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The emission of dibenzofurans and dioxins from industrial processes is a major environmental concern. Focussing on dibenzofuran, this study tend to improve our understanding of the general oxidation chemistry and to provide a mechanism suitable for future modelling studies.Based on quantum chemical methods, energies, chemical structures and reactions are calculated numerically. Not only stable molecules and radicals, but also transition states are reported in this work.

ab initio --- Transition state theory --- Thermochemistry --- DFT --- Dioxin --- Dibenzofuran --- Groupe additivity --- Kinetics --- QRRK --- Isodesmic reactions

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"Because of continuing uncertainty about the long-term health effects of the sprayed herbicides on Vietnam veterans, Congress passed the Agent Orange Act of 1991. The legislation directed the Secretary of Veterans Affairs (VA) to request the Institite of Medicine to perform a comprehensive evaluation of scientific and medical information regarding the health effects of exposure to Agent Orange and other herbicides used in Vietnam to be followed by biennial updates. The 2010 update recommends further research of links between Vietnam service and specific health outcomes, most importantly COPD, tonsil cancer, melanoma, brain cancer, Alzheimer's disease, and paternally transmitted effects to offspring."--Publisher's description.

Agent Orange -- Health aspects. --- Agent Orange -- Toxicology. --- Vietnam War, 1961-1975 -- Veterans -- Health risk assessment -- United States. --- Agent Orange --- Vietnam War, 1961-1975 --- Asia, Southeastern --- Environmental Pollution --- Heterocyclic Compounds, 1-Ring --- Health --- North America --- Pesticides --- History, 20th Century --- History, Modern 1601 --- -Americas --- Asia --- Population Characteristics --- Toxic Actions --- Public Health --- Agrochemicals --- Heterocyclic Compounds --- Specialty Uses of Chemicals --- Chemical Actions and Uses --- Geographic Locations --- History --- Health Care --- Chemicals and Drugs --- Environment and Public Health --- Geographicals --- Humanities --- Veterans Health --- Environmental Exposure --- Herbicides --- United States --- Vietnam --- Vietnam Conflict --- Dioxins --- Dioxin --- Second Indochina War --- Viet Nam War --- Vietnamese Conflict --- Viet Nam Conflict --- Conflict, Viet Nam --- Conflict, Vietnam --- Conflict, Vietnamese --- Conflicts, Vietnamese --- Indochina War, Second --- Indochina Wars, Second --- Vietnamese Conflicts --- War, Second Indochina --- War, Viet Nam --- Wars, Second Indochina --- Wars, Viet Nam --- Algaecides --- Algicides --- Algaecide --- Algicide --- Herbicide --- Plants --- Weed Control --- Exposure, Environmental --- Environmental Exposures --- Exposures, Environmental --- Sentinel Species --- Health, Veterans --- War Exposure --- Veterans --- Specialty Chemicals and Products --- Heterocyclic Compound --- Compound, Heterocyclic --- Compounds, Heterocyclic --- Polycyclic Compounds --- Agrichemicals --- Chemicals, Agricultural --- Agrichemical --- Agricultural Chemical --- Agricultural Chemicals --- Agrochemical --- Chemical, Agricultural --- Community Health --- Environment, Preventive Medicine & Public Health --- Environment, Preventive Medicine and Public Health --- Health, Community --- Health, Public --- Preventive Medicine --- Education, Public Health Professional --- Environmental Pollutants, Noxae, and Pesticides --- Toxic Action --- Action, Toxic --- Actions, Toxic --- Population Heterogeneity --- Population Statistics --- Characteristic, Population --- Characteristics, Population --- Heterogeneity, Population --- Population Characteristic --- Statistics, Population --- History of Medicine, Modern --- Medicine, Modern --- Modern History (Medicine) --- Modern Medicine --- History, Modern --- Modern History --- 1601- History, Modern --- History, Modern (Medicine) --- Modern 1601- History --- 20th Cent. History (Medicine) --- 20th Cent. History of Medicine --- 20th Cent. Medicine --- Historical Events, 20th Century --- History of Medicine, 20th Cent. --- History, Twentieth Century --- Medical History, 20th Cent. --- Medicine, 20th Cent. --- 20th Century History --- 20th Cent. Histories (Medicine) --- 20th Century Histories --- Cent. Histories, 20th (Medicine) --- Cent. History, 20th (Medicine) --- Century Histories, 20th --- Century Histories, Twentieth --- Century History, 20th --- Century History, Twentieth --- Histories, 20th Cent. (Medicine) --- Histories, 20th Century --- Histories, Twentieth Century --- History, 20th Cent. (Medicine) --- Twentieth Century Histories --- Twentieth Century History --- Pesticide --- Community-Based Distribution --- Contraceptive Distribution --- Delivery of Healthcare --- Dental Care Delivery --- Distribution, Non-Clinical --- Distribution, Nonclinical --- Distributional Activities --- Healthcare --- Healthcare Delivery --- Healthcare Systems --- Non-Clinical Distribution --- Nonclinical Distribution --- Delivery of Dental Care --- Health Care Delivery --- Health Care Systems --- Activities, Distributional --- Activity, Distributional --- Care, Health --- Community Based Distribution --- Community-Based Distributions --- Contraceptive Distributions --- Deliveries, Healthcare --- Delivery, Dental Care --- Delivery, Health Care --- Delivery, Healthcare --- Distribution, Community-Based --- Distribution, Contraceptive --- Distribution, Non Clinical --- Distributional Activity --- Distributions, Community-Based --- Distributions, Contraceptive --- Distributions, Non-Clinical --- Distributions, Nonclinical --- Health Care System --- Healthcare Deliveries --- Healthcare System --- Non Clinical Distribution --- Non-Clinical Distributions --- Nonclinical Distributions --- System, Health Care --- System, Healthcare --- Systems, Health Care --- Systems, Healthcare --- Aspects, Historical --- Historical Aspects --- Aspect, Historical --- Historical Aspect --- Histories --- Heterocyclic Cpds, 1-Ring --- 1-Ring Heterocyclic Compounds --- 1-Ring Heterocyclic Cpds --- Heterocyclic Compounds, 1 Ring --- Heterocyclic Cpds, 1 Ring --- Pollution, Environmental --- Soil Pollution --- Pollution, Soil --- Environmental Pollutants --- Vietnam Conflict, 1961-1975 --- Vietnamese Conflict, 1961-1975 --- Vietnamese War, 1961-1975 --- Herbicide Orange --- Orange, Agent --- Orange, Herbicide --- Dichlorophenoxyacetic acid --- Trichlorophenoxyacetic acid --- Health aspects --- Toxicology --- Health risk assessment --- War use --- -Population Characteristics --- Geography --- Factor, Geographic --- Factors, Geographic --- Geographic Factor --- Geographic Factors --- Geography, Human --- Human Geography --- Americas --- North Vietnam --- Viet Nam --- Vietnam, Republic of --- Southern Asia --- America --- Northern America --- Southeastern Asia --- Southeast Asia --- Military Health --- Health aspects. --- Toxicology.