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To appreciate the chemistry and physical properties of complexes of the transition series, an understanding of metal-ligand interactions applied to complexes of the d-block is needed. Metal Ligand Bonding aims to provide this through an accessible, detailed, non-mathematical approach.Initial chapters detail the crystal-field model, using it to describe the use of magnetic measurements to distinguish complexes with different electronic configurations and geometries. Subsequent chapters look at the molecular orbital theory of transition metal complexes using a pictorial approach. Bonding in octa

Metal bonding. --- Transition metals. --- Basic Sciences. Chemistry --- Chemistry (General). --- 541.574 --- 541.574 Metallic bonds --- Metallic bonds --- Metal bonding --- Transition metals --- Transition elements --- Metals --- Sealing (Technology) --- Bonding

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541.5 <05> --- Valencies. Bonds. Affinity--Tijdschriften --- Periodicals --- Chemical bonds. --- Binding Sites --- Chemistry, Analytical --- Chemistry --- Life Sciences --- General and Others --- Biochemistry --- Biology --- 541.5 <05> Valencies. Bonds. Affinity--Tijdschriften --- Chemical bonds --- Liaisons chimiques --- 547.74 --- 541.574 --- 541.574 Metallic bonds --- Metallic bonds --- 547.74 Pyrroles in general --- Pyrroles in general --- Biochimie. (Mélanges) --- Biochemie. (Versch. onderwerpen)

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Internet Tiered Services: Theory, Economics, and Quality of Service (QoS) presents a theoretical framework for reasoning about and pricing Internet tiered services, and develops a practical algorithmic toolset for network providers to develop customized menus of service offerings. The material includes a comprehensive study of the design, sizing, and pricing of tiered structures for Internet services, and illustrates their potential in simplifying the operation of complex components such as packet schedulers. Specifically, the book addresses the following issues: Optimization of service tier selection and sizing, using fundamental concepts from location theory; several variants of the problem are considered, including deterministic vs. stochastic demands. Economic models for optimal pricing of service tiers that take into account simultaneously the (usually conflicting) objectives of users and providers. Models for optimizing "bundles of services," e.g., when a provider offers a service that includes both access bandwidth and data storage. Applications of tiered services in simplifying important QoS functions in the network, including fair packet scheduling. Internet Tiered Services: Theory, Economics, and Quality of Service is a useful resource for engineers in the fields of Internet services, economics, and quality of service (QoS) in network resource allocation.

Molecular theory --- 539.194 --- 541.574 --- 541.67 --- 541.67 Relation of chemical structure to electrical and magnetic properties --- Relation of chemical structure to electrical and magnetic properties --- 541.574 Metallic bonds --- Metallic bonds --- 539.194 Internal mechanics of molecules. Energy relationships. Vibration and rotation in molecules. Electronic levels. Bonds. Resonance energies, potentials. Nuclear coupling. Polarizability etc. --- Internal mechanics of molecules. Energy relationships. Vibration and rotation in molecules. Electronic levels. Bonds. Resonance energies, potentials. Nuclear coupling. Polarizability etc. --- Chemistry, Physical and theoretical --- Matter --- Internal mechanics of molecules. Energy relationships. Vibration and rotation in molecules. Electronic levels. Bonds. Resonance energies, potentials. Nuclear coupling. Polarizability etc --- Constitution --- Internet service providers --- Quality control. --- Prices. --- IAPs (Internet service providers) --- Internet access providers --- Internet service industry --- ISPs (Internet service providers) --- Internet industry --- Molecular theory. --- Telecommunication. --- Computer Communication Networks. --- Communications Engineering, Networks. --- Signal, Image and Speech Processing. --- Electric communication --- Mass communication --- Telecom --- Telecommunication industry --- Telecommunications --- Communication --- Information theory --- Telecommuting --- Electrical engineering. --- Computer communication systems. --- Signal processing. --- Image processing. --- Speech processing systems. --- Computational linguistics --- Electronic systems --- Modulation theory --- Oral communication --- Speech --- Telecommunication --- Singing voice synthesizers --- Pictorial data processing --- Picture processing --- Processing, Image --- Imaging systems --- Optical data processing --- Processing, Signal --- Information measurement --- Signal theory (Telecommunication) --- Communication systems, Computer --- Computer communication systems --- Data networks, Computer --- ECNs (Electronic communication networks) --- Electronic communication networks --- Networks, Computer --- Teleprocessing networks --- Data transmission systems --- Digital communications --- Information networks --- Cyberinfrastructure --- Electronic data processing --- Network computers --- Electric engineering --- Engineering --- Distributed processing