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This contribution presents an analytical and a numerical model for predicting the effective thermal conductivity of porous electrode coatings as a function of microstructure parameters. Both models account for the morphological parameters and the thermal bulk materials of the constitutive cell components. The results of both models have been successfully verified against each other and validated with literature data as well as own experimental measurements.
Mechanical engineering & materials --- thermal conductivity --- thermal transport properties --- porous electrodes --- lithium-ion cell --- lithium-ion battery --- Wärmeleitfähigkeit --- thermische Transporteigenschaften --- poröse Elektroden --- Lithium-Ionen Zelle --- Lithium-Ionen Batterie
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In the present work, lithium-ion battery cathodes and battery half-cells are numerically investigated. Of main interest is the influence of the calendering of an electrode during its manufacture on the mechanically induced changes in the microstructure and the resulting performance characteristics of a cell. In particular, the influence of varying particle shape and plastic material properties is considered.
Mechanical engineering & materials --- Lithium-Ionen-Batterien --- Diskrete Elemente --- Mechanik --- Lithium-Ion-Batteries --- discrete elements --- mechanics
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In this work, the influence of compaction of LiNi1/3Co1/3Mn1/3O2 and graphite-based electrodes is characterized electrochemically at current rates between C/20 and 5C in a wide porosity range from uncompacted states to porosities < 20%. From the determined capacitances, gravimetric and volumetric considerations, among others, are presented in Ragone plots and correlated with the microstructural analysis findings.
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The focus of this work is on the modelling of the degradation behaviour of conventional lithium-ion cells with graphite/NMC electrodes in conjunction with electrolytes based on LiPF6 in organic solvents. The potential for improvements of parameterization methods dealing with physical-chemical aging effects and simulation studies for optimization of the battery lifetime is shown. In the process of model parameterization mostly data-based as well as non-invasive analysis methods are used.
Mechanical engineering & materials --- Lithium-Ionen-Zelle --- Batterie --- Elektrofahrzeug --- Degradationsmechanismen --- Lebensdauerprädiktion --- lithium-ion cell --- battery --- electric vehicle --- degradation mechanism --- lifetime prediction
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In this work the production of a thin film of lithium lanthanum titanate by tape casting for use in a lithium ion solid state battery is described. The influence of the composition of the slip on its flow properties is investigated. The layers produced are characterized both individually and in connection with a composite anode made of lithium titanate. Their suitability for use in a solid-state battery is demonstrated.
Mechanical engineering & materials --- Keramik --- Foliengießen --- Festkörperelektrolyt --- Lithium-Ionen-Batterie --- Lithium-Lanthan-Titanat --- ceramics --- tape casting --- solid electrolyte --- lithium ion battery --- lithium lanthanum titanate
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Chemistry, Analytic --- Chemistry, Inorganic --- Qualitative --- Chemistry. --- 543.061 --- 543.7 --- -Chemistry, Inorganic --- Inorganic chemistry --- Analysis, Chemical --- Analytical chemistry --- Chemical analysis --- 543.7 Analysis of inorganic substances --- Analysis of inorganic substances --- 543.061 Analytical chemistry--?.061 --- Analytical chemistry--?.061 --- Anionen --- Anorganische analyse --- Anorganische chemie --- 543.063 --- Ionen --- 546 --- Kationen --- 546 Inorganic chemistry --- 543.063 Analytical chemistry--?.063 --- Analytical chemistry--?.063 --- Chemistry --- Inorganic compounds --- Qualitative analysis (Chemistry) --- Qualitative chemical analysis --- Chemistry, Inorganic. --- Kwalitatieve anorganische analyse. --- Qualitative. --- Chimie analytique --- Chimie inorganique --- Qualitative analytical chemistry --- Analytic chemistry --- Chemistry, Analytic - Qualitative --- CHEMISTRY, ANALYTIC --- CHEMISTRY, INORGANIC --- QUALITATIVE
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