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Bestimmung der thermischen Transporteigenschaften poröser Elektroden von Lithium-Ionen Batterien
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ISBN: 1000136047 3731511193 Year: 2021 Publisher: Karlsruhe KIT Scientific Publishing

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Abstract

This contribution presents an analytical and a numerical model for predicting the effective thermal conductivity of porous electrode coatings as a function of microstructure parameters. Both models account for the morphological parameters and the thermal bulk materials of the constitutive cell components. The results of both models have been successfully verified against each other and validated with literature data as well as own experimental measurements.


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Modellierung der Mechanik und der effektiven Transporteigenschaften von partikulären Kathoden sowie deren Einfluss auf die elektrochemische Performance von Lithium-Ionen-Batterien
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ISBN: 1000143718 3731511746 Year: 2022 Publisher: Karlsruhe KIT Scientific Publishing

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In the present work, lithium-ion battery cathodes and battery half-cells are numerically investigated. Of main interest is the influence of the calendering of an electrode during its manufacture on the mechanically induced changes in the microstructure and the resulting performance characteristics of a cell. In particular, the influence of varying particle shape and plastic material properties is considered.


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Einfluss der Kompaktierung auf die Elektrodenmikrostruktur und elektrochemische Performance bei Lithium-Ionen-Zellen
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ISBN: 1000131644 3731510987 Year: 2021 Publisher: Karlsruhe KIT Scientific Publishing

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In this work, the influence of compaction of LiNi1/3Co1/3Mn1/3O2 and graphite-based electrodes is characterized electrochemically at current rates between C/20 and 5C in a wide porosity range from uncompacted states to porosities < 20%. From the determined capacitances, gravimetric and volumetric considerations, among others, are presented in Ragone plots and correlated with the microstructural analysis findings.


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Modellierung von Lithium-Ionen-Batterien zur Lebensdauerprädiktion unter besonderer Berücksichtigung des Anodenüberhangeffekts
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ISBN: 1000139455 3731511398 Year: 2022 Publisher: Karlsruhe KIT Scientific Publishing

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The focus of this work is on the modelling of the degradation behaviour of conventional lithium-ion cells with graphite/NMC electrodes in conjunction with electrolytes based on LiPF6 in organic solvents. The potential for improvements of parameterization methods dealing with physical-chemical aging effects and simulation studies for optimization of the battery lifetime is shown. In the process of model parameterization mostly data-based as well as non-invasive analysis methods are used.


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Herstellung dünner Folien aus Lithium-Lanthan-Titanat zur Anwendung als Festkörperelektrolyt
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ISBN: 1000105152 3731510081 Year: 2022 Publisher: Karlsruhe KIT Scientific Publishing

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Abstract

In this work the production of a thin film of lithium lanthanum titanate by tape casting for use in a lithium ion solid state battery is described. The influence of the composition of the slip on its flow properties is investigated. The layers produced are characterized both individually and in connection with a composite anode made of lithium titanate. Their suitability for use in a solid-state battery is demonstrated.

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