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Carbenes (Methylene compounds) --- Carbon, Divalent --- Divalent carbon --- Methene compounds --- Methylene compounds --- Carbon compounds --- Intermediates (Chemistry)

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Reduction (Chemistry) --- Electrocatalysis. --- Carbon dioxide --- Carbenes (Methylene compounds) --- Photosensitizing compounds. --- Liquid fuels --- Synthesis. --- Research.

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Coal mines and mining --- Mine ventilation --- Carbenes (Methylene compounds) --- Industrial hygiene --- Personal protective equipment --- Employees --- Health and hygiene --- Threshold limit values --- Consolidation Coal Company. --- Health and hygiene.

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This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of recent developments in the applications of reactions involving carbene and nitrene intermediates directed to the synthesis of heterocyclic compounds. Multiple pathways through which diverse heterocyclic compounds are accessed occur from a variety of carbene and nitrene precursors through C-H/X-H insertions, cycloadditions, ylide transformations, rearrangements, and cascade reactions. Catalytic processes that form metallo-carbenes and nitrenes offer unparalleled chemo-, regio-, and stereo-selectivities. Insights are provided into the scope of these methodologies and the inherent control of catalyst ligands on reaction selectivities.

Chemistry. --- Chemistry, Organic. --- Heterogeneous catalysis. --- Materials. --- Chemical Synthesis. --- Organic Chemistry. --- Heterogeneneous Catalysis. --- Engineering --- Engineering materials --- Industrial materials --- Engineering design --- Manufacturing processes --- Catalysis --- Organic chemistry --- Chemistry --- Physical sciences --- Materials --- Carbenes (Methylene compounds) --- Heterocyclic compounds.

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It was only in the early 1990s that carbenes with the carbene carbon being incorporated in a nitrogen containing heterocycle (N-heterocyclic carbenes or NHCs) were found to be stable enough to be isolated. Since the first report on the application of NHCs as ligands in transition metal catalysis in 1995, NHC have found numerous applications and have been established as a versatile and indispensable class of ligands. For many reactions like metathesis or cross-coupling reactions NHCs have often become the ligands of choice, allowing otherwise difficult transformations. In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes. The use of NHC as ligands in catalysis has reached a certain level of maturity and this book allows the reader to get a balanced view of this increasingly important ligand class.

Carbenes (Methylene compounds) --- Heterocyclic compounds. --- Transition metal catalysts. --- Carbènes --- Composés hétérocycliques --- Métaux de transition --- Catalyseurs --- Carbenes (Methylene compounds) -- Reactivity. --- Electronic books. -- local. --- Heterocyclic compounds --- Transition metal catalysts --- Organic Chemistry --- Chemistry --- Physical Sciences & Mathematics --- Reactivity. --- Carbon, Divalent --- Divalent carbon --- Methene compounds --- Methylene compounds --- Chemistry. --- Inorganic chemistry. --- Organometallic chemistry. --- Medicinal chemistry. --- Catalysis. --- Organometallic Chemistry. --- Inorganic Chemistry. --- Medicinal Chemistry. --- Carbon compounds --- Intermediates (Chemistry) --- Metal catalysts --- Chemistry, Organic. --- Chemistry, inorganic. --- Biochemistry. --- Biological chemistry --- Chemical composition of organisms --- Organisms --- Physiological chemistry --- Biology --- Medical sciences --- Inorganic chemistry --- Inorganic compounds --- Activation (Chemistry) --- Chemistry, Physical and theoretical --- Surface chemistry --- Organic chemistry --- Composition --- Organometallic chemistry . --- Chemistry, Medical and pharmaceutical --- Chemistry, Pharmaceutical --- Drug chemistry --- Drugs --- Medical chemistry --- Medicinal chemistry --- Pharmacochemistry --- Chemistry, Organometallic --- Metallo-organic chemistry --- Chemistry, Organic --- Cycloids, Mixed (Chemistry) --- Heteroatomic compounds --- Heterocycles --- Mixed cycloids (Chemistry) --- Organic cyclic compounds