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This book addresses primarily the chemist and engineer in industrial research and process development, where competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such scale-up should be based on ""fundamental"" kinetics, that is, mathematics that reflect the elementary steps of which the reactions consist. The book forges fundamental kinetics into a practical tool by presenting new effective methods for elucidation of mechanisms and reduction of mathematical complexity without unacceptable sacrifice in accuracy.
Chemical kinetics. --- Decomposition (Chemistry) --- Chemistry, Inorganic. --- Organometallic compounds. --- Cinétique chimique. --- Chimie inorganique. --- Décomposition (chimie) --- Composés organométalliques. --- Excited state chemistry. --- Chimie des états excités. --- Esters. --- Hydrolysis. --- Hydrolyse. --- Aromatic compounds. --- Inorganic compounds. --- Nonmetals. --- Chemical reactions. --- Composés aromatiques. --- Réactions chimiques. --- Composés inorganiques. --- Non-métaux. --- Complex compounds. --- Salts --- Composés complexes. --- Sels --- Reactivity. --- Réactivité (chimie) --- Organic compounds. --- Isomerization. --- Composés organiques. --- Isomérisation. --- Electrodes --- Chemical reactions --- Electrochemistry --- Addition polymerization --- Chemical kinetics --- 541.135.5 --- chemische reactie --- elektrode --- kinetica --- 541.135.5 Electrodes and diaphragms, e.g. --- Electrodes and diaphragms, e.g. --- Addition polymerization. --- Chemical reaction, Kinetics of --- Chemical reaction, Rate of --- Chemical reaction, Velocity of --- Chemical reaction rate --- Chemical reaction velocity --- Kinetics, Chemical --- Rate of chemical reaction --- Reaction rate (Chemistry) --- Velocity of chemical reaction --- Chemical affinity --- Reactivity (Chemistry) --- Anionic polymerization --- Cationic polymerization --- Chain addition polymerization --- Chain-growth polymerization --- Free-radical polymerization --- Ionic polymerization --- Polymerization --- Reactions, Chemical --- Chemical processes --- Electric resistors --- Chemistry, Physical and theoretical --- 530.145 --- 530.145 Quantum theory --- Quantum theory --- 678.02:66.095.2 --- 678.02:66.095.2 Manufacturing processes and operations-:-Chemical technology. Chemical and related industries--?.095.2 --- Manufacturing processes and operations-:-Chemical technology. Chemical and related industries--?.095.2 --- 541.183 --- Surface chemistry --- Catalysis --- Corrosion and anti-corrosives --- Solid-liquid interfaces --- Liquid-solid interfaces --- Interfaces (Physical sciences) --- Anti-corrosive paint --- Atmospheric corrosion --- Metal corrosion --- Metals --- Rust --- Rustless coatings --- Chemical inhibitors --- Chemistry, Technical --- Fouling --- Materials --- Weathering --- Paint --- Protective coatings --- Waterproofing --- Activation (Chemistry) --- Chemistry, Surface --- Interfaces, Chemistry of --- Surface phenomena --- Surfaces (Chemistry) --- Capillarity --- Surface energy --- Surface tension --- Surfaces (Physics) --- 541.183 Contact systems. Adsorption. Surface chemistry --- Contact systems. Adsorption. Surface chemistry --- Corrosion --- Deterioration --- Surfaces --- Chemical reaction [Rate of ] --- Diffusion. --- Gases --- Liquids --- Physics --- Separation (Technology) --- Solution (Chemistry) --- Solutions, Solid --- Matter --- Packed towers --- Semiconductor doping --- Diffusion --- Properties --- Electrodes. --- Electrochemistry. --- 541.124 --- 539.219.3 --- Charge exchange. --- Tunneling (Physics) --- Penetration probability --- Quantum mechanical tunneling --- Tunnel effect --- Electric conductivity --- Solids --- Electron transfer --- Exchange, Charge --- Transfer, Electron --- Charge transfer --- Collisions (Nuclear physics) --- Chemical reaction, Conditions and laws of --- 539.219.3 Diffusion. Autodiffusion --- Diffusion. Autodiffusion --- 541.124 Chemical dynamics in general. Reaction mechanism in general --- 541.124 Limits of reactions --- Chemical dynamics in general. Reaction mechanism in general --- Limits of reactions --- Electrochemical analysis. --- Voltammetry. --- Voltametry --- Electrochemical analysis --- Analysis, Electrochemical --- Analysis, Electrolytic --- Electroanalysis --- Electrolytic analysis --- Analytical chemistry --- Quantitative
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This book has been written by a group of mathematicians and chemists whose common interest is in the complex dynamics of catalytic reactions. Based on developments in mathematical chemistry, a general theory is described that allows the investigation of the relationships between the kinetic characteristics of complex reactions and their detailed reaction mechanism. Furthermore, a comprehensive analysis is made of some typical mechanism of catalytic reactions, in particular for the oxidation of carbon monoxide on platinum metals. In fact, the book presents three kinetics: (a)
Addition polymerization. --- Addition reactions. --- Aliphatic compounds. --- Aromatic compounds. --- Carboxylic acids. --- Catalysis. --- Catastrophes (Mathematics). --- Chemical kinetics --- Chemical kinetics. --- Chemical reaction, Conditions and laws of. --- Chemical reactions. --- Chemistry --- Chemistry, Inorganic. --- Combustion. --- Corrosion and anti-corrosives. --- Decomposition (Chemistry). --- Diffusion. --- Electrochemistry. --- Electrodes. --- Elimination reactions. --- Energy transfer. --- Free radicals (Chemistry). --- Isomerism. --- Kinetics. --- Lipids. --- Organometallic compounds. --- Oxidation. --- Photochemistry. --- Polymerization. --- Polymers --- Polymers. --- Proton transfer reactions. --- Radiochemistry. --- Solid state chemistry. --- Solid-liquid interfaces. --- Substitution reactions. --- Surface chemistry. --- Mathematical models. --- physical. --- Deterioration. --- Cinétique chimique. --- Réactions chimiques. --- Chemical thermodynamics --- fysicochemie --- POLYMERIZATION --- Free radicals (Chemistry) --- Hydrocarbons --- Displacement reactions --- Replacement reactions --- Chemical reactions --- Reactions, Chemical --- Chemical processes --- Chemistry, Solid state --- Chemistry, Physical and theoretical --- Polymerization --- 541.64 --- 66.095.26 --- 541.64 Macromolecular chemistry. Polymerization products. Polycondensation products. Polyaddition products --- Macromolecular chemistry. Polymerization products. Polycondensation products. Polyaddition products --- 66.095.26 Polymerization --- Polymerisation --- Polymers and polymerization --- Synthesis of polymers --- Radicals (Chemistry) --- Free radical reactions --- Synthesis --- Thermochemistry. --- Thermodynamics --- Heat --- Thermochemistry --- Smoke --- Electrochemistry --- Electrodes --- 541.135.5 --- 541.138 --- 541.138 Electrochemical reactions --- Electrochemical reactions --- 541.135.5 Electrodes and diaphragms, e.g. --- Electrodes and diaphragms, e.g. --- Electric resistors --- 541.12 --- 541.12 Chemical mechanics --- Chemical mechanics --- Chemical reaction, Kinetics of --- Chemical reaction, Rate of --- Chemical reaction, Velocity of --- Chemical reaction rate --- Chemical reaction velocity --- Kinetics, Chemical --- Rate of chemical reaction --- Reaction rate (Chemistry) --- Velocity of chemical reaction --- Chemical affinity --- Reactivity (Chemistry) --- 541.128 --- 541.128 Catalysis. Acceleration and retardation of reactions by catalysts. Autocatalysis. Spontaneous combustion --- Catalysis. Acceleration and retardation of reactions by catalysts. Autocatalysis. Spontaneous combustion --- Dynamics. --- Dynamical systems --- Kinetics --- Mathematics --- Mechanics, Analytic --- Force and energy --- Mechanics --- Physics --- Statics --- Solid state chemistry --- 541.124-16 --- 541.124-16 Chemical dynamics in general. Reaction mechanism in general--?-16 --- 541.124-16 Limits of reactions--?-16 --- Chemical dynamics in general. Reaction mechanism in general--?-16 --- Limits of reactions--?-16 --- Catastrophes (Mathematics) --- Chemical reaction, Conditions and laws of --- #KVIV:BB --- #WSCH:MODS --- 515.16 --- 541.12.03 --- 541.12.03 Physical properties and constants. Mechanical and physical effects --- Physical properties and constants. Mechanical and physical effects --- 515.16 Topology of manifolds --- Topology of manifolds --- Conditions and laws of chemical reaction --- Reaction, Conditions and laws of (Chemistry) --- Physical laws --- Differentiable mappings --- Manifolds (Mathematics) --- Singularities (Mathematics) --- Electrodes. Cinétique. --- Elektroden. Kinetica. --- Chemical reaction [Rate of ] --- Low temperature research --- Cinétique chimique --- Chemistry, Technical. --- Chemical technology --- Industrial chemistry --- Technical chemistry --- Technology --- Chemical engineering --- Carboxylic Acids --- Chemistry, Physical --- 66.095.1 --- 541.124 --- 66.09 --- 541.124 Chemical dynamics in general. Reaction mechanism in general --- 541.124 Limits of reactions --- Chemical dynamics in general. Reaction mechanism in general --- Limits of reactions --- 66.095.1 Acylation. Esterification. Preparation of acid amides --- Acylation. Esterification. Preparation of acid amides --- Physical Chemistry --- Chemistries, Physical --- Physical Chemistries --- Carboxylic Acid --- Acid, Carboxylic --- Acids, Carboxylic --- 66.09 Specific chemical processes. Synthesis. Decomposition, addition and substitution processes. Catalysis --- Specific chemical processes. Synthesis. Decomposition, addition and substitution processes. Catalysis --- Oxidation --- Autoxidation --- Activation (Chemistry) --- Surface chemistry --- Graphic methods. --- Chemistry, Surface --- Interfaces, Chemistry of --- Surface phenomena --- Surfaces (Chemistry) --- Capillarity --- Surface energy --- Surface tension --- Surfaces (Physics) --- Esters. --- Organic compounds --- Combustion --- Physical. --- Cinétique chimique. --- Réactions chimiques.
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