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Flexible Polyurethane (PUR) foams have been used since the 1950s in textiles and furniture upholsteries, and in art and design objects that can now be found in museum collections. Composed from 'short-life' consumer materials, these objects present severe conservation problems as they age. This book presents an in-depth examination of the challenges presented by PUR foams; the case studies of preservation of two works by the artist Piero Gilardi; and a manual on preparing and applying a light stabilizing system that can protect new PUR foams from degrading and restore the flexibility of old foams.
Art --- Foam. --- Polyurethanes. --- Conservation and restoration. --- Flexible Polyurethane, art, design, conservation.
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Global concern about climate change caused by the exploitation of fossil fuels is encouraging the use of renewable energies. For instance, the European Union aims to be climate neutral by 2050. Biogas is an interesting renewable energy source due to its high calorific value. Today, biogas is mainly used for the production of electricity and heat by a combined heat and power engine. However, before its valorization, biogas needs to be desulfurized (H2S removal) to avoid corrosion and sulfur oxides emissions during its combustion. Biogas can be upgraded (CO2 removal) and used as vehicle fuel or injected into the natural gas grid. In the last 15 years, significant advances have occurred in the development of biological desulfurization processes. In this book with five chapters, the reader can find some of the latest advances in the biogas desulfurization and an overview of the state-of-the-art research. Three of them are research studies and two are reviews concerning the current state of biogas desulfurization technologies, economic analysis of alternatives, and the microbial ecology in biofiltration units. Biogas desulfurization is considered to be essential by many stakeholders (biogas producers, suppliers of biogas upgrading devices, gas traders, researchers, etc.) all around the world.
biotrickling filters --- in-situ biogas desulphurisation --- response surface methodology --- microbial ecology --- anoxic biotrickling filter --- desulfurization --- molecular techniques --- open-pore polyurethane foam --- anaerobic digestion --- autotrophic denitrification --- anoxic biofiltration --- Teflon --- biotrickling filter --- biogas --- desulphurisation --- H2S --- post-biogas desulphurisation --- hydrogen sulfide elimination --- removal process --- Ottengraf’s model --- packing material --- hydrogen sulfide --- open polyurethane foam --- sulfur-oxidizing bacteria --- anoxic --- PVC --- biofiltration --- PET
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Les répliques de biens de consommation que les artistes zurichois Peter Fischli et David Weiss se sont mis à exécuter dès 1991 oscillent entre une superficialité, dont Fredric Jameson a fait un trait définitoire du postmodernisme, et un épaississement matériel propre aux choses. Ces images d’artefacts, dont on ne peut attendre aucun des services que rendent leurs modèles, nous ramènent pourtant constamment à la lente fréquentation d’objets dans l’usage quotidien qui informe notre vie. S’attachant à examiner la place qu’elles occupent dans l’histoire de l’art contemporain et à décrire notamment la relation qu’elles entretiennent avec les productions artistiques, littéraires, théoriques des années 1960, ce livre est aussi bien une réflexion sur le temps, tel que les œuvres le construisent.
Art --- Peter Fischli --- David Weiss --- superficialité --- chose --- Postmodernisme --- intérieur --- image --- valeur d’usage --- simulacre --- Surrogate --- polyuréthane --- Fredric Jameson --- Roland Barthes --- Guy Debord --- Jean Baudrillard --- Jean Bazin --- Paul Thek --- Robert Watts --- Gabriel Orozco --- Rachel Whiteread --- Heidi Bucher --- Peter Fischli David Weiss --- superficiality --- thing --- Postmodernism --- interior --- value of use --- simulacrum --- polyurethane --- Peter Fischli David Weiss --- Objet --- Choses --- Superficialité --- Image --- Intérieur --- Jean Baudrillard --- Guy Debord --- Fredric Jameson
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A comprehensive account of the physical / mechanical behaviour of polyurethanes (PU´s) elastomers, films and blends of variable crystallinity. Aspects covered include the elasticity and inelasticity of amorphous to crystalline PUs, in relation to their sensitivity to chemical and physical structure. A study is made of how aspects of the constitutive responses of PUs vary with composition: the polyaddition procedure, the hard segment, soft segment and chain extender (diols and diamines) are varied systematically in a large number of systems of model and novel crosslinked andthermoplastic PUs. Results will be related to: microstructural changes, on the basis of evidence from x-ray scattering (SAXS and WAXS), and also dynamic mechanical analyses (DMA), differential scanning calorimetry (DSC) and IR dichroism. Inelastic effects will be investigated also by including quantitative correlations between the magnitude of the Mullins effect and the fractional energy dissipation by hysteresis under cyclic straining, giving common relations approached by all the materials studied. A major structural feature explored is the relationship between the nature of the hard segment (crystallising or not) and that of the soft segments. Crystallinity has been sometimes observed in the commercial PUs hard phase but this is usually limited to only a few percent for most hard segment structures when solidified from the melt. One particular diisocyanate, 4,4’-dibenzyl diisocyanate (DBDI) that, in the presence of suitable chain extenders ( diols or diamines), gives rise to significant degrees of crystallinity [i-iii] and this is included in the present work. Understanding the reaction pathways involved, in resolving the subtle morphological evolution at the nanometre level, and capturing mathematically the complex, large-deformation nonlinear viscoelastic mechanical behaviour are assumed to bring new important insights in the world basic research in polyurethanes and towards applied industrial research in this area.
Polyurethane elastomers. --- Polyurethanes -- Industrial applications. --- Polyurethane elastomers --- Elastomers --- Chemistry --- Chemical & Materials Engineering --- Physical Sciences & Mathematics --- Engineering & Applied Sciences --- Chemical Engineering --- Organic Chemistry --- Elastomers. --- Elastomeric materials --- Reinforced elastomers --- Urethane elastomers --- Chemistry. --- Polymers. --- Crystallography. --- Materials science. --- Polymer Sciences. --- Characterization and Evaluation of Materials. --- Polymers --- Plastics --- Rubber --- Surfaces (Physics). --- Crystallography and Scattering Methods. --- Physics --- Surface chemistry --- Surfaces (Technology) --- Leptology --- Physical sciences --- Mineralogy --- Polymere --- Polymeride --- Polymers and polymerization --- Macromolecules --- Polymers . --- Material science
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Advances in nanotechnology have boosted the development of more efficient materials, with emerging sectors (electronics, energy, aerospace, etc.) demanding novel materials to fulfill the complex technical requirements of their products. This is the case of polymeric foams, which may display good structural properties alongside functional characteristics through a complex composition and (micro)structure in which a gas phase is combined with rigid ones, mainly based on nanoparticles, dispersed throughout the polymer matrix. In recent years, there has been an important impulse in the development of nanocomposite foams, extending the concept of nanocomposites to the field of cellular materials. This, alongside developments in new advanced foaming technologies which have allowed the generation of foams with micro, sub-micro, and even nanocellular structures, has extended the applications of more traditional foams in terms of weight reduction, damping, and thermal and/or acoustic insulation to novel possibilities, such as electromagnetic interference (EMI) shielding. This Special Issue, which consists of a total of 22 articles, including one review article written by research groups of experts in the field, considers recent research on novel polymer-based foams in all their aspects: design, composition, processing and fabrication, microstructure, characterization and analysis, applications and service behavior, recycling and reuse, etc.
graphene oxide --- n/a --- microstructure --- multi-objective particle swarm optimization --- electromagnetic wave absorption --- polyamide --- lignin --- expandable microspheres --- surfactants --- aluminum microfibers --- biomaterials --- permittivity --- compression properties --- shock compression --- syntactic foams --- 1 --- impact wedge–peel test --- phenolic foams --- 3 --- foam extrusion --- energy conservation --- heat transfer --- heterogeneous nucleation --- polyurethane foam --- leaching test --- functional --- cellulose foam --- impact property --- foam injection molding --- itaconic acid --- composites --- foaming quality --- phosphorus flame retardants --- polymer waste --- metallic tube --- 5-benzene-trisamides --- polyurethane foam composites --- polyetherimide foams --- scCO2 --- Ethylene Propylene Diene Monomer --- thermal conductivity --- ethyl cellulose --- super critical CO2 --- thermal insulation --- cell nucleation --- crystalline --- polypropylene --- PZT --- burning characteristic --- foams --- quasi-static compression tests --- flame-retardant ABS microcellular foams --- nanotubes --- conductivity --- energy absorption capability --- intrinsic toughness --- ternary synergistic effect --- multilayers --- absorbent PMI foam --- semi-rigid polyurethane foams --- phosphorus --- EMI --- supramolecular additives --- MuCell® injection-molding foaming --- piezocomposite --- ultrasonication --- scCO2 foaming --- automobile structural adhesives --- thermogravimetric analysis --- rigid polyurethane foam --- failure mechanism --- mechanical properties --- multifunctional foams --- SANS --- fluoelastomer --- sound absorption coefficient --- acoustic performances --- functional foam --- foam morphology --- mechanical property --- polystyrene foams --- piezoelectric --- graphene --- Pluronic --- epoxy composite foam adhesive --- polymers --- flame retardancy --- core–shell rubber --- extrusion foaming --- equation of state --- cellulose nanofiber --- epoxy --- DOPO --- PUR --- grey relational analysis --- activation energies --- adjacent façade --- electrical conductivity --- impact wedge-peel test --- core-shell rubber --- adjacent façade
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Carbon-based nanomaterials such as carbon nanotubes, graphene and its derivatives, nanodiamond, fullerenes, and other nano-sized carbon allotropes have recently attracted a lot of attention among the scientific community due to their enormous potential for a wide number of applications arising from their large specific surface area, high electrical and thermal conductivity, and good mechanical properties. The combination of carbon nanomaterials with polymers leads to new nanocomposites with improved structural and functional properties due to synergistic effects. In particular, the properties of carbon-based polymer nanocomposites can be easily tuned by carefully controlling the carbon nanomaterial synthesis route and additionally the versatile synergistic interactions amongst the nanomaterials and polymers. This book provides selected examples of the most recent advances regarding carbon nanomaterial-reinforced polymeric composites. It includes the most representative types of polymeric matrices and covers aspects of new processing techniques, novel surface modifications of carbon nanomaterials and their applications in diverse fields, in particular in electronics and energy storage.
multi walled carbon nanotubes --- polyacrylonitrile --- nascent fiber --- thermal properties --- morphological structure --- nanocomposites --- graphene --- melt processing --- mechanical properties --- electrical conductivity --- electrostatic spraying --- multi-walled carbon nanotubes --- waterborne polyurethane coating --- dispersity --- surface hardness --- wear rate --- friction coefficient --- in-mold decoration injection molding --- microcellular injection molding --- surface quality --- warpage --- multiwalled carbon nanotube --- hyaluronic acid --- microfibers --- wet-spinning --- microstructures --- tensile properties --- Ag --- CNT --- flexible supercapacitor electrode --- polymer conductive film --- cellulose acetate membrane --- PANI --- graphene oxide --- hexamethylene diisocyanate --- nanocomposite --- thermal stability --- polydiphenylamine-2-carboxylic acid --- single-walled carbon nanotubes --- conjugated polymers --- in situ oxidative polymerization --- hybrid nanocomposites --- polypropylene --- carbon nanotube --- titanium dioxide --- reduced graphene oxide --- polyurethane foam --- flexible electronics --- pressure sensing --- polyethyleneimine --- thermoelectric properties --- carrier type --- Paal-Knorr reaction --- polyketone --- carbon nanotubes --- Diels-Alder --- click-chemistry --- hydrogen bonding --- self-healing --- re-workability --- recycling --- Joule heating --- flexible electrode --- cross-linked acrylamide/alginate --- tensile strength --- impedance spectroscopy --- polymer electrolyte --- Li-ion micro-batteries --- flexible anode --- pre-lithiation --- carbon-based polymer nanocomposite --- energy storage --- fuel cell --- electrochemical devices --- n/a
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Materials from renewable resources have attracted increasing attention in recent decades as a result of environmental concerns and due to the depletion of petroleum resources. Polymeric materials from renewable sources have a long history. They were used in ancient times and later accompanied the development of man and civilization. Currently, they are widespread in many areas of life and used, for example, in packaging and in the automotive, construction and pharmaceutical industries.The aim of this Special Issue is to highlight the progress in the manufacturing, characterization, and applications of environmentally friendly polymeric blends from renewable resources. The following aspects were investigated: (i) synthesis of composites based on natural llers; (ii) chemical modi cation of polymers or fillers in order to improve interfacial interactions; (iii) potential applications of the biobased materials.
lignin --- microspheres --- composites --- polymeric material --- fractionation --- porosity --- radiation grafting --- cotton linter --- phosphate adsorption --- dynamic studies --- bio-polyethylene --- barley straw --- thermomechanical fibers --- interface --- automotive industry --- natural fiber --- polypropylene --- stiffness --- curauá fibers --- microcrystalline cellulose (MCC) --- unsaturated polyester resins --- thermogravimetric analysis (TG) --- mechanical analysis --- dynamic mechanical analysis (DMA) --- LignoBoost® kraft lignin --- potentiometric sensors --- carbon nanotubes --- impedance spectroscopy --- transition metals --- rice nanofibers --- biocomposites --- casting --- mechanical properties --- thermal properties --- rigid polyurethane foams --- lignocellulosic materials --- filler --- chemical treatment --- mechanical characteristics --- pyrolysis process --- Caragana korshinskii biochar --- physicochemical properties --- adsorption characteristics --- nitrate nitrogen --- bio-oil --- polyurethanes --- hemp shives --- bio-filler --- oil impregnation --- sugar beet pulp --- thermal conductivity --- polyurethane composites --- lavender --- kaolinite --- hydroxyapatite --- high-ball milling process --- antibacterial activity --- wood–resin composites --- unsaturated polyester resin --- recycled PET --- wood flour --- renewable resources --- silver nanoparticles --- n/a --- curauá fibers --- wood-resin composites
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"Advances in Polyurethane Biomaterials brings together a thorough review of advances in the properties and applications of polyurethanes for biomedical applications. The first set of chapters in the book provides an important overview of the fundamentals of this material with chapters on properties and processing methods for polyurethane. Further sections cover significant uses such as their tissue engineering and vascular and drug delivery applications. Written by an international team of leading authors, the book is a comprehensive and essential reference on this important biomaterial"--
Chemical Engineering --- Chemical & Materials Engineering --- Engineering & Applied Sciences --- Polyurethanes. --- Biomedical materials. --- Biocompatible materials --- Biomaterials --- Medical materials --- Medicine --- Biomedical engineering --- Materials --- Biocompatibility --- Prosthesis --- Urethane polymers --- Polymers --- Urethanes --- Biocompatible Materials. --- Bioartificial Materials --- Hemocompatible Materials --- Bioartificial Material --- Biocompatible Material --- Biomaterial --- Hemocompatible Material --- Material, Bioartificial --- Material, Biocompatible --- Material, Hemocompatible --- Materials Testing --- Biomimetic Materials --- Regenerative Medicine --- Ostamer --- Pellethane --- Spandex --- Polyisocyanates --- Ostamers --- Pellethanes --- Polyisocyanate --- Polyurethane --- Spandices --- Bioartificial materials --- Hemocompatible materials --- Biomaterials (Biomedical materials)
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The utilization of bio-resourced macromolecules for polymer applications has been the subject of increasing interest, mainly for sustainability and functionality reasons. This Special Issue of Processes brings together nine papers from leading scientists and researchers active in the area of “Sustainable and Renewable Polymers, Processing, and Chemical Modifications”. The collected papers include seven original research and two review articles related to renewable feedstock for polymer applications, processes for the fabrication of renewable polymer-based nanomaterials, the design and modification of renewable polymers, and applications of renewable polymers. The journal Processes will continue to nurture progress in this field through its position as an open access platform.
ramie fabric --- nitroxide mediated polymerization --- polymerization --- chitosan --- n/a --- itaconate esters --- graft --- polysaccharide --- dust suppressant --- bio-filler --- recycled polyol --- specified risk materials --- glutaraldehyde --- lignin --- used printed circuit board --- pelletization --- soybean protein isolate modification --- functional materials --- viscoelasticity --- emulsion --- optimal concentration --- binder --- superhydrophobicity --- copolymerization --- Starch --- glycolysis --- analysis of dust suppression mechanism --- bioenergy --- rigid polyurethane foam --- modification --- hydroxymethylation --- rubber composite --- performance characterization --- torrefied wood --- wood pellets --- barrier properties --- antimicrobicity --- citric acid --- chemical recycling --- crosslinking --- heterogeneous crosslinking --- properties --- cellulose nanocrystals --- anionic polyamide-6
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In recent decades, there have been extensive developments in science and technology. These advances provide new techniques to deposit coatings onto various substrates, thus, addressing the ever-increasing performance requirements of various applications. Moreover, as technology itself develops, there are new problems that require new solutions, some of which can be solved through the application of coatings. Thus, the demands from coatings are continually increasing and the field is growing. The collection of articles contained within this volume cover a wide range of different research approaches to coatings reflecting the expanding field of coatings. It covers examples from topics such as a cold spray of magnesium alloys onto steel substrates, mechanical coatings of Ti-based materials onto steel balls, electroless plating of Ni-P coating onto an Mg-based alloy, magnetron sputtering of Ru-Zr coatings onto a Si wafer, a review of ionic liquids that form surface layers, as corrosion inhibitors, nano-composite epoxy coatings containing exfoliated clay (montmorillonite) for steel protection, a coating based on plasma electrolytic oxidation of an aluminum alloy and inhibited epoxy primer for aerospace aluminum alloys. This volume provides a wide-angle snapshot of current coating technologies through the presentation of some specific studies.
cyclical gradient concentration --- internal oxidation --- multilayer coating --- nanocomposite coating --- Ti coatings --- steel balls --- mechanical coating --- process analysis --- steel --- corrosion --- protection --- coatings --- epoxy—clay nanocomposites --- primer --- Li-inhibited --- AA2024 --- polyurethane --- SEM --- EDS --- PIXE --- PIGE --- leaching --- pigments --- ionic liquid --- polyionic liquid --- graphene --- hybrid coating --- electroless deposition --- Ni–P coating --- magnesium alloy --- ZE10 --- adhesion --- microhardness --- EDS analysis --- polarization test --- plasma electrolytic oxidation (PEO) --- aluminum --- three-dimensional structure --- aluminum/coating interface --- growth model --- cold spraying --- coating --- composite coatings --- microstructure
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