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Fire resistant polymers --- Nanocomposites (Materials) --- Nanocomposite materials --- Nanostructured composite materials --- Nanostructured composites --- Composite materials --- Nanostructured materials --- Fire retardant polymers --- Flame retardant polymers --- Fire resistant materials --- Polymers --- Fire resistant polymers.
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Sustainable development has become a great concern in modern society. The authors of this brief describe how one strategy to reach this objective is to replace oil-based materials with bio-based materials. They emphasize the great efforts that have been made to synthesize new bio-based polymers or additives or to replace glass fibers by natural fibers in composites. Flame retardancy is one of the most desired properties for many applications in wires and cables, building, transport, electric and electronic devices. The authors of this fascinating and timely brief summarize this important field in three parts. The flame retardancy of biobased polymers, the flame retardancy of natural fibers composites, and the synthesis and efficiency of biobased flame retardants.
Materials science. --- Polymers. --- Chemical engineering. --- Sustainable development. --- Biomaterials. --- Materials Science. --- Polymer Sciences. --- Sustainable Development. --- Industrial Chemistry/Chemical Engineering. --- Fire resistant polymers. --- Fire retardant polymers --- Flame retardant polymers --- Fire resistant materials --- Polymers --- Chemistry, Industrial --- Engineering, Chemical --- Industrial chemistry --- Engineering --- Chemistry, Technical --- Metallurgy --- Development, Sustainable --- Ecologically sustainable development --- Economic development, Sustainable --- Economic sustainability --- ESD (Ecologically sustainable development) --- Smart growth --- Sustainable development --- Sustainable economic development --- Economic development --- Polymere --- Polymeride --- Polymers and polymerization --- Macromolecules --- Biocompatible materials --- Biomaterials --- Medical materials --- Medicine --- Biomedical engineering --- Materials --- Biocompatibility --- Prosthesis --- Environmental aspects --- Polymers . --- Bioartificial materials --- Hemocompatible materials --- Biomaterials (Biomedical materials)
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This thesis investigates the early ignition behavior of polymer/clay nanocomposites, which are perceived as potential eco-friendly flame retardant systems. It examines the correlation between clay structural chemistry and high-temperature transformations with clay-assisted decomposition of organic macromolecules. In particular, it investigates the unique effects of metal ions like Mg2+, Al3+ and Fe3+ that are inherent in clays (smectite) on the combustion and thermo-oxidative decomposition of polyamide 6. The results indicate that metal ions present on/in montmorillonite platelets have preferential reactivity towards peroxy/alkoxy groups during polyamide 6 thermal decomposition. Lastly, a simple solution in the form of a physical coating on clay surface is proposed, based on the role of polymer–clay interfacial interaction.
Fire resistant polymers. --- Nanocomposites (Materials) --- Combustion. --- Materials science. --- Polymers. --- Engineering --- Ceramics. --- Glass. --- Composites (Materials). --- Composite materials. --- Materials Science. --- Ceramics, Glass, Composites, Natural Materials. --- Materials Engineering. --- Polymer Sciences. --- Materials. --- Nanocomposite materials --- Nanostructured composite materials --- Nanostructured composites --- Composite materials --- Nanostructured materials --- Fire retardant polymers --- Flame retardant polymers --- Fire resistant materials --- Polymers --- Polymere --- Polymeride --- Polymers and polymerization --- Macromolecules --- Engineering—Materials. --- Polymers . --- Composites (Materials) --- Multiphase materials --- Reinforced solids --- Solids, Reinforced --- Two phase materials --- Materials --- Amorphous substances --- Ceramics --- Glazing --- Ceramic technology --- Industrial ceramics --- Keramics --- Building materials --- Chemistry, Technical --- Clay
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The book provides practical recommendations for creation of fire retardant materials with an increased service life. The enhanced fire resistance seen in these materials is based on the regularities of the chemical and physicochemical interaction of the components of intumescent composition in the process of thermolytic synthesis of heat-insulating char-foamed layers. The aim of fire protection of various objects with intumescent materials is to create a heat-insulating charred layer on the surface of structural elements; this layer can withstand high temperatures and mechanical damage which are typical during fires. The authors describe the contribution of basic components (melamine, pentaerythritol, ammonium polyphosphate), additional components (chlorinated paraffin, urea, cellulose, carbon nano additives, etc.) and polymer binders of intumescent compositions on the process of charring. The technological aspects of manufacturing, application and operation of fire retardant intumescent compositions, which can be useful for organizations that produce and use fire retardant materials, are also described.
Polymers . --- Fire prevention. --- Building materials. --- Materials—Surfaces. --- Thin films. --- Polymer Sciences. --- Fire Science, Hazard Control, Building Safety. --- Building Materials. --- Surfaces and Interfaces, Thin Films. --- Films, Thin --- Solid film --- Solid state electronics --- Solids --- Surfaces (Technology) --- Coatings --- Thick films --- Architectural materials --- Architecture --- Building --- Building supplies --- Buildings --- Construction materials --- Structural materials --- Materials --- Fire safety --- Fires --- Prevention of fires --- Fire protection engineering --- Public safety --- Insurance engineering --- Polymere --- Polymeride --- Polymers and polymerization --- Macromolecules --- Fires and fire prevention --- Prevention --- Fire resistant materials. --- Building, Fireproof. --- Fire resistant polymers. --- Fire retardant polymers --- Flame retardant polymers --- Fire resistant materials --- Polymers --- Fireproof building --- Building materials --- Fire prevention --- Fire retardant materials --- Flame resistant materials --- Fireproofing --- Protection
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Metal nanoparticles/polymers hybrid materials have significantly contributed to the develop of nanotechnology. Moreover, these hybrid materials can respond to stimuli (e.g., pH, temperature, light, magnetic field) or self-degrade in a controlled manner to release metal nanoparticles or therapeutics encapsulated. Functional and structural hybrid materials provide opportunities for creative fields, remarkable properties, and future advanced applications. This Special Issue focuses on highlighting the progress of new hybrid materials, based on metal nanoparticles and polymers, their design, preparation, functionalization, characterization, and advanced applications.
Technology: general issues --- History of engineering & technology --- Mining technology & engineering --- alginate --- non-chloride in situ preparation --- nano-cuprous oxide --- flame-retardant --- mechanism --- nanoparticles --- polyethylene glycol --- Tween 80 --- cytotoxicity --- hemotoxicity --- primary cell culture --- medical applications --- SERS --- PMMA --- AgNPs --- in-situ --- adenosine --- methylene-blue --- smart hybrid materials --- properties of nanoparticles–reinforced polymers --- biotechnology --- cellulose acetate --- porosity --- ionic radius --- water-pressure --- silver nanoparticles --- nanocellulose --- engineered nanomaterials --- water monitoring --- water treatment --- ecosafety --- ecotoxicology --- eco-design --- polymersomes --- vesicles --- drug-delivery --- ultrafast laser --- plasmonic --- nanobubble --- fragmentation --- zero valent copper --- Cu0-containing hybrid anion exchanger --- Cu2O reduction --- ascorbic acid as reducer --- n/a --- properties of nanoparticles-reinforced polymers
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This Special Issue covers manufacturing of a smart polymer composites via choice of ingredients, such as polymer, filler, and additives, as well as their unique composition. It also covers the smart processing of polymer composites, which is influenced by the choice of mixers, processing condition, processing technique, etc.
Technology: general issues --- thermoplastic polyurethane --- expanded bead --- supercritical CO2 foaming --- expansion ratio --- resilience --- hardness --- poly(lactic acid) --- lignin --- maleic anhydride --- chemical modification --- 3D printing filament --- SEBS --- membrane --- water uptake --- impedance spectroscopy --- ionic conductivity --- phlogopite --- natural rubber (NR) --- ethylene-propylene-diene monomer rubber (EPDM) --- mechanical properties --- compatibility --- nylon 6 --- polyketone --- chain extender --- hydrogen bonding --- chain branching --- chain crosslinking --- melt viscosity --- shape memory polymer --- NIR light responsive --- semicrystalline maleated polyolefin elastomer --- polyaniline --- melt blending --- adhesive --- fluorosilicone --- thermal conductivity --- magnesium oxide --- boron nitride --- syntactic foams --- hyperbranched polymer --- polyamide 6 --- hollow glass microsphere --- lubricant --- compatibilizer --- composites --- silica --- silane --- hydrolysis --- interfacial adhesion --- zinc mechanism --- hybrid flame retardant materials --- influence of gypsum --- minimum total heat release --- n/a
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Natural polysaccharides, such as cellulose and chitin, possess unique hierarchical nanoarchitectures that can never be artificially reconstructed, and their nano-organized structures are involved in the hidden materials functions with great potential. Pioneering the emerging functions of nano-organized polysaccharides will break through to achieve the Sustainable Development Goals.
Technology: general issues --- chitin nanofiber --- deacetylated chitin --- nanopaper --- thermal diffusivity --- powder electroluminescent device --- cellulose nanofiber --- paper electronic device --- paper-based light-emitting device --- dehydrogenative polymer --- enzymatic radical coupling --- lignin --- nanocellulose --- microsphere --- TEMPO-oxidized cellulose nanofiber --- chitosan−ZnCl2 complex --- crystal structure --- X-ray fiber diffraction --- nanofibrillated bacterial cellulose --- bacterial cellulose --- peritoneally disseminated gastric cancer --- doxorubicin --- intraperitoneal chemotherapy --- hemicellulose --- xylan --- nanocrystal --- Pickering emulsion --- cellulose derivatives --- cellulose nanocrystal --- cholesteric liquid crystal --- functional materials --- material form --- cellulose nanofibers --- nanocomposite --- xerogel --- flame-retardant --- polydopamine doping --- pyrolysis --- 3D porous nanocarbon --- supercapacitor --- surface carboxylation --- surface deacetylation --- cell culture scaffold --- skin repair --- wound healing --- biomedical applications --- functional nanocomposite --- aqueous process --- sol–gel --- hydrogels --- aerogels --- freeze-drying --- cryogels --- n/a --- sol-gel
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Materials with sound-absorbing or sound-insulating properties have been rapidly evolving in recent years for several reasons. On one side, there is the ever-increasing awareness of the adverse effects that noise and lack of acoustic comfort may have on human health. On the other, the availability of more sophisticated fabrication techniques, calculation methods, and new materials, has stimulated researchers and, more and more frequently, industry to develop customized materials with improved properties.This book collects contributions from different researchers covering several topics. A group of papers investigated the use of 3D printing to obtain perforated panels with extended frequency response, as well as to ideally design an optimized cell distribution to print (when fabrication techniques will make it possible) a porous material with a broader sound absorption. The role of the geometrical and microstructural properties of granular molecular sieves is investigated by another paper. A second group of papers focused its attention on the use of natural or recycled components to create a skeleton of porous materials with good sound-absorbing properties and low environmental impact. Cigarette butts, recycled textile waste, and almond skins have been investigated by different authors.Finally, the last batch of papers included a review of sound insulation properties of innovative concretes and two research papers focussing on a numerical and experimental analysis of wood plastic composite (WPC) panels and on the potential of semi-active solutions employing compressible constrained layer damping (CCLD).
Technology: general issues --- perforated panel --- absorber array --- low frequency absorption --- sound absorber --- cigarette butts --- sustainable material --- recycling --- variability analysis --- textile waste --- biopolymers --- sound absorption --- sustainable materials --- circular economy --- polyurethane foam --- thermal property --- phase change material --- flame retardant --- perforated plates with extended tubes --- porous materials --- periodic absorber --- wood plastic composite --- transmission loss --- radiation efficiency --- orthotropic panel --- wavenumber analysis --- molecular sieve pellets --- impedance tube --- sound transmission loss --- semi-active damping --- sandwich panel --- morphing structure --- compressible constrained layer damping --- composite materials --- anisotropic materials --- optimized absorption --- diffuse field --- graded properties --- agro-waste --- hygrothermal performances --- concrete --- noise --- acoustic properties --- sound-absorbing --- sound-reflecting --- n/a
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The combination of functional polymers with inorganic nanostructured compounds has become a major area of research and technological development owing to the remarkable properties and multifunctionalities deriving from their nano and hybrid structures. In this context, polyhedral oligomeric silsesquioxanes (POSSs) have increasing importance and a dominant position with respect to the reinforcement of polymeric materials. Although POSSs were first described in 1946 by Scott, these materials, however, have not immediately been successful if we consider that, starting from 1946 and up to 1995, we find in the literature 85 manuscripts regarding POSSs; which means that less than two papers per year were published over 50 years. Since 1995, we observe an exponential growth of scientific manuscripts concerning POSSs. It is changing from an annual average of 20 manuscripts for the period 1995–2000 to an annual average of about 400 manuscripts, with an increase of 2800%. The introduction of POSSs inorganic nanostructures into polymers gives rise to polymer nanostructured materials (PNMs) with interesting mechanical and physical properties, thus representing a radical alternative to the traditional filled polymers or polymer compositions.
graphene oxide --- n/a --- lithium ion battery --- liquefied --- polypropylene --- silsesquioxanes --- self-assembly behaviors --- nanocomposites --- Octavinyl-POSS --- polyimide --- thermal properties --- polyhedral oligomeric silsesquioxane-based ionic liquids --- aqueous self-assembly --- bi-functional POSS --- blends --- low refractive material --- cellular structure --- mechanism analysis --- morphology --- flame retardant --- hydrogels --- mercapto-modified --- damping --- POSS nanoparticles --- phthalonitrile polymers --- mechanical properties --- flame-retardant mechanism --- thiol-ene ‘click’ reaction --- POSS --- poly(?-caprolactone) --- siloxane-silsesquioxane resins --- polyhedral oligomeric silsesquioxane (POSS) --- surface properties --- fluoropolymer --- thiol–ene “click” reaction --- Monomethacryloxy POSS --- monodisperse --- thermogravimetry --- OLEDs --- fluorescent sensors --- double-decker-shaped silsesquioxane (DDSQ) --- dielectric constant --- composites --- organic-inorganic hybrids --- poly(?-caprolactone) nanocomposite --- POSS-based copolymer --- organic-inorganic crosslinking --- optoelectronics --- flame retardancy --- cone calorimeter tests --- lauryl methacrylate --- octa-ammonium POSS --- nitroaromatic explosives --- phthalonitrile-polyhedral oligomeric silsesquioxane copolymers --- cyanate ester --- thermoplastic polyurethane --- sodium alginate --- giant surfactant --- benzoxazine --- thermal stability --- temperature responsiveness --- polymerization kinetics --- mechanical performance --- Si@C anode --- ridgid polyurethane foams --- epoxy resin --- grafting synthesis --- direct synthesis --- filler --- bridged silsesquioxane --- hydrophobic modification --- dispersion --- polyhedral oligomeric silsesquioxanes --- anchor effect --- thiol-ene 'click' reaction --- thiol-ene "click" reaction
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This book summarizes comprehensively many recent technical research accomplishments in the area of flame retardant research. It presents mainly flame retardant studies of polymer blends, composites and nanocomposites such as rubber, thermosets and thermoplastics. This book discusses different types of flame retardant using in polymers especially nanocomposites, as well as the role and chemistry. Leading researchers from industry, academy, government and private research institutions across the globe contribute to this book. Academics, researchers, scientists, engineers and students in research and development will benefit from an application-oriented book that helps them to find solutions to both fundamental and applied problems.
Materials Science. --- Characterization and Evaluation of Materials. --- Engineering Thermodynamics, Heat and Mass Transfer. --- Polymer Sciences. --- Nanotechnology. --- Polymers. --- Engineering. --- Surfaces (Physics). --- Polymères --- Ingénierie --- Nanotechnologie --- Surfaces (Physique) --- Materials. --- Chemical & Materials Engineering --- Engineering & Applied Sciences --- Materials Science --- Fireproofing agents. --- Fire resistant polymers. --- Nanocomposites (Materials) --- Nanocomposite materials --- Nanostructured composite materials --- Nanostructured composites --- Fire retardant polymers --- Flame retardant polymers --- Chemical fire retardants --- Fire resisting agents --- Fire retardants --- Flame retardants --- Flameproofing agents --- Materials science. --- Thermodynamics. --- Heat engineering. --- Heat transfer. --- Mass transfer. --- Composite materials --- Nanostructured materials --- Fire resistant materials --- Polymers --- Fire prevention --- Polymere --- Polymeride --- Polymers and polymerization --- Macromolecules --- Construction --- Industrial arts --- Technology --- Molecular technology --- Nanoscale technology --- High technology --- Physics --- Surface chemistry --- Surfaces (Technology) --- Polymers . --- Mass transport (Physics) --- Thermodynamics --- Transport theory --- Heat transfer --- Thermal transfer --- Transmission of heat --- Energy transfer --- Heat --- Mechanical engineering --- Chemistry, Physical and theoretical --- Dynamics --- Mechanics --- Heat-engines --- Quantum theory --- Material science --- Physical sciences
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