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With conventional materials contributing greatly to environmental waste, biodegradable and natural composites have grown in interest and display low environmental impact at low cost across a wide range of applications. This book provides an overview of different biodegradable and natural composites and focuses on efforts into increasing their mechanical performance to extend their capabilities and applications.
Composite materials. --- Biodegradability. --- Composite Materials.
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This eBook is a collection of articles from a Frontiers Research Topic. Frontiers Research Topics are very popular trademarks of the Frontiers Journals Series: they are collections of at least ten articles, all centered on a particular subject. With their unique mix of varied contributions from Original Research to Review Articles, Frontiers Research Topics unify the most influential researchers, the latest key findings and historical advances in a hot research area! Find out more on how to host your own Frontiers Research Topic or contribute to one as an author by contacting the Frontiers Editorial Office: frontiersin.org/about/contact
biodegradable polymers --- biodegradable composites --- biodegradability --- material characterization --- environmental sustainability --- recyclability
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In recent years, there has been significant progress in biomass research as bio-based products are beneficial to the environment, energy-saving, and cost-saving if they are processed properly. The book collects the most state-of-the-art works related to the natural fiber composites in a Special Issue entitled “Natural Fiber Biocomposites”. These works address all the issues related the manufacturing of natural fiber composite products, from (1) raw materials, such as wood, flax fiber, and cellulose nanofiber; to the (2) raw material treatments, such as furfuryl alcohol pretreatment, ultrasonic vibration treatment (UVT), and extraction method for the resins; to the (3) process of the composites fabrication, such as thermo-hygro-mechanical densification; and to the (4) performance of the composites, including mechanical, moisture absorption, opacity, thermal, and biodegradability. Discussions on the adhesives/resins used in the natural fiber composites fabrication, such as dried distiller’s grains and solubles (DDGS), pennycress (Thlaspi arvense L.) press cakes (PPC), and lesquerella [Lesquerella fendleri (A. Gary) S. Watson] press cake (LPC), starch, and polylactic acid (PLA), are also part of the book. It is believed the technical information presented in this book will contribute to the development of the bio-based composites.
flexural properties --- panels --- by-products --- non-dietetic uses --- modulus of rupture --- modulus of elasticity --- nanofiber cellulose --- water hyacinth --- thermoplastic starch --- bionanocomposites --- ultrasonic vibration time --- density --- gas permeability --- thermal conductivity --- densification --- durability --- green composites --- cellulosic fibers --- water uptake --- biocomposite --- starch --- cellulose --- ultrasonication --- moisture absorption --- opacity --- mat porosity --- mat thermal conductivity --- fiber size --- hot-pressing process --- PLA --- flax --- thermoplastic composites --- mechanical properties --- biodegradability
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The bioeconomy initially focused on resource substitution, including the production of biomass from various resources; its conversion, fractionation, and processing by means of biotechnology; and chemistry and process engineering towards the production and marketing of food, feed, fuel, and fibre. Nevertheless, although resource substitution is still considered important, the emphasis has been recently shifted to the biotechnological innovation perspective of the bioeconomy, in terms that ensure environmental sustainability. It is estimated that around one-third of the food produced for human consumption is wasted throughout the world, posing not only a sustainability problem related to food security but also a significant environmental problem. Food waste streams, mainly derived from fruits and vegetables, cereals, oilseeds, meat, dairy, and fish processing, have unavoidably attracted the interest of the scientific community as an abundant reservoir of complex carbohydrates, proteins, lipids, and functional compounds, which can be utilized as raw materials for added-value product formulations. This Special Issue focuses on innovative and emerging food and by-products processing methods for the sustainable transition to a bioeconomy era.
ash content --- sorghum milling waste --- lipids --- compost --- oleic acid --- microbial oil --- bioprocess development --- glucoamylase --- fatty acid methyl esters --- oleaginous yeast --- integrated biorefineries --- biorefineries --- hydrophobic substrates --- food processing --- hydrophilicity --- biodiesel --- films --- biodegradability --- clarified butter sediment waste --- submerged fungal fermentation --- blood plasma protein powder --- Morchella --- hydrogels --- heat-induced gelation --- sustainability --- bacterial cellulose --- bioprocesses --- circular economy --- olive waste --- prebiotics --- Rhodosporidium toruloides --- carotenoids --- waste valorization --- glucosamine --- food-processing --- size exclusion chromatography (SEC) --- bioeconomy --- food waste valorization --- whey proteins --- arabinoxylan --- Ostwald ripening --- emulsion --- emulsifier --- food biotechnology --- drying method --- polysaccharides --- food packaging --- texture --- lactose esters --- morel mushrooms --- circular-economy --- solid state fermentation --- bioactive compounds --- edible films --- hydrolysis --- Aspergillus awamori
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Plasma electrolytic oxidation (PEO), also known as micro-arc oxidation (MAO), functionalizes surfaces, improving the mechanical, thermal, and corrosion performance of metallic substrates, along with other tailored properties (e.g., biocompatibility, catalysis, antibacterial response, self-lubrication, etc.). The extensive field of applications of this technique ranges from structural components, in particular, in the transport sector, to more advanced fields, such as bioengineering. The present Special Issue covers the latest advances in PEO‐coated light alloys for structural (Al, Mg) and biomedical applications (Ti, Mg), with 10 research papers and 1 review from leading research groups around the world.
magnesium --- plasma electrolytic oxidation --- SiO2 particle --- corrosion resistance --- wear resistance --- micro arc oxidation (MAO) --- Cu nano-layer --- hydrophilic surface --- apatite --- in vitro bioactivity --- antibacterial properties --- PEO --- LDH --- active protection --- corrosion --- aluminium --- biodegradable implants --- magnesium alloy --- micro-arc oxidation --- Taguchi method --- SBF --- in-vivo test --- biodegradability --- plasma electrolytic oxidation (PEO) --- aluminum 6082 --- luminescent coatings --- phosphorescence --- anodized aluminum --- Mott-Schottky analysis --- defect --- annealing --- titanium dioxide --- anatase and rutile --- surface treatment --- wear --- medical engineering --- aluminum --- titanium --- Al7075 alloy --- aluminum oxide --- molten salt --- microhardness --- radio frequency magnetron sputtering (RFMS) --- calcium-phosphate (CaP) coating --- n/a
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Bioenergy is renewable energy obtained from biomass—any organic material that has stored sunlight in the form of chemical energy. Biogas is among the biofuels that can be obtained from biomass resources, including biodegradable wastes like manure, sewage sludge, the organic fraction of municipal solid wastes, slaughterhouse waste, crop residues, and more recently lignocellulosic biomass and algae. Within the framework of the circular economy, biogas production from biodegradable waste is particularly interesting, as it helps to save resources while reducing environmental pollution. Besides, lignocellulosic biomass and algae do not compete for arable land with food crops (in contrast with energy crops). Hence, they constitute a novel source of biomass for bioenergy.Biogas plants may involve both high-tech and low-tech digesters, ranging from industrial-scale plants to small-scale farms and even households. They pose an alternative for decentralized bioenergy production in rural areas. Indeed, the biogas produced can be used in heaters, engines, combined heat and power units, and even cookstoves at the household level. Notwithstanding, digesters are considered to be a sustainable technology that can improve the living conditions of farmers by covering energy needs and boosting nutrient recycling. Thanks to their technical, socio-economic, and environmental benefits, rural biogas plants have been spreading around the world since the 1970s, with a large focus on farm-based systems and households. However, several challenges still need to be overcome in order to improve the technology and financial viability.
Mixing --- optimised --- household digester --- Chinese dome digester (CDD) --- self-agitation --- blank --- mixing --- Chinese dome digester --- impeller mixed digester --- unstirred digester --- hydraulically mixed --- total solids (TS) concentration --- plug-flow reactor --- anaerobic digestion --- animal manures --- biogas --- unconfined gas injection mixing --- mixing recirculation --- biomethane potential tests --- Italy --- manure --- energy crops --- agriculture residues --- digestate --- biochemical methane potential --- micro-aeration --- iron --- bioenergy --- H2S scrubber --- methane --- fermentation --- dairy --- poultry --- absorbent --- ammonia --- inhibition --- acclimatization --- trace elements --- anaerobic treatment --- energy assessment --- rural sanitation --- sludge --- wastewater --- agricultural runoff --- biomethane --- biorefinery --- microalgae --- photobioreactor --- pretreatment --- low cost digester --- psychrophilic anaerobic digestion --- thermal behavior --- anaerobic co-digestion --- slaughterhouse wastewater --- synergistic effects --- kinetic modeling --- biodegradability
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Over the few coming decades, bio-based and biodegradable plastics produced from sustainable bioresources should essentially substitute the prevalent synthetic plastics produced from exhaustible hydrocarbon fossils. To the greatest extend, this innovative trend has to apply to the packaging manufacturing area and especially to food packaging implementation. To supply the rapid production increment of biodegradable plastics, there must be provided the effective development of scientific-technical potential that promotes the comprehensive exploration of their structural, functional, and dynamic characteristics. In this regard, the transition from passive barrier materials preventing water and oxygen transport as well as bacteria infiltration to active functional packaging that ensures gas diffusion selectivity, antiseptics' and other modifiers' release should be based on the thorough study of biopolymer crystallinity, morphology, diffusivity, controlled biodegradability and life cycle assessment. This Special Issue accumulates the papers of international teams that devoted to scientific and industrial bases providing the biodegradable material development in the barrier and active packaging as well as in agricultural applications. We hope that book will bring great interest to the experts in the area of sustainable biopolymers.
bio-HDPE --- GA --- natural additives --- thermal resistance --- UV stability --- food packaging --- antimicrobial properties --- polyethylene --- birch bark extract --- ultrasound --- thermoplastic starch --- biodegradation --- permeability --- diffusion --- sorption --- porous membranes --- hydrophilic and hydrophobic polymers --- PLA bottle --- bio-based and biodegradable polymers --- life cycle assessment --- environmental impact --- ReCiPe2016 method --- packaging material --- bio-based polymer composite --- natural rubber --- water absorption --- mycological test --- biodegradability --- mechanical properties --- poly(3-hydroxybutyrate) (PHB) --- polylactic acid (PLA) --- biomaterials --- gas permeability --- gas diffusion --- segmental dynamics --- electron spin resonance (ESR) --- scanning electron microscopy (SEM) --- differential scanning calorimetry (DSC) --- poly(3-hydroxybutyrate) --- poly(3-hydroxybutyrate-co-3-hydroxyvalerate) --- poly(3-hydroxybutyrate-co-4-methyl-3-hydroxyvalerate) --- hydrolysis --- pancreatic lipase --- mechanical behavior --- chitosan --- polymeric films --- crosslinking --- genipin --- sorption isotherm --- degree of crosslinking --- polylactide --- poly(ethyleneglycol) --- blending under shear deformations --- electrospinning --- oil absorption --- Monte Carlo --- bio-based polymers --- biodegradable packaging --- biopolymer structure --- encapsulation --- life cycle analysis
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Since the turn of the last century when the field of catalysis was born, iron and cobalt have been key players in numerous catalysis processes. These metals, due to their ability to activate CO and CH, haev a major economic impact worldwide. Several industrial processes and synthetic routes use these metals: biomass-to-liquids (BTL), coal-to-liquids (CTL), natural gas-to-liquids (GTL), water-gas-shift, alcohol synthesis, alcohol steam reforming, polymerization processes, cross-coupling reactions, and photocatalyst activated reactions. A vast number of materials are produced from these processes, including oil, lubricants, waxes, diesel and jet fuels, hydrogen (e.g., fuel cell applications), gasoline, rubbers, plastics, alcohols, pharmaceuticals, agrochemicals, feed-stock chemicals, and other alternative materials. However, given the true complexities of the variables involved in these processes, many key mechanistic issues are still not fully defined or understood. This Special Issue of Catalysis will be a collaborative effort to combine current catalysis research on these metals from experimental and theoretical perspectives on both heterogeneous and homogeneous catalysts. We welcome contributions from the catalysis community on catalyst characterization, kinetics, reaction mechanism, reactor development, theoretical modeling, and surface science.
polynuclear cobalt complexes --- water oxidation --- artificial photosynthesis --- Fe/Cu catalytic-ceramic-filler --- nitrobenzene compounds wastewater --- pilot-scale test --- biodegradability-improvement --- Fischer–Tropsch synthesis (FTS) --- oxygenates --- iron --- cobalt --- ruthenium --- Anderson-Schulz-Flory (ASF) distribution --- Fischer–Tropsch --- catalyst deactivation --- potassium --- liquid-phase catalytic oxidation --- limonene --- carvone --- zeolitic imidazolate frameworks --- Fischer-Tropsch synthesis --- chain growth --- CO insertion --- kinetic isotope effect --- DFT --- hydrogenation of CO --- iron catalysts --- syngas --- monometallic iron catalysts --- Fischer–Tropsch product distribution --- reaction mechanism --- catalysis --- process synthesis and design --- energy conversion --- iron–cobalt bimetal catalysts --- electrochemical application --- hydrogen evolution --- oxygen evolution --- oxygen reduction --- RWGS --- iron oxides --- CO2 conversion --- gas-switching --- Synthetic natural gas (SNG) --- Cobalt --- Iron --- C2–C4 hydrocarbons --- paraffin ratio --- asymmetric hydrogenation --- homogeneous catalysis --- structural design --- conformational analysis --- NMR spectroscopy --- alumina --- strong metal support interactions --- CO2 hydrogenation --- pressure --- temperature --- cobalt carboxylate --- coating --- autoxidation --- alkyd --- siccative --- polymerization --- manganese --- Fischer–Tropsch synthesis --- modeling --- kinetics --- Co --- Al2O3 --- Pt --- Cd --- In --- Sn --- hydrocarbon selectivity --- synergic effect --- GTL --- additives --- reducibility --- XANES --- mesoporous silica based catalysts --- kinetic studies --- 3-D printed microchannel microreactor --- cobalt–nickel nanoparticles --- cobalt–nickel alloys --- nickel --- HAADF-STEM --- TPR-EXAFS/XANES --- CO hydrogenation --- CSTR --- n/a --- Fischer-Tropsch synthesis (FTS) --- Fischer-Tropsch --- Fischer-Tropsch product distribution --- iron-cobalt bimetal catalysts --- C2-C4 hydrocarbons --- cobalt-nickel nanoparticles --- cobalt-nickel alloys
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Clean water is one of the most important natural resources on earth. Wastewater, which is spent water, is also a valuable natural resource. However, wastewater may contain many contaminants and cannot be released back into the environment until the contaminants are removed. Untreated wastewater and inadequately treated wastewater may have a detrimental effect on the environment and has a harmful effect on human health. Water quality engineering addresses the sources, transport and treatment of chemical and microbiological contaminants that affect water. Objectives for the treatment of wastewater are that the treated wastewater can meet national effluent standards for the protection of the environment and the protection of public health. This book, which is based on the Special Issue, includes contributions on advanced technologies applied to the treatment of municipal and industrial wastewater and sludge. The book deals with recent advances in municipal wastewater, industrial wastewater, and sludge treatment technologies, health effects of municipal wastewater, risk management, energy efficient wastewater treatment, water sustainability, water reuse and resource recovery.
Dimocarpus longan seeds --- leachate treatment --- coagulant–flocculation --- polyaluminium chloride --- enteric virus --- remediation technology --- water quality --- chitosan --- diclofenac --- ibuprofen --- magnetic biochar --- naproxen --- aerobic–MOB–anoxic process --- biogas --- denitrification --- mixed methanotroph culture --- WWTP --- ionizing radiation --- agricultural effluents --- dye treatment --- pharmaceutical effluents --- disinfection --- ammonia --- zeolite --- electrocoagulation --- response surface methodology --- stabilized --- leachate --- adsorption capacity --- decentralized water supply --- electrochemical reaction --- inconsistent view --- sand filtration --- wastewater treatment --- zero-valent iron --- submergence --- eutrophication --- invasive-native competition --- growth rate --- morphological traits --- polluted urban river --- sequential constructed wetlands --- purification effect --- water restoration --- Yitong River --- air gap membrane distillation --- heavy metal removal --- industrial wastewater --- greywater treatment --- house onsite --- reuse --- irrigation --- acceptance --- barriers --- heavy metals determination --- groundwater --- greywater --- adsorption --- separation --- inductively coupled plasma mass spectroscopy --- natural and modified polymer --- biodegradability --- toxicant dyes --- industrial wastewater treatment --- kinetic studies --- Moringa oleifera --- plant seed biomass --- prediction modeling --- diclofenac (DIC) --- pH-dependent degradation mechanism --- reactive site --- tunnel-structured manganese oxide --- γ-MnO2 --- Lemna minor bioassay --- visual system --- computer vision --- water pollution assessment --- bioindicators --- synthetic nanoparticles --- nTiO2 and nCeO2 --- waste water treatment --- sp-ICP-MS nanoparticle tracking --- acid mine drainage --- sulphate reduction --- sulphate reducing bacteria --- n/a --- coagulant-flocculation --- aerobic-MOB-anoxic process
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The aim of this reprint is to highlight the progress and fundamental aspects for the synthesis, characterization, properties, and application of novel polymeric materials, as well as their copolymers, composites, and nanocomposites.
Plastics & polymers technology --- poly(lactic acid) --- epoxidized natural rubber --- polymer blend --- natural additives --- antioxidant --- polymer blending --- radiation crosslinking --- polyethylene --- polyurethane --- heat resistance --- mechanical property --- aramid fiber --- ballistic test --- failure mechanism --- cyclotriphosphazane --- flame retardancy --- dielectric properties --- azo compound --- liquid crystal --- structure–property relationship --- axial behavior --- geopolymer concrete (GC) --- ferrocement --- finite element analysis (FEA) --- polyacrylonitrile --- lignin --- electrospinning --- selective chemical dissolution --- porous nanofibers --- nanofibers --- soft template --- peat soil --- cement --- stabilization --- fly ash --- polypropylene fiber --- unconfined compressive strength (UCS) --- California bearing ratio (CBR) --- scanning electron microscopy (SEM) --- bio-based polyurethanes --- jatropha oil --- algae oil --- recovered palm oil --- epoxy composite --- green composite --- corn cob --- polycarbonates --- transesterification --- polycondensation --- polymer --- hydrogen --- hydrophobic --- sensing --- nanostructures --- palladium --- polymer composite --- fibre-prestressing --- residual stresses --- PCL–SBA-15 nanocomposites --- real-time variable-temperature synchrotron measurements --- confinement --- mechanical behavior --- nanoclay --- nanocomposites --- mechanical properties --- impact properties --- hardness --- polymer composites --- graphene quantum dots --- bioactive --- biomedical --- synthesis --- PVK --- hexylthiophene --- PANI --- nanocomposite --- photovoltaic cells --- DFT --- polyhydroxyalkanoates --- fibers --- biodegradability --- packaging --- patents --- poly(aminopropyl/phenyl)silsesquioxane --- thiol-ene --- kinetics --- activation energy --- polymer characterization --- viscoelasticity --- DMA --- solution blow spinning --- polyethylene oxide --- morphology --- materials characterization --- polymer dissolution --- kaolin flocculation --- aggregate resistance --- salinity --- flocculation kinetic --- shear rate --- thermoplastic starch --- silane --- foam --- carbon dioxide --- microcapsules --- dip coating --- encapsulation --- spectroscopy --- microscopy --- antibacterial silver --- polyaniline --- dodecylbenzene sulfonic acid --- γ-Al2O3 --- in situ polymerization --- core–shell nanocomposite --- polyphosphazene --- micro-nanospheres --- species-absorbing mechanisms --- hydrophobicity --- thermochemical --- PVDF --- alkali-grafting --- α-methyl styrene --- acrylonitrile --- proton exchange membrane --- block copolymers --- random copolymers --- catalytic membranes --- esterification --- isopropyl acetate --- bioinspired bottlebrush polymers --- aqueous boundary lubrication --- friction --- wear resistance --- supramolecular hydrogel --- acrylic acid --- maleic anhydride --- terpyridine --- coordination interaction --- thermoplastic polyurethanes --- surface free energy --- dithiol --- differential scanning calorimetry --- optical properties --- arsine --- ligands --- polypropylene --- catalyst --- degradation --- sol-gel process --- 3D network hybrid materials --- nanoparticles --- nanodispersity --- ionic liquids --- n/a --- structure-property relationship --- PCL-SBA-15 nanocomposites --- core-shell nanocomposite
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