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This book is a follow-up to Ivins Olefin Metathesis, (Academic Press, 1983). Bringing the standard text in the field up to date, this Second Edition is a result of rapid growth in the field, sparked by the discovery of numerous well-defined metal carbene complexes that can act as very efficient initiators of all types of olefin metathesis reaction, including ring-closing metathesis of acyclic dienes, enynes, and dienynes; ring-opening metathesis polymerizationof cycloalkenes, acyclic diene metathesis polymerization; and polymerization of alkynes, as well as simple olefin metathesis.

547.313 --- Hydrocarbons of the series CnH2n. Olefins (alkenes) --- Alkenes. --- Polymerization. --- Metathesis (Chemistry) --- Metathesis (Chemistry). --- 547.313 Hydrocarbons of the series CnH2n. Olefins (alkenes) --- Decomposition, Double (Chemistry) --- Double decomposition (Chemistry) --- Chemical reactions --- Polymerisation --- Polymers --- Polymers and polymerization --- Synthesis of polymers --- Ethene series --- Ethylene series --- Olefines --- Olefins --- Hydrocarbons --- Synthesis --- ALKENES --- METATHESIS --- METATHESIS POLYMERIZATION --- METATHESIS CATALYSTS --- REACTIONS

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Polymerization --- Metathesis (Chemistry) --- Polymérisation --- Chemistry. --- Chemistry, Organic. --- Polymers. --- Surfaces (Physics). --- Polymer Sciences. --- Organic Chemistry. --- Characterization and Evaluation of Materials. --- Organic Chemistry --- Chemistry --- Physical Sciences & Mathematics --- Polymerization. --- Metathesis (Chemistry). --- Decomposition, Double (Chemistry) --- Double decomposition (Chemistry) --- Polymerisation --- Polymers --- Polymers and polymerization --- Synthesis of polymers --- Polymere --- Polymeride --- Organic chemistry --- Synthesis --- Organic chemistry. --- Materials science. --- Macromolecules --- Physical sciences --- Material science --- Physics --- Surface chemistry --- Surfaces (Technology) --- Polymers  .

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An outstanding international scientific event in the field of metathesis chemistry, the NATO ASI "Green Metathesis Chemistry: Great Challenges in Synthesis, Catalysis and Nanotechnology" has been recently organized in Bucharest, Romania (July 21- August 2, 2008). Numerous renowned scientists, young researchers and students, convened for two weeks to present and debate on the newest trends in alkene metathesis and identify future perspectives in this fascinating area of organic, organometallic, catalysis and polymer chemistry with foreseen important applications in materials science and technology. Following the fruitful practice of NATO Advanced Study Institutes, selected contributions covering plenary lectures, short communications and posters have been compiled in this special volume dedicated to this successful convention on green metathesis chemistry. General interest was primarily focused on relevant "green chemistry" features related to all types of metathesis reactions (RCM, CM, enyne metathesis, ADMET and ROMP). Diverse opportunities for green and sustainable technologies and industrial procedures based on metahesis have been identified. Largely exemplified was the utility of this broadly applicable strategy in organic synthesis, for accessing natural products and pharmaceuticals, and also its ability to fit in the manufacture of smart and nanostructured materials, self-assemblies with nanoscale morphologies, macromolecular engineering.

Biosynthesis -- Congresses. --- Catalysis -- Congresses. --- Metathesis (Chemistry) -- Congresses. --- Nanotechnology -- Congresses. --- Catalysis --- Metathesis (Chemistry) --- Biosynthesis --- Nanotechnology --- Biochemistry --- Chemistry - General --- Physical & Theoretical Chemistry --- Chemistry --- Physical Sciences & Mathematics --- Biological synthesis --- Synthesis, Biological --- Decomposition, Double (Chemistry) --- Double decomposition (Chemistry) --- Chemistry. --- Organic chemistry. --- Organometallic chemistry. --- Polymers. --- Catalysis. --- Nanochemistry. --- Organic Chemistry. --- Organometallic Chemistry. --- Polymer Sciences. --- Biochemical engineering --- Organic compounds --- Biochemical templates --- Chemical reactions --- Synthesis --- Chemistry, Organic. --- Nanoscale chemistry --- Chemistry, Analytic --- Nanoscience --- Activation (Chemistry) --- Chemistry, Physical and theoretical --- Surface chemistry --- Polymere --- Polymeride --- Polymers and polymerization --- Macromolecules --- Organic chemistry --- Analytical chemistry --- Organometallic chemistry . --- Polymers  . --- Chemistry, Organometallic --- Metallo-organic chemistry --- Chemistry, Organic --- Synthetic biology

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In this book we have collected a series of state-of-the art papers written by specialists in the field of ionic liquid crystals (ILCs) to address key questions concerning the synthesis, properties, and applications of ILCs. New compounds exhibiting ionic liquid crystalline phases are presented, both of calamitic as well as discotic type. Their dynamic and structural properties have been investigated with a series of experimental techniques including differential scanning calorimetry, polarized optical spectroscopy, X-ray scattering, and nuclear magnetic resonance, impedance spectroscopy to mention but a few. Moreover, computer simulations using both fully atomistic and highly coarse-grained force fields have been presented, offering an invaluable microscopic view of the structure and dynamics of these fascinating materials.

photoconductivity --- n/a --- thermotropic --- X-ray diffraction --- mesophases --- crystal polymorphs --- columnar --- viologens --- alignment layer --- crown ether --- imidazolium --- electron transport --- metathesis reaction --- polarizing optical microscopy --- liquid crystals --- Ag nano-particles doping --- discotic --- molecular orientational order --- thermogravimetric analysis --- ion transport --- molecular dynamics --- nuclear magnetic resonance --- smectic phase A --- ion channels --- ionic liquid --- ionic liquid crystal --- phase behavior --- impedance spectroscopy --- residual DC --- differential scanning calorimetry --- 4-n-alkylbenzenesulfonic acids --- ionic liquid crystals --- ionic liquids --- thiazolium --- liquid crystal --- salt effect

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Electromembrane processes offer a multitude of applications, allowing for the recovery of water, other products, and energy. This book is a collection of contributions on recent advancements in electromembrane processes attained via experiments and/or models. The first paper is a comprehensive review article on the applications of electrodialysis for wastewater treatment, highlighting current status, technical challenges, and key points for future perspectives. The second paper focuses on ZSM-5 zeolite/PVA mixed matrix CEMs with high monovalent permselectivity for recovering either acid or Li+. The third paper regards direct numerical simulations of electroconvection in an electrodialysis dilute channel with forced flow under potentiodynamic and galvanodynamic regimes. The fourth paper investigates the reasons for the formation and properties of soliton-like charge waves in overlimiting conditions. The fifth paper focuses on the characterization of AEMs functionalized by surface modification via poly(acrylic) acid yielding monovalent permselectivity for reverse electrodialysis. In the sixth paper, CFD simulations of reverse electrodialysis systems are performed. The seventh paper proposes an integrated membrane process, including electrochemical intercalation–deintercalation, for the preparation of Li2CO3 from brine with a high Mg2+/Li+ mass ratio. Finally, the eighth paper is a perspective article devoted to the acid–base flow battery with monopolar and bipolar membranes.

ion-exchange membrane --- electrodialysis --- current-voltage curve --- electroconvection --- potentiodynamic regime --- galvanodynamic regime --- numerical simulation --- ZSM-5 zeolite --- monovalent cation separation --- mixed matrix membrane --- anion exchange membranes --- poly(acrylic) acid modification --- monovalent permselective membranes --- antifouling strategies --- reverse electrodialysis --- electro-membrane process --- electrodialysis reversal --- bipolar membrane electrodialysis --- selectrodialysis --- electrodialysis metathesis --- electrodeionisation --- monovalent selective membranes --- water reuse --- brine valorisation --- mathematical modelling --- using overlimiting current modes --- membrane systems --- cation-exchange membrane --- effect of the breakdown of the space charge --- computational fluid dynamics --- power density --- factorial design --- membrane process --- Li2CO3 --- electrochemical intercalation deintercalation --- high Mg/Li brine --- flow battery --- energy storage --- bipolar membrane --- water dissociation --- n/a