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This book covers the most important topics concerning cationic Ziegler-Natta and ring-opening metathesis polymerization of cycloolefins. The work describes the major pathways that cycloolefins can follow under the action of specific catalytic systems, essentially vinyl and ring-opening polymerization, both reaction types allowing the manufacture of distinct products with wide applicability in modern technologies. The comprehensive data available on this subject are logically and systematically selected and reviewed throughout 18 chapters, according to the basic catalytic processes involved, ty
Cycloalkenes. --- Ring-opening polymerization. --- Catalysis. --- Activation (Chemistry) --- Chemistry, Physical and theoretical --- Surface chemistry --- Polymerization --- Cycloolefins --- Alicyclic compounds --- Alkenes
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Creating antibacterial surfaces is the primary approach in preventing the occurrence and diffusion of clinical infections and foodborne diseases as well as in contrasting the propagation of pandemics in everyday life. Proper surface engineering can inhibit microorganism spread and biofilm formation, can contrast antimicrobial resistance (AMR), and can avoid cross-contamination from a contaminated surface to another and eventually to humans. For these reasons, antibacterial surfaces play a key role in many applications, ranging from biomedicine to food and beverage materials, textiles, and objects with frequent human contact. The incorporation of antimicrobial agents within a surface or their addition onto a surface are very effective strategies to achieve this aim and to properly modify many other surface properties at the same time. In this framework, this Special Issue collects research studying several materials and methods related to the antibacterial properties of surfaces for different applications and discussions about the environmental and human-safety aspects.
nanocomposite --- mechanical properties --- cytotoxicity --- nanosilica --- antibiotics --- drug loading --- electrodeposition --- halloysite nanotubes --- zinc --- metal nanoparticles --- titanium implants --- cellulose --- silver --- nanoparticle --- antibacterial --- composite --- thin film --- xanthan gum --- zinc oxide --- quorum sensing --- biofilm --- virulence --- S. marcescens --- C. violaceum --- proteins --- titanium dioxide --- functionalization --- hybrid composites --- antimicrobial coatings --- aluminum-doped zinc oxide (AZO) --- RF sputtering (RFS) --- supersonic cluster beam deposition (SCBD) --- silver nanoparticles --- atomic force microscopy (AFM) --- health --- biomedical applications --- food packaging --- antibacterial coating --- antimicrobial peptide --- plasma polymer --- LL 37 --- Magainin --- Parasin --- bacterial attachment --- polylactide --- photodynamic --- supramolecular systems --- micelles --- drug delivery --- copolymers --- ring opening polymerization --- aPDT --- BODIPY --- antimicrobial --- polycaprolactone (PCL) --- nanofibers --- electrospinning --- sputtering --- antiviral --- biomedical --- bioremediation --- antifouling --- metal ions --- graphene --- antibiotic resistance --- foams --- biomaterials --- n/a
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Thermoresponsive polymers, materials able to undergo sharp and often reversible phase separations in response to temperature stimuli, are introducing new paradigms in different fields, including medicine, advanced separations and oil and gas. In "Advances in Thermoresponsive Polymers", a clear picture of the frontiers reached in the understanding of the mechanistic behavior associated with temperature-induced phase separation, the influence of the polymer structure in regulating the macroscopic behavior of these materials and the latest applications for which thermoresponsive polymers show great potential is provided.
poly(N,N-diethylacrylamide) --- glycidyl methacrylate --- thermoresponsive copolymer --- α-chymotrypsin --- polymer-enzyme conjugate nanoparticle --- polymeric nanoparticles --- emulsion polymerization --- RAFT --- thermo-responsive polymers --- smart materials --- LCST --- phase diagram --- phase separation --- thermoresponsive star-shaped polymers --- poly-2-alkyl-2-oxazines and poly-2-alkyl-2-oxazolines --- aqueous solutions --- light scattering --- turbidimetry --- microcalorimetry --- aggregation --- dual-stimuli-responsive materials --- thin films --- out-of-equilibrium --- thermoresponsive --- oligo(ethylene glycol) --- OEGylated --- poly(amino acid) --- ring-opening polymerization --- post-polymerization modification --- Ugi reaction --- synthesis --- star-shaped macromolecules --- calix[n]arene --- block and gradient copolymers of poly-2-alkyl-2-oxazolines --- conformation --- thermoresponsibility --- self-organization --- poly-N-vinylcaprolactam --- thermoresponsive polymers --- polymer-protein conjugates --- controlled release --- temperature-sensitive polymers --- hydrogels --- stereocomplexation --- polylactic acid --- temperature/reduction --- self-recombination --- thermosensitive polymers --- enzyme complexation --- reversible inactivation --- UCST polymers --- stimuli-responsive polymers --- electronic paramagnetic resonance --- spin probe --- nitroxides --- coil to globule --- poly(L-lysine) --- N-isopropylacrylamide --- aza-Michael addition reaction --- thermo-responsive --- pH-responsive --- biodegradable polymer
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