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Over the last decades, natural fibers have received growing attention as alternatives to synthetic materials for the reinforcement of polymeric composites. Their specific properties, low price, health advantages, renewability and recyclability make natural fibers particularly attractive for these purposes. Furthermore, natural fibers have a CO2-neutral life cycle, in contrast to their synthetic counterparts. However, natural fibers are also widely known to possess several drawbacks, such as a hydrophilic nature, low and variable mechanical properties, poor adhesion to polymeric matrices, high susceptibility to moisture absorption and low aging resistance. Therefore, extensive research has been conducted on natural fiber-reinforced composites in the last 20 years. In this context, this book presents several interesting papers concerning the use of natural fibers for the reinforcement of polymer-based composites, with a focus on the evaluation of their mechanical performances, ballistic properties, rheological behavior, thermal insulation response and aging resistance in humid or aggressive environments.
flax FRP --- basalt FRP --- glass FRP --- wood beam --- bending --- hybrid FRP --- flax fiber --- nano-clay --- water uptake --- hygrothermal properties --- coaxial electrospinning --- length of straight fluid jet --- spreading angle --- nanoribbons --- linear relationship --- curaua fibers --- graphene oxide coating --- epoxy composites --- ballistic performance --- recycled cotton fibers --- stiffness --- micromechanics --- Young’s modulus --- polymer matrix composites --- flax fibers --- surface treatments --- adhesion --- polymer-matrix composites (PMCs) --- composite laminates --- low-velocity impact --- delamination --- X-ray micro CT --- polypropylene --- basalt fibers --- composite laminate --- flexural --- impact damage --- dog wool fibers --- fillers --- polyurethane --- eco-composites --- renewable resources --- poly(lactic acid) --- poly(butylene succinate) --- plasticizer migration --- diffusion --- natural fibre composites --- mechanical properties --- elastic behaviour --- viscous response --- empty fruit bunch fiber (EFB) --- polybutylene succinate (PBS) --- starch --- glycerol --- characterizations --- biocomposite --- polymer Blends --- Mopa-Mopa resin --- biobased composite --- fique fibers --- wood–plastic --- leather waste --- thermoplastic starch --- mechanical characterization --- thermal characterization --- n/a --- Young's modulus --- wood-plastic
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The chemical industry is essential in the daily human life of modern society; despite the misconception about the real need for chemical production, everyone enjoys the benefit of the chemical progress. However, the chemical industry generates a large variety of products, including (i) basic chemicals, e.g., polymers, petrochemicals, and basic inorganics; (ii) specialty chemicals for crop protection, paints, inks, colorants, textiles, paper, and engineering; and (iii) consumer chemicals, including detergents, soaps, etc. For these reasons, chemists in both academia and industry are challenged with developing green and sustainable chemical production toward the full-recycling of feedstocks and waste. Aiming to improve the intensification of the process, chemists have established chemical reactions based on catalysis, as well as alternative technologies, such as continuous flow. The aim of this book is to cover promising recent research and novel trends in the field of novel catalytic reactions (homogeneous, heterogeneous, and enzymatic, as well as their combinations) in continuous flow conditions. A collection of recent contribution for conversion of starting material originated from petroleum resources or biomass into highly-added value chemicals are reported.
n/a --- dynamic mesh --- catalytic hydrodechlorination --- Pd catalyst --- fuel reactor --- catalysis --- alcohols --- Rhynchophorus ferrugineus --- ketones --- numerical prediction --- heterogeneous catalyst --- 5-hydroxymethylfurfural (HMF) --- CO2 capture --- chemical looping combustion --- SBA-15 --- biodiesel --- ?-valerolactone --- (bio) catalysis --- economizer --- erosion rate --- magnesium --- circulating fluidized bed --- continuous reactor --- erosion evolution --- kinetics --- Meerwein–Ponndorf–Verley reduction --- flow microreactor --- CFD --- micro reactor --- Oppenauer oxidation --- chlorophenols --- succinate --- aldehydes --- multiphase catalysis --- methyl levulinate --- pheromone --- zirconium --- flow chemistry --- continuous flow --- biomass --- glucose --- oxidation --- dialkyl succinates --- tube-in-tube --- aerobic --- chemo-enzymatic catalysis --- homogeneous catalysis --- lipase Cal B --- expiry period --- titanium dioxide --- Meerwein-Ponndorf-Verley reduction
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Beauty masks, diapers, wound dressings, wipes, protective clothes and biomedical products: all these high-value and/or large-volume products must be highly compatible with human skin and they should have specific functional properties, such as anti-microbial, anti-inflammatory and anti-oxidant properties. They are currently partially or totally produced using fossil-based sources, with evident issues linked to their end of life, as their waste generates an increasing environmental concern. On the contrary, biopolymers and active biomolecules from biobased sources could be used to produce new materials that are highly compatible with the skin and also biodegradable. The final products can be obtained by exploiting safe and smart nanotechnologies such as the extrusion of bionanocomposites and electrospinning/electrospray, as well as innovative surface modification and control methodologies. For all these reasons, recently, many researchers, such as those involved in the European POLYBIOSKIN project activities, have been working in the field of biomaterials with anti-microbial, anti-inflammatory and anti-oxidant properties, as well as biobased materials which are renewable and biodegradable. The present book gathered research and review papers dedicated to materials and technologies for high-performance products where the attention paid to health and environmental impact is efficiently integrated, considering both the skin-compatibility of the selected materials and their source/end of life.
pullulan --- biopolymers --- exopolysaccharides --- biodegradation --- biocompatibility --- poly(lactic acid) --- poly(butylene succinate) --- chitin nanofibrils --- starch --- skin compatibility --- anti-microbial --- poly(hydroxyalkanoate) --- biopolyesters --- beauty masks --- releasing --- skin compatible --- polyhydroxyalkanotes --- sugarcane molasses --- antibacterial materials --- essential oils --- coating --- poly(lactide) --- chitin–lignin nanocomplex --- grafting from --- lactide oligomers --- platelet-rich fibrin --- wound healing --- skin wounds --- wound dressing --- hyperspectral imaging --- principal component analysis --- spectroscopy --- chitosan --- partial least squares regression --- nir --- actives substances --- cn-nl/ga --- skin --- antifouling --- antimicrobial --- antiviral --- electrospinning --- breast implant --- ear prosthesis --- biomedical device --- chronic wound --- biopolymer --- bio-based --- surface modification --- nanolignin --- electrospray --- anti-inflammatory --- blends --- PLA --- PHBV --- nanocomposite --- tissue engineering --- biodegradable --- nanofiber --- n/a --- chitin-lignin nanocomplex
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This reprint includes research articles on various applications of electrospun nanofibers. Nanofibers have potential to be used in tissue engineering, energy harvesting, sensors, separators, water filtration, air filtration, and other applications as well. This Special Issue has received 11 interesting research articles, which covers such application areas.
nanofibers --- fibroblast --- cell culture --- cell adhesion --- cell viability --- biobased polyester --- silver nanoclusters --- sericin --- cellulose acetate --- electrospinning --- Antibacterial Nanofibers --- polybutylene succinate --- filter membrane --- electrospun fiber --- graphene oxide --- protein adsorption --- nanofiber --- hollow ball --- alginate --- tissue engineering --- 3D structure --- nanofiber fabric --- protein --- affinity adsorption --- selective separation --- poly(homocysteine thiolactone) --- sensing --- catalysis --- nanonet --- polyacrylonitrile --- surfactant --- meltblown --- nanofiber/nanonet --- hybrid nanofiber --- cytotoxicity --- folic acid --- in vitro study --- drug release --- polyimide --- solid state batteries --- composite polymer electrolyte --- photo polymerization --- fireproof --- cellulose nanofiber --- silver nanoparticle --- orange essential oil --- antibacterial activity --- polymer composites --- nanoparticle --- polymer blends --- medical applications --- n/a
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Food packaging and shelf life have been the subject of remarkable research in recent years. They are so important because only by understanding a good storage system is it possible to avoid any food waste. Moreover, the best packaging has to prolong the food quality while also reducing the packaging volume or better, become itself biodegradable, and guarantee the nutritional characteristics of food products.In particular, the increasing interest in reducing packaging wastes is becoming a rising problem, just considering that food packaging alone contributes to a huge portion of total packaging wastes in the world. On the other side, consumers judge the food quality based on appearance and freshness, but also using their awareness of the environmental implications of packaging. Nowadays, many technologies can be applied to improve food quality and shelf life, such the application of edible films or coatings, from biodegradable materials or biopolymers, trying to reduce the package barrier requirements, incorporating natural bioactive compounds and lengthening shelf life making then packaging easily compostable.
asparagus --- enzyme activity --- lignin --- fiber --- weight loss --- color --- polypropylene film --- essential oil emitter --- globe artichoke genotype --- quality parameters --- microbial growth --- antioxidants’ retention --- biodegradable --- active --- natural --- essential oil --- shelf life --- antimicrobial --- sensory --- poultry --- PET --- sepiolite --- nanocomposites --- MAP --- microbiological quality --- chicken --- food packaging --- drip loss --- liquid absorbent pad --- chicken breast fillet --- texture --- sensory evaluation --- fresh-cut fruit --- pomegranate peel powder --- natural preservative --- by-product --- sustainable approach --- Lepidium sativum --- potato --- browning index --- oil uptake --- antioxidant activity --- Malvasia --- sweet wine --- shelf-life --- accelerated shelf-life test --- 5-hydroxymethylfurfural --- 2-furaldehyde --- antimicrobial activity --- fish storability --- prickly pear cactus --- by-products --- zero-waste --- biomaster-silver --- SANAFOR® --- tapioca starch --- polybutylene succinate
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Continuous research advances have been observed in the field of environmentally-friendly polymers and polymer composites due to the dependence of polymers on fossil fuels and the sustainability issues related to plastic wastes. This book compiles the most recent research works in biopolymers, their blends and composites, and the use of natural additives, such as vegetable oils and other renewable and waste-derived liquids, with their marked environmental efficiency devoted to developing novel sustainable materials. Therefore, Environmentally Friendly Polymers and Polymer Composites provides an overview to scientists of the potential of these environmentally friendly materials and helps engineers to apply these new materials for industrial purposes.
PLA --- PCL --- TPS --- biopolymer blends --- mechanical properties --- compostable plastics --- green composites --- natural fillers --- poly(butylene succinate) (PBS) --- almond shell flour (ASF) --- poly (lactic acid) (PLA) --- poly(butylene succinate-co-adipate) (PBSA) --- binary blends --- shape memory behaviour --- polymer‒matrix composites (PMCs) --- thermomechanical --- electron microscopy --- compatibilizers --- poly(lactic acid) (PLA) --- natural fibre (NF) --- nano-hydroxyapatite (nHA) --- flammability --- crab shell --- chitin --- spherical microgels --- reverse micelle --- gelation --- chitosan (CS) --- anti-oxidant --- anti-apoptotic activity --- rotenone --- Parkinson’s disease (PD) --- composite materials --- hybrid resin --- natural reinforcement --- non-uniformities --- mechanical behavior --- antifungal activity --- dendrimer --- Origanum majorana L. essential oil --- Phytophthora infestans --- maleinized linseed oil MLO --- poly(lactic acid) --- diatomaceous earth --- biocomposites --- active containers --- polymer mixtures --- blends --- cashew nut shell liquid (CNSL) --- polypropylene --- high impact polystyrene --- compatibilization --- PHB --- PHBV --- rice husk --- biosustainability --- waste valorization --- bacterial cellulose --- natural rubber --- reinforcing --- biodegradable polymers --- Arboform --- epoxidized oil --- maleinized linseed oil --- toughness --- thermal stability --- pectin --- food packaging --- active compounds --- agro-waste residues --- circular economy --- graphene oxide --- size selection --- sodium alginate --- bio-based polymers --- biodegradable polyesters --- wood plastic composites --- natural additives and fillers --- composites characterization --- bioplastics manufacturing
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This book, as a collection of 17 research articles, provides a selection of the most recent advances in the synthesis, characterization, and applications of environmentally friendly and biodegradable biopolymer composites and nanocomposites. Recently, the demand has been growing for a clean and pollution-free environment and an evident target regarding the minimization of fossil fuel usage. Therefore, much attention has been focused on research to replace petroleum-based commodity plastics by biodegradable materials arising from biological and renewable resources. Biopolymers—polymers produced from natural sources either chemically from a biological material or biosynthesized by living organisms—are suitable alternatives for addressing these issues due to their outstanding properties, including good barrier performance, biodegradation ability, and low weight. However, they generally possess poor mechanical properties, a short fatigue life, low chemical resistance, poor long-term durability, and limited processing capability. In order to overcome these deficiencies, biopolymers can be reinforced with fillers or nanofillers (with at least one of their dimensions in the nanometer range). Bionanocomposites are advantageous for a wide range of applications, such as in medicine, pharmaceutics, cosmetics, food packaging, agriculture, forestry, electronics, transport, construction, and many more.
biodegradable films --- chitosan --- natural rubber --- n/a --- toughening --- elastomer --- deoxycholic acid --- cellulose fibers --- amphiphilic polymer --- cross-link density --- antioxidant activity --- nanocomposites --- silk fibroin --- impact properties --- conductivity --- antimicrobial agents --- Py-GC/MS --- Poly(propylene carbonate) --- biodisintegration --- peptide-cellulose conformation --- nanocomposite --- alginate films --- toughness --- protease sensor --- physical and mechanical properties --- biocomposites --- nanocellulose --- thermal decomposition kinetics --- potato protein --- micelles --- nanofibers --- mechanical properties --- active packaging materials --- cellulose --- structural profile --- glycol chitosan --- glass transition --- essential oils --- compatibility --- plasticized starch --- natural fibers --- biopolyester --- human neutrophil elastase --- biodegradation --- bio-composites --- fiber/matrix adhesion --- ?-tocopherol succinate --- MgO whiskers --- carbon nanotubes --- PLLA --- electrospinning --- chitin nanofibrils --- FTIR --- biopolymers composites --- DMA --- wheat gluten --- water uptake --- folic acid --- polycarbonate --- aerogel --- surfactant --- paclitaxel --- chemical pre-treatment --- biomass --- thermoplastic polyurethane --- poly(3-hydroxybutyrate-3-hydroxyvalerate) --- stress-strain --- polyfunctional monomers --- bio-based polymers --- tensile properties --- compatibilizer --- TG/FTIR --- PVA --- in vitro degradation --- poly(lactic acid) --- heat deflection temperature
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The range of human neurodegenerative diseases continues to pose significant unmet medical needs for societies around the world. The progressive and terminal nature of these conditions places a considerable personal burden on the individual affected but also on public health systems and health services. Tens of millions of people are indiscriminately affected by various dementias, which are rising at an alarming rate. There are no cures for many conditions, and it is clear that treatments applied as early as possible could greatly improve outcomes for patients. Therefore, new disease classification and diagnostic tools should be a key priority. Metabolomics represents a relatively new field of analytical science, which can be extremely useful in the early diagnosis of disease. The relatively unique feature of metabolites is that they sit at the intersection between the genetic background of an organism and its environment. Because many neurodegenerative diseases are not genetically inherited (instead having a range of known genetic risk factors and also a large number of unknown environmental triggers) the field of metabolomics offers great promise for the discovery of new, biologically, and clinically relevant biomarkers for neurodegenerative disorders. It is already bringing forward new knowledge in terms of the mechanisms of neurodegenerative disease.
glutamic acid --- n/a --- direct mass spectrometry --- neurodegeneration --- 6-OHDA --- targeted mass spectrometry --- mitochondrial dysfunction --- myo-inositol --- metabolomics --- bile acids --- subacute mild traumatic brain injury --- age-related macular degeneration --- metabolic pathways --- energy metabolism --- midbrain --- Alzheimer’s disease --- biomarkers --- 1H NMR --- Parkinson’s disease dementia --- GC-MS --- pathogenesis --- tricarboxylic acid cycle --- micro-dialysis --- 13C-labeled succinate --- metabolism --- lipidomics --- dementia with Lewy bodies --- fatty acid --- prodromal Parkinson’s disease --- malonate --- cerebral ischemia --- mass spectrometry --- retinal pigment epithelium --- excitotoxicity --- endothelin-1 --- reperfusion --- C. elegans --- Streptomyces venezuelae --- ?-synuclein aggregates --- natural product --- fatty acid metabolism --- imaging mass spectrometry --- LC-MS --- drusen --- cerebral palsy --- plasma --- Parkinson’s disease --- Alzheimer's disease --- Parkinson's disease dementia --- prodromal Parkinson's disease --- Parkinson's disease
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This Book serves to highlight the mechanisms related to the low intestinal drug absorption, the strategies to overcome the obstacles or intestinal drug absorption, and in situ, in vitro, and in silico methodologies to predict to intestinal drug absorption. This Book presents a series of drug absorption studies and related technologies that predict intestinal permeation of drugs that govern the pharmacokinetic features of therapeutic drugs. It also contains the mechanistic understanding regarding the first-pass metabolism and intestinal efflux that modulate the pharmacokinetics of drug and suggest the formulation strategies to enhance the bioavailability of investigated drugs.
rebamipide --- nanocrystals --- oral mucositis --- hydrogel --- endocytosis --- enoxaparin --- lipid–polymer hybrid nanoparticles --- oral --- intestinal absorption --- naftidrofuryl oxalate --- solubility --- permeability --- dissolution profiles --- pharmaceutical availability --- BCS drug classification --- non-sink condition --- solubility–permeability interplay --- unstirred water layer --- poorly soluble drugs --- solubilizer additive --- phenylketonuria --- l-phenylalanine ammonia-lyase --- enzyme --- kinetics --- catabolism disorder --- biomedical drug --- P-glycoprotein --- breast cancer resistance protein --- LY335979 --- WK-X-34 --- in vivo–in vitro correlation --- lipolysis-permeation --- lipid-based drug delivery system --- PermeaPad --- cinnarizine --- lipolysis --- amorphous solid dispersion --- candesartan Cilexetil --- PVPK30 --- pH-modulation --- spray drying --- bioavailability --- nasal administration --- spray-drying --- chitosan --- microsphere --- meloxicam --- silymarin --- D-α-Tocopherol polyethylene glycol 1000 succinate (TPGS) --- liver distribution --- acetaminophen-induced hepatotoxicity --- extra virgin olive oil --- secoiridoids --- metabolism --- phenolic compounds --- intestinal permeability --- drug-phytochemical interaction --- hepatic metabolism --- mixed inhibition --- quercetin --- repaglinide
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This book focuses on how nanoscale systems can be used to deliver molecules to help with cancer management. It provides a broad overview of some of the key strategies for nanocarrier design. These strategies are brought together by the wide compositional variety of these systems and the diversity of molecules that may be carried. Additionally, functionalization strategies, codelivery, and combination with other treatment modalities highlight a very active research field.
nanostructured lipid carriers --- doxorubicin --- mucositis --- cell internalization --- albumin --- BSA --- CPP --- gold nanorods --- gold nanoprisms --- arginine-rich peptide --- glutathione --- nanoparticles --- oxidative stress --- breast cancer --- gastric cancer --- nanoparticle --- fucoidan --- d-alpha-tocopherylpoly (ethylene glycol) succinate --- combination chemotherapy --- G-quadruplex --- nucleolin --- DNA nanocages --- intracellular localization --- cancer targeting --- molecular dynamics simulations --- mesoporous silica nanoparticles --- radiotherapy --- immunotherapy --- tumor microenvironment --- abscopal effect --- magnetofection in vivo --- magnetic nanoparticles --- iron oxide --- gene delivery --- gene vectors --- codelivery nanocarriers --- photodynamic therapy --- anticancer therapies --- combination therapy --- phthalocyanine --- uterine cervical neoplasms --- photochemotherapy --- in vitro --- in vivo --- nanocarrier --- polyplexes --- siRNA delivery --- glioblastoma therapy --- amphiphilic poly(α)glutamate --- P-selectin --- prodrug --- drug delivery --- targeted therapy --- chemotherapy --- prostate cancer --- prostate-specific membrane antigen --- targeted delivery --- encapsulation --- cabazitaxel --- nanocarriers --- nanosystems --- radiosensitizer --- hypoxia --- synergism --- cancer --- photothermal therapy --- combined antitumor effect --- oxygenation --- hydrogel --- hypoxic tumor --- n/a
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