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Porous silicon. --- Semiconductors --- Silicon
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Luminescence --- Photoluminescence --- Porous silicon --- Silicon
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Diatomite is a natural porous silica material of sedimentary origin, formed by remainsof diatom skeletons called "frustules." The abundance in many areas of the world andthe peculiar physico-chemical properties made diatomite an intriguing material forseveral applications ranging from food production to pharmaceutics. However,diatomite is a material still rarely used in biomedical applications. In this chapter, theproperties of diatom frustules reduced to nanoparticles, with an average diameter lessthan 350 nm, as potential drug vectors are described. Their biocompatibility, cellularuptake, and capability to transport molecules inside cancer cells are discussed.Preliminary studies of in vivo toxicity are also presented.
Porous silicon. --- Nanostructured materials. --- Drug delivery systems.
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Porous silicon is rapidly attracting increasing interest in the biomaterials community. This nanostructured and biodegradable material has a range of properties, making it ideal for drug delivery, cancer therapy, and tissue engineering. Porous silicon for biomedical applications provides a comprehensive review of this emerging biomaterial.Chapters in part one focus on the fundamentals and properties of porous silicon for biomedical applications including thermal properties and stabilization, photochemical and nonthermal chemical modification, protein-modified porous silicon films, and
Human biochemistry --- Silicones in medicine. --- Biomedical materials. --- Porous silicon.
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Luminescence --- Nanostructured materials --- Polycrystalline semiconductors --- Porous materials --- Porous silicon --- Semiconductors --- Thin film devices --- Congresses --- Congresses --- Congresses --- Congresses --- Congresses --- Congresses
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Metal-assisted chemical etching (MacEtch) has recently emerged as a new etching technique capable of fabricating high aspect ratio nano- and microstructures in a few semiconductors substrates—Si, Ge, poly-Si, GaAs, and SiC—and using different catalysts—Ag, Au, Pt, Pd, Cu, Ni, and Rh. Several shapes have been demonstrated with a high anisotropy and feature size in the nanoscale—nanoporous films, nanowires, 3D objects, and trenches, which are useful components of photonic devices, microfluidic devices, bio-medical devices, batteries, Vias, MEMS, X-ray optics, etc. With no limitations of large-areas and low-cost processing, MacEtch can open up new opportunities for several applications where high precision nano- and microfabrication is required. This can make semiconductor manufacturing more accessible to researchers in various fields, and accelerate innovation in electronics, bio-medical engineering, energy, and photonics. Accordingly, this Special Issue seeks to showcase research papers, short communications, and review articles that focus on novel methodological developments in MacEtch, and its use for various applications.
porous silicon --- Pd nanoparticles-assisted chemical etching --- etching rate --- ethanol electrooxidation --- X-ray diffractive optics --- zone plate --- high aspect ratio nanostructures --- metal-assisted chemical etching --- electroless deposition --- Al2O3 nanotube --- ultra-high aspect ratio --- gold (Au) metal assisted chemical etching --- atomic layer deposition --- anisotropic dry etching --- silicon cones --- metal assisted chemical etching --- transversal pores --- antireflection --- black GaAs --- photon recycling --- X-ray grating interferometry --- catalyst --- silicon --- gold electroplating --- magnetically guided metal-assisted chemical etching --- bulk Si etching --- curved Si structure --- catalyst encapsulation --- n/a
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2D nanomaterials are a relatively populous and ever-expanding class of innovative materials with disruptive potential for different application contexts. Although for some of them, such as graphene, various possible implementations have already been explored in different application fields, others, (e.g., Mxenes), are still relatively at an infantile stage with regard to handling, stability, exploitation, processing and practical use in devices and structures with higher dimensionality.In any case, regardless of the specific nature of each of these materials, their degree of purity and structure (mono-layers/few-layers/multi-layers) and their level of maturity, they all share the same challenges since their onset, such as processing, patterning, transfer and integration in devices, allowing smart exploitation of their unique properties, incorporation in matrices of different nature for the synthesis of nano-composites, and so on.Accordingly, this book aims to showcase research papers and review articles outlining recent progress and innovative approaches for 2D nanomaterials synthesis and/or processing, preparatory to their assembly or integration into devices, microstructures, microsensors and composites for different application fields.
graphene --- patterning --- Pt --- 2D materials --- chemical vapor deposition (CVD) --- naked-eye 3D --- microstructure --- flexible --- film --- fabrication --- biodevices --- integration --- miniaturized devices --- Si3N4 --- lubrication --- friction --- temperature rise --- photo-assisted etching --- porous silicon --- illumination --- doping level --- total current --- reflectance --- fano resonance --- plasmonic sensor --- Au/Pd --- SiC --- nanomorphology --- coalescence --- percolation --- scanning electron microscopy --- inkjet printing --- nanoparticle --- metal-organic decomposition --- silver thin film --- adhesion strength --- electrical resistivity --- monolayer MoS2 --- 10-nm nanogap --- localized surface plasmon resonance --- photoluminescence --- n/a
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This book entitled “Protein Crystallization under the Presence of an Electric Field” covers recent trends and original contributions on the use of electric fields (internal and external) for applications for nucleation control and the effect on the kinetics of crystallization processes. This book also includes basic strategies for growing crystals of biological macromolecules for characterization via X-ray and neutron diffraction as well as using modern X-ray-free electron-lasers. There are six main topics covered on this book, including recent insights into the crystallization process from nucleation and growth peculiarities, when using different kinds of electric fields; the effect of external electric fields on the kinetics of the dislocation-free growth of model proteins; the use of very strong external electric fields for the crystallization of a model protein glucose isomerase; and the use of alternant electric fields using different kinds of pulses and their combination with strong magnetic fields. There are also contributions related to applications in developing electron-transfer devices as well as graphene-based platforms for electrocrystallization and in situ X-ray diffraction characterization.
porous silicon --- silanes --- microbatch method --- growth kinetics --- impact of electric fields on the protein crystallization --- cytochrome C nucleation and crystallization --- protein infiltration --- I–V characteristics --- electric fields --- number density --- protein crystallization --- protein crystals --- electron-transfer biomolecular devices --- external DC electric field --- classical and two-step nucleation mechanisms --- macromolecular crystallography --- in situ diffraction --- external and internal electric fields --- size and quality of protein crystals --- lysozyme --- magnetic fields --- electrical properties --- gel-growth --- crystal growth in solution --- electric field --- pulse-wave --- crystal quality --- crystallization --- serial crystallography --- microfluidics --- electrocrystallization
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