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Thanks to their outstanding hydrogen selectivity, palladium membranes have attracted extensive R&D interest. They are a potential breakthrough technology for hydrogen production and also have promising applications in the areas of thermochemical biorefining. This book summarises key research in palladium membrane technologies, with particular focus on the scale-up challenges. After an introductory chapter, Part one reviews the fabrication of palladium membranes. Part two then focuses on palladium membrane module and reactor design. The final part of the book reviews the operation of palladium
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Zur Bewertung der Umweltrelevanz der Kfz-emittierten PGE (Pt, Pd, Rh) ist das Verständnis ihres Verhaltens im Boden von grundlegender Bedeutung.In dieser Arbeit wurde das Sorptionsverhalten wasserlöslicher PGE an fünf typischen Bodenmineralen (Mn/Fe-Oxide, Kaolinit, Feldspat, Kalk, Quarz) untersucht.
Edelmetallkomplexe --- Adsorption --- Mobilität --- Rhodium --- Platinmetallverbindungen --- Umweltgefährdung --- Palladium
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Neuere Erkenntnisse zum Umsatzverhalten an Dieseloxidationskatalysatoren (DOCs) zeigen, dass das Umsatzverhalten von Schadstoffen vom Oxidationsgrad der verwendeten Edelmetallkatalysatoren abhängen kann. Dabei wird deutlich, dass sich der Oxidationsgrad bei typischen Abgaszusammensetzungen langsam und reversibel mit der Katalysatortemperatur ändert. Das kann bei periodischen Katalysatortemperaturänderungen zu einem ausgeprägten Hystereseverhalten führen. Bisherige Ergebnisse liegen insbesondere zum Verhalten der NO-Oxidation an Platin-Katalysatoren vor. Ziel der vorliegenden Arbeit ist es daher, die Untersuchungen auf seriennahe Pd- und PtPd-Mischkatalysatoren sowie auf andere abgastypische Schadstoffe, wie CO und Kohlenwasserstoffe, zu erweitern und dabei auch den Einfluss der Katalysatoralterung zu erfassen. Es wurde ein globalkinetisches Modell entwickelt und an die experimentellen Befunde angepasst. Dabei zeigte sich, dass es in der Regel möglich ist, das Umsatzverhalten bei reinen Pt- und Pd-Katalysatoren mit diesem örtlich eindimensionalen, makrokinetischen Zweiphasenmodell zutreffend zu beschreiben, wohingegen das Verhalten auf Pt/Pd-Mischkatalysatoren weniger gut simuliert werden kann. Dies ist vermutlich auf die heterogene Struktur der Pt/Pd-legierten Partikel zurückzuführen.
Chemistry. --- Deaktivierung --- Dieseloxidationskatalysator --- Hysterese --- Platin --- Palladium
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This comprehensive handbook will be an indispensable research tool for chemists. Handbook of Palladium Catalysed Organic Reactions provides a synoptic description of the main types of reactions which are catalyzed by Palladium and the mechanism which causes these reactions. Each reaction is presented in graphical form and classified according to the type of transformation involved.Other books covering the use of Palladium complexes as catalysts have been written, but the Handbook is the only to offer a synoptic view, showing the catalytic cycle of each reaction. This complete
Catalyseurs au palladium --- Chimie organique. --- Catalyse. --- Chemistry, Inorganic. --- Palladium catalysts. --- Catalysts --- Inorganic chemistry --- Chemistry --- Inorganic compounds
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Palladium compounds --- Palladium --- Platinum group --- Transition metal compounds --- Industrial applications. --- Metallurgy.
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"Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides describes the procedures and protocols related to the modification of nucleosides, nucleotides and oligonucleotides via Pd-mediated cross-coupling processes. The book highlights the growing area of nucleic acid modification and how Pd-mediated coupling reactions can assist this development. Users will find key synthetic protocols for these reactions in this latest volume in the Latest Trends in Palladium Chemistry series. As most of the research in the field of antiviral agents has centered on the use of modified nucleosides that have exhibited promising activity, this book provides an up-to-date reference for both professionals in industry and other interested parties" -- elsevier.com.
Palladium catalysts. --- Nucleosides. --- Nucleotides. --- Phosphonucleosides --- Nucleic acids --- Nucleotides --- Catalysts
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Das Ziel dieser Arbeit war die Entwicklung eines kontinuierlichen MOCVS/MOCVD-Verfahrens zur Generierung und Funktionalisierung von gasgetragenen, nanoskaligen Partikeln bei atmosphärischen Bedingungen und dessen Anwendung auf die Herstellung von Siliziumdioxid geträgerten Palladiumkatalysatoren (Pd/SiO2).
MOCVD-Verfahren --- Katalyse --- Funktionalisierung --- Siliziumdioxid --- Palladium --- Nanostrukturiertes Material --- Nanopartikel
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Palladium in Heterocyclic Chemistry
Descriptive organic chemistry --- Heterocyclic Compounds. --- 661.898 --- 546.98 --- 547.057 --- Organopalladium compounds --- Palladium catalysts --- Heterocyclic compounds --- -#WSCH:LOSH --- Cycloids, Mixed (Chemistry) --- Heteroatomic compounds --- Heterocycles --- Mixed cycloids (Chemistry) --- Organic cyclic compounds --- Catalysts --- Palladium organic compounds --- Organotransition metal compounds --- Palladium compounds --- Compounds, Heterocyclic --- Palladium --- Organic chemistry--?.057 --- Synthesis --- Polycyclic Compounds --- 547.057 Organic chemistry--?.057 --- 546.98 Palladium --- 661.898 Palladium compounds --- Heterocyclic Compounds --- #WSCH:LOSH --- Organopalladium compounds. --- Palladium catalysts. --- Synthesis.
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Palladium chemistry, despite its immaturity, has rapidly become an indispensable tool for synthetic organic chemists. Heterocycles are of paramount importance in the pharmaceutical industry and palladium chemistry is one of the most novel and efficient ways of making heterocycles. Today, palladium-catalyzed coupling is the method of choice for the synthesis of a wide range of biaryls and heterobiaryls. The number of applications of palladium chemistry to the syntheses of heterocycles has grown exponentially. These developments highlight the need for a monograph dedicated solely to the p
Heterocyclic compounds. --- Heterocyclic compounds - Synthesis. --- Heterocyclic compounds--Synthesis, Organopalladium compounds. --- Organopalladium compounds. --- Synthesis. --- Heterocyclic compounds --- Organopalladium compounds --- Inorganic Chemistry --- Organic Chemistry --- Chemistry --- Physical Sciences & Mathematics --- Synthesis --- Palladium organic compounds --- Organotransition metal compounds --- Palladium compounds --- Cycloids, Mixed (Chemistry) --- Heteroatomic compounds --- Heterocycles --- Mixed cycloids (Chemistry) --- Organic cyclic compounds --- Palladium catalysts.
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Find out how theoretical calculations are used to determine, elucidate and propose mechanisms for Pd-catalyzed C-C cross-coupling reactions in Max Garcia Melchor's outstanding thesis. Garcia Melchor investigates one of the most significant and useful types of reactions in modern organic synthesis; the Pd-cross coupling reaction. Due to its versatility, broad scope and selectivity under mild conditions, this type of reaction can now be applied in fields as diverse as the agrochemical and pharmaceutical industry. Garcia Melchor studies the reaction intermediates and transition states involved in the Negishi, the copper-free Sonogashira and the asymmetric version of Suzuki-Miyaura coupling. He also characterizes and provides a detailed picture of the associated reaction mechanisms. The author has won numerous prizes for this work which has led to over eight publications in internationally renowned journals.
Catalysts. --- Heterocyclic compounds -- Synthesis. --- Palladium catalysts. --- Chemistry --- Physical Sciences & Mathematics --- Inorganic Chemistry --- Physical & Theoretical Chemistry --- Organopalladium compounds. --- Organic reaction mechanisms. --- Mechanisms, Organic reaction --- Catalytic agents --- Palladium organic compounds --- Chemistry. --- Organic chemistry. --- Chemistry, Physical and theoretical. --- Catalysis. --- Theoretical and Computational Chemistry. --- Organic Chemistry. --- Reaction mechanisms (Chemistry) --- Catalysis --- Chemical inhibitors --- Organotransition metal compounds --- Palladium compounds --- Chemistry, Organic. --- Activation (Chemistry) --- Chemistry, Physical and theoretical --- Surface chemistry --- Organic chemistry --- Physical sciences --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Organic compounds --- Synthesis.
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