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The book opens with a general overview of the constitution and reactivity of organomagnesium compounds, followed by information on handling them and on their detection and estimation. Throughout, practical aspects aswell as principles are emphasized.The chapters on the synthesis of organomagnesium compounds cover the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes, as well as the traditional preparation of Grignard reagents. Preparations by metallation and metal-halogen exchanges are also included, as are newer methods such as
Organomagnesium compounds. --- Organic compounds --- Composés organiques --- Synthesis. --- Synthèse --- 547.057 --- 546.46 --- Organic chemistry--?.057 --- Magnesium Mg --- 546.46 Magnesium Mg --- 547.057 Organic chemistry--?.057 --- Composés organiques --- Synthèse --- Grignard reagents. --- Grignard reaction --- Chemical tests and reagents --- Organomagnesium compounds --- Magnesium organic compounds --- Magnesium compounds --- Organometallic compounds --- Grignard reagents --- ORGANIC COMPOUNDS --- MAGNESIUM COMPOUNDS --- ORGANOMETALLIC COMPOUNDS --- PREPARATION --- REACTIONS
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In 1912, the Chemistry Nobel Prize was awarded for the discovery of the so-called Grignard reagents. Nowadays, many transition metal variants are developed to modify reactivity and selectivity of the C-C bond formation reaction. The Grignard reaction is one of the fundamental organometallic reactions, often used in alcohol syntheses. With transition metals like iron, cobalt and nickel or with noble metals like copper, silver and palladium, modern Grignard reagents can be designed in reactivity, selectivity and functional group tolerance. This book, written by international experts, presents an overview on timely Grignard chemistry involving transition metals.
Grignard reagents. --- Chemical tests and reagents. --- Transition metal catalysts. --- Chemical bonds. --- Bonds, Chemical --- Chemical structure --- Chemistry, Physical and theoretical --- Overlap integral --- Quantum chemistry --- Valence (Theoretical chemistry) --- Metal catalysts --- Chemical reagents --- Reagents, Chemical --- Indicators and test-papers --- Grignard reaction --- Chemical tests and reagents --- Organomagnesium compounds --- Grignard Reaction. --- Organic Chemistry. --- Reactivity. --- Transition Metals.
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