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Interfaces of solid materials play an increasingly important role when the size of active elements used in different areas of science and technology shrinks to the nanometer range. This has required development of analytical tools specifically sensitive to the properties of a material in the vicinity of its boundary with other phase (a heterojunction). The present book is the first to describe the basics of internal photoemission spectroscopy - a method based on the detection of electron transitions from one solid to another. This spectroscopy combines the interface sensitivity typical of conv

Photoelectron spectroscopy. --- Photoemission. --- Semiconductors --- Junctions.

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Photoelectron spectroscopy. --- Spectroscopy, Photoelectron --- Electron spectroscopy --- Molecular orbitals --- Molecular spectra --- Molecular spectroscopy --- Photoelectricity --- Spectrum analysis

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The second edition of Internal Photoemission Spectroscopy thoroughly updates this vital, practical guide to internal photoemission (IPE) phenomena and measurements. The book's discussion of fundamental physical and technical aspects of IPE spectroscopic applications is supplemented by an extended overview of recent experimental results in swiftly advancing research fields. These include the development of insulating materials for advanced SiMOS technology, metal gate materials, development of heterostructures based on high-mobility semiconductors, and more. Recent results concerning

Photoelectron spectroscopy. --- Photoemission. --- Semiconductors -- Junctions. --- Photoelectron spectroscopy --- Photoemission --- Semiconductors --- Chemistry --- Physics --- Physical Sciences & Mathematics --- Analytical Chemistry --- Light & Optics --- Junctions --- Junctions. --- Emission, Photoelectric --- External photoelectric effect --- Photoelectric effect, External --- Photoelectric emission --- Electrons --- Photoelectricity --- Junctions, Semiconductor --- Semiconductor interface --- Semiconductor interfaces --- Semiconductor junctions --- Interfaces (Physical sciences) --- Spectroscopy, Photoelectron --- Electron spectroscopy --- Molecular orbitals --- Molecular spectra --- Molecular spectroscopy --- Spectrum analysis --- Emission --- Interfaces

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This book provides the first complete and up-to-date summary of the state of the art in HAXPES and motivates readers to harness its powerful capabilities in their own research. The chapters are written by experts. They include historical work, modern instrumentation, theory and applications. This book spans from physics to chemistry and materials science and engineering. In consideration of the rapid development of the technique, several chapters include highlights illustrating future opportunities as well.

Physical & Theoretical Chemistry --- Atomic Physics --- Chemistry --- Physics --- Physical Sciences & Mathematics --- X-ray photoelectron spectroscopy. --- Electron spectroscopy for chemical analysis --- ESCA (Electron spectroscopy for chemical analysis) --- XPS (X-ray photoelectron spectroscopy) --- Photoelectron spectroscopy --- Spectroscopy. --- Surfaces (Physics). --- Atomic/Molecular Structure and Spectra. --- Spectroscopy/Spectrometry. --- Spectroscopy and Microscopy. --- Surfaces and Interfaces, Thin Films. --- Surface and Interface Science, Thin Films. --- Surface chemistry --- Surfaces (Technology) --- Analysis, Spectrum --- Spectra --- Spectrochemical analysis --- Spectrochemistry --- Spectroscopy --- Chemistry, Analytic --- Interferometry --- Optics --- Radiation --- Wave-motion, Theory of --- Absorption spectra --- Light --- Spectroscope --- Qualitative --- Atomic structure  . --- Molecular structure . --- Microscopy. --- Materials—Surfaces. --- Thin films. --- Interfaces (Physical sciences). --- Surfaces (Physics) --- Films, Thin --- Solid film --- Solid state electronics --- Solids --- Coatings --- Thick films --- Analysis, Microscopic --- Light microscopy --- Micrographic analysis --- Microscope and microscopy --- Microscopic analysis --- Optical microscopy --- Spectrometry --- Structure, Molecular --- Chemical structure --- Structural bioinformatics --- Structure, Atomic --- Atomic theory --- Analytical chemistry

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Jonelle Harvey’s thesis outlines two related experimental techniques which are utilised to investigate small halogenated molecules: threshold photoelectron spectroscopy and threshold photoelectron photoion coincidence techniques. All the experiments were conducted at the vacuum ultraviolet beamline of the Swiss Light Source, which is a synchrotron photon source offering easy tunability. In this thesis, three studies are presented which combine experimental and computational ab initio approaches. The first study involves the fast dissociation of halogenated methanes in order to construct a self-consistent thermochemical network. The second study investigates the fragmentations of fluoroethenes from timebombs, which break apart very slowly but explosively, to fast dissociators. The third study uncovers how vital conical interactions underpin both the results of photoelectron spectra and dissociation patterns.The details included in this work are useful for researchers in the same field as well as those readers wishing to obtain a solid introduction into the types of systems encountered in threshold photoelectron photoion coincidence spectroscopy.

Chemistry. --- Halogenation. --- Physical chemistry. --- Chemistry, Physical and theoretical. --- Atomic structure. --- Molecular structure. --- Spectra. --- Physical Chemistry. --- Atomic/Molecular Structure and Spectra. --- Theoretical and Computational Chemistry. --- Physical sciences --- Chemistry, Physical organic. --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Atomic structure  . --- Molecular structure . --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Structure, Molecular --- Chemical structure --- Structural bioinformatics --- Structure, Atomic --- Atomic theory --- Photoelectron spectroscopy. --- Dissociation. --- Halocarbons.