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This Special Issue of "Applications of SERS" for Nanomaterials is a collection of articles which is representative of much of the current research being undertaken in the field of Surface-Enhanced Raman Scattering (SERS) spectroscopy. SERS is a fascinating, multidisciplinary field of scientific study which combines elements from chemistry, physics, material science, and engineering. Essentially, SERS is a molecular spectroscopy technique by which a measurable Raman signal for molecules on metal and semiconductor surfaces is generated through the interaction of laser light, absorbed molecules, and structured nanomaterial surfaces. This Special Issue contains an article regarding the fabrication of metal nanostructured Ag-Cu chips for SERS chemical analysis and the electromagnetic properties of Ag, Au, and Al nano-tips for use in the SERS imaging technique for tip-enhanced Raman Scattering (TERS). In another article, SERS spectra were simulated using density Functional Theory (DFT/TD-DFT) for the N3 dye molecule on a TiO2 nanocluster, which can be compared to experimental SERS spectra found in studies of Dye-Sensitized Solar Cells (DSSCs). In two other articles, the SERS photoinduced charge-transfer mechanism was studied experimentally in wide-bandgap semiconductors regarding molecules on ZrO2 and a composite system with molecules that linked Au nanorods and a CuO2 shell. An example of the use of SERS in solid-state physics is shown in an article which examined the effect of oxygen vacancy defects in MO3 on the SERS mechanism. Finally, this Special Issue contains two noteworthy examples of SERS applications for biochemical and chemical analysis. One paper addresses the detection of the COVID-19 coronavirus SARS-CoV-2 using SERS, and the other examines a SERS assay of the notorious herbicide glyphosate. In these papers, nanomaterials all served as the enhancing substrate, while some acted as the physical-chemical system which was being investigated.

Raman spectroscopy. --- Raman effect, Surface enhanced.

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Raman spectroscopy has a number of applications in various fields including material science, physics, chemistry, biology, geology, and medicine. This book illustrates necessary insight and guidance in the field of Raman spectroscopy with detailed figures and explanations. This presents deep understanding of new techniques from basic introduction to the advance level for scientists and engineers. The chapters cover all major aspects of Raman spectroscopy and its application in material characterization with special emphasis on both the theoretical and experimental aspects. This book is aimed to provide solid foundation of Raman spectroscopy to the students, scientists, and engineers working in various fields as mentioned above.

Raman spectroscopy. --- CARS spectroscopy --- Coherent anti-Stokes Raman spectroscopy --- Spectroscopy, Raman --- Spectrum analysis --- Spectroscopy --- Physical Sciences --- Engineering and Technology --- Chemistry --- Physical Chemistry

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The conversion of lignocellulosic biomass into renewable fuels and other commodities has provided an appealing alternative towards supplanting global dependence on fossil fuels. The suitability of multitudes of plants for deconstruction to useful precursor molecules and products is currently being evaluated. These studies have probed a variety of phenotypic traits, including cellulose, non-cellulosic polysaccharide, lignin, and lignin monomer composition, glucose and xylose production following enzymatic hydrolysis, and an assessment of lignin-carbohydrate and lignin-lignin linkages, to name a few. These quintessential traits can provide an assessment of biomass recalcitrance, enabling researchers to devise appropriate deconstruction strategies. Plants with high polysaccharide and lower lignin contents have been shown to breakdown to monomeric sugars more readily. Not all plants contain ideal proportions of the various cell wall constituents, however. The capabilities of biotechnology can alleviate this conundrum by tailoring the chemical composition of plants to be more favorable for conversion to sugars, fuels, etc. Increases in the total biomass yield, cellulose content, or conversion efficiency through, for example, a reduction in lignin content, are pathways being evaluated to genetically improve plants for use in manufacturing biofuels and bio-based chemicals. Although plants have been previously domesticated for food and fiber production, the collection of phenotypic traits prerequisite for biofuel production may necessitate new genetic breeding schemes. Given the plethora of potential plants available for exploration, rapid analytical methods are needed to more efficiently screen through the bulk of samples to hone in on which feedstocks contain the desired chemistry for subsequent conversion to valuable, renewable commodities. The standard methods for analyzing biomass and related intermediates and finished products are laborious, potentially toxic, and/or destructive. They may also necessitate a complex data analysis, significantly increasing the experimental time and add unwanted delays in process monitoring, where delays can incur in significant costs. Advances in thermochemical and spectroscopic techniques have enabled the screening of thousands of plants for different phenotypes, such as cell-wall cellulose, non-cellulosic polysaccharide, and lignin composition, lignin monomer composition, or monomeric sugar release. Some instrumental methods have been coupled with multivariate analysis, providing elegant chemometric predictive models enabling the accelerated identification of potential feedstocks. In addition to the use of high-throughput analytical methods for the characterization of feedstocks based on phenotypic metrics, rapid instrumental techniques have been developed for the real-time monitoring of diverse processes, such as the efficacy of a specific pretreatment strategy, or the formation of end products, such as biofuels and biomaterials. Real-time process monitoring techniques are needed for all stages of the feedstocks-to-biofuels conversion process in order to maximize efficiency and lower costs by monitoring and optimizing performance. These approaches allow researchers to adjust experimental conditions during, rather than at the conclusion, of a process, thereby decreasing overhead expenses. This Frontiers Research Topic explores options for the modification of biomass composition and the conversion of these feedstocks into to biofuels or biomaterials and the related innovations in methods for the analysis of the composition of plant biomass, and advances in assessing up- and downstream processes in real-time. Finally, a review of the computational models available for techno-economic modeling and lifecycle analysis will be presented.

biomass --- NIMS --- pretreatment --- high-throughput --- Proteomics --- transgenic --- Raman spectroscopy --- Biofuels --- Agave --- sugarcane

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This work presents the application of organic semiconductor distributed feedback laser as free-space excitation source in Raman spectroscopy. Surface-enhanced Raman scattering effect is exploited to improve the detection sensitivity. The SERS conditionis achiedved by using substrates consisting of gold-coated polymeric nanopillar arrays. The organic-laser-excited SERS measurements are applied to verify the concentration variation of biomolecule adenosine in aqueous solutions.

Lab-on-Chiporganic semiconductor --- lab-on-a-chip --- oberflächenverstärkte Raman-Spektroskopie --- Organischer Halbleiter --- DFB-laser --- DFB-Laser --- surface-enhanced Raman spectroscopy

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Sample preparation is and will always be the most important step in chemical analysis. Numerous techniques, methods, methodologies, and approaches are published in the literature offering a wide range of analytical tools to the lab practitioner. Analytical scientists all over the world are trying to develop protocols for a plethora of analytes in various sample matrices. In the last decade, sample pre-treatment advances have followed green chemistry and green analytical chemistry demands, focusing on miniaturization and automation, using the least possible amount of organic solvents. The question is how far we have been till now, and what the future perspectives are. To answer this question, analytical chemists were invited to share their experience in the field and report on the recent advances in sample-preparation approaches. The outcome of our invitation was eleven excellent manuscripts, including four review articles and seven original research articles in the first edition of the Special Issue “Sample Preparation-Quo Vadis: Current Status of Sample Preparation Approaches”.The second edition is a collection of ten significant contributions to the field of sample preparation. It includes two highly interesting and comprehensive review articles and eight innovative research articles.

Research & information: general --- Chemistry --- Analytical chemistry --- sample preparation --- matrix solid-phase dispersion --- salting-out --- homogenous liquid-liquid extraction --- bisphenol --- bee pollen --- tricyclic antidepressants --- urine samples --- bar adsorptive microextraction (BAμE) --- novel sorbent phases --- biomaterials waste --- flotation sampling technology --- GC-MS --- amino acids --- chocolate --- derivatization --- HPLC --- fluorescence --- automation --- flow injection --- inductively coupled plasma --- sol-gel --- solid-phase extraction --- metals --- molecular imprinted polymer --- interaction mechanism --- template-monomer interaction --- MIP-template interaction --- microwave-assisted extraction --- tocopherols --- phenolics --- flavonoids --- authenticity --- HPLC-UV --- bismuth oxide --- API particle size --- API morphology --- film-coated tablets --- Raman spectroscopy --- ImageJ --- tablet disintegration --- green extraction techniques --- microextraction techniques --- biological samples --- food samples --- environmental samples --- carbaryl --- cassia bark (Senna siamea Lam.) --- smartphone-based digital image analysis --- 1-naphthol --- peroxidase enzyme --- raman spectroscopy --- carriers --- sample holders --- gold layer --- cuvette --- ethanol --- urine --- volatile compounds --- biological fluids --- n/a