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This computational study investigates diverse bonding situations in nanostructures (carbon nanotubes, fullerenes, metal compounds) spanning a broad range of energies. Weak, dispersive interactions and covalent metal-ligand and metal-metal bonding are examined. The results of efficient density functional calculations are compared to those of correlated wavefunction calculations on model systems. This rigorous validation is crucial in evaluating the balance between computational cost and accuracy.

open-cage fullerenes --- single-walled carbon nanotubes --- subvalent aluminium and magnesium compounds --- computational chemistry --- nanostructures

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The book opens with a general overview of the constitution and reactivity of organomagnesium compounds, followed by information on handling them and on their detection and estimation. Throughout, practical aspects aswell as principles are emphasized.The chapters on the synthesis of organomagnesium compounds cover the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes, as well as the traditional preparation of Grignard reagents. Preparations by metallation and metal-halogen exchanges are also included, as are newer methods such as

Organomagnesium compounds. --- Organic compounds --- Composés organiques --- Synthesis. --- Synthèse --- 547.057 --- 546.46 --- Organic chemistry--?.057 --- Magnesium Mg --- 546.46 Magnesium Mg --- 547.057 Organic chemistry--?.057 --- Composés organiques --- Synthèse --- Grignard reagents. --- Grignard reaction --- Chemical tests and reagents --- Organomagnesium compounds --- Magnesium organic compounds --- Magnesium compounds --- Organometallic compounds --- Grignard reagents --- ORGANIC COMPOUNDS --- MAGNESIUM COMPOUNDS --- ORGANOMETALLIC COMPOUNDS --- PREPARATION --- REACTIONS