylation, V-catalyzed oxidation of hydrocarbons, and Zn-, Pd- and Rh-catalyzed cyclization processes, leading to heterocyclic derivatives.

palladium --- indole --- indomethacin --- C-H functionalization --- sulfoximide --- C–H activation --- benzothiazine --- rhodium --- catalysis --- synthesis --- organosulfur compounds --- S-S bond cleavage --- chemical equilibrium --- reversible reaction --- alkynes --- annulation --- benzimidazoxazinones --- heterocycles --- polycyclic heterocycles --- heterocyclization --- zinc --- direct arylation --- pincer complexes --- vanadium(IV) complexes --- biological activity --- catalytic properties --- 8-hydroxyquinoline --- cytotoxicity studies --- hydroformylation --- hydrogenation --- tandem reaction --- n/a --- C-H activation

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Kinetics and reactor modeling for heterogeneous catalytic reactions are prominent tools for investigating and understanding catalyst functionalities at nanoscale and the related rates of complex reaction networks. This book illustrates some examples related to the transformation of simple to more complex feedstocks, including different types of reactor designs, i.e., steady-state, transient plug flow reactors, and TAP reactors for which there is sometimes a strong gap in the operating conditions from ultra-high-vacuum to high-pressure conditions. In conjunction, new methodologies have emerged, giving rise to more robust microkinetics models. As exemplified, they include the kinetics and the dynamics of the reactors and span a large range of length and time scales. The objective of this Special Issue is to provide contributions that can illustrate recent advances and novel methodologies for elucidating the kinetics of heterogeneous reactions and the necessary multiscale approach for optimizing the reactor design. This book is dedicated to postgraduate and scientific researchers, and experts in heterogeneous catalysis. It may also serve as a source of original information for the elaboration of lessons on catalysis for Master students.

microkinetics --- n/a --- internal effectiveness factor --- FTIR spectroscopy --- automation --- power-law --- AEIR method --- promoter --- TAP reactor --- rhodium --- Temkin model --- mechanism analysis --- H2S --- N2O --- catalytic decomposition --- cracking --- 1 --- 2 --- methanol-to-olefins (MTO) --- zeolite --- ZSM-23 --- kinetic model --- pilot-scale fixed-bed reactor --- methane --- effective diffusion coefficient --- SAPO-18 --- kinetics --- alkali metal --- ZSM-5 --- digitalization --- gas-phase oxidation --- kinetic modeling --- temporal analysis of products --- selective oxidation --- Methyl Ethyl Ketone --- amorphous calcium phosphate --- reactor modeling --- HNO3 --- 3-Butadiene --- transient kinetics --- catalytic combustion --- cobalt mixed oxide --- 3-Butanediol dehydration --- ammonia decomposition --- heats of adsorption --- Pd/?-Al2O3 --- SAPO-34 --- Langmuir–Hinshelwood --- hierarchical graphite felts

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This Special Issue on “Catalysts for Syngas Production”, included in the Catalysts open access journal, shows new research about the development of catalysts and catalytic routes for syngas production, and the optimization of the reaction conditions for the process. This issue includes ten articles about the different innovative processes for syngas production. Synthesis gas (or syngas) is a mixture of hydrogen and carbon monoxide, with different chemical composition and H2/CO molar ratios, depending on the feedstock and production technology used. Syngas may be obtained from alternative sources to oil, such as natural gas, coal, biomass, organic wastes, etc. Syngas is a very good intermediate for the production of high value compounds at the industrial scale, such as hydrogen, methanol, liquid fuels, and a wide range of chemicals. Accordingly, efforts should be made on the co-feeding of CO2 with syngas, as an alternative for reducing greenhouse gas emissions. In addition, more syngas will be required in the near future, in order to satisfy the demand for synfuels and high value chemicals.

x%Co-Ni/Ce-Al2O3 --- steam reforming --- regeneration --- thermal stability --- anti-coking ability --- carbon --- combined Co–Fe species --- deactivation --- hydrogen production --- methane decomposition --- Ni catalysts --- combustion method --- dry reforming of methane --- RWGS reaction --- improved stability --- CH4 --- CeO2 --- dry reforming --- MgO --- Ni --- TiO2 --- syngas production --- hydrogen sulfide --- carbon dioxide --- Ni-Mo sulfide semiconductor --- non-thermal plasma --- methane steam reforming --- bench scale --- effectiveness factor --- Sulfur tolerant water gas shift catalyst --- steam/gas ratio --- Mo–Co/alkali/Al2O3 catalyst --- catalyst deactivation --- syngas --- H2 production --- Hydrogen --- Low Temperature Steam Reforming --- Rh4(CO)12 cluster --- microemulsion synthesis --- CeZr oxide --- Zr oxide --- heterogeneous catalysis --- solar thermochemical --- iridium catalyst --- rhodium catalyst --- catalytic cracking --- ethylene --- carbon nanofilaments --- hydrogen --- n/a --- combined Co-Fe species --- Mo-Co/alkali/Al2O3 catalyst

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Objects of nanotechnology such as micro- and nanoparticles are very interesting due to their unique properties. This reprint will be useful to scientists of diverse backgrounds, i.e., material science, organic and inorganic chemistry, biochemistry, and biology.

electropolymerization --- poly(Azure B) --- poly(proflavine) --- DNA sensor --- doxorubicin determination --- electrochemical impedance spectroscopy --- calix[4]arene --- NHC complex --- Suzuki–Miyaura coupling --- DPPC vesicles --- heparin/protamine particles --- hepatocyte --- intravenous injection --- lacZ protein --- nanoparticles --- protein delivery --- self-assembling --- antiviral agent --- nanoparticle --- coronavirus --- viral mechanism of entry --- antiviral mechanism --- therapeutic approaches --- SARS-CoV-2 --- COVID-19 --- polyol synthesis --- rhodium nanoparticles --- surfactants --- role of additives --- morphology control --- toxicity --- bio-imaging --- X-ray fluorescence --- contrast agent --- XFCT --- nanomaterials --- 2D nanostructures --- thiacalix[4]arene --- terpenoids --- geraniol --- X-ray crystal analysis --- 2D monomolecular-layer nanosheets --- polymorphism --- silica --- polystyrene --- maghemite supraparticles --- patchy particles --- seeded-growth emulsion polymerization --- solvent-induced self-assembly --- pillar[5]arene --- tetrazole --- drug delivery systems --- fluorescein --- ceria --- nanorods --- nanosheets --- nanozyme --- biomolecule --- template --- catalysis --- anti-oxidant --- oxygen radicals --- lithium iron phosphate --- hydrothermal synthesis --- heating rate --- morphology --- crystallinity and purity --- polyelectrolyte multilayers --- encapsulation --- calcium carbonate --- drug delivery --- shrinkage --- layered oxides --- perovskites --- bismuth titanates --- exfoliation --- coating --- silver nanoparticles --- AgNPs --- synthesis --- separation --- purification --- n/a --- Suzuki-Miyaura coupling