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Plants are the most important renewable source of feedstock for polymeric materials. They are a resource of monomers and macromolecules after the appropriate chemical treatment. By analogy with the petrochemistry industry, plant macromolecules are depolymerized into simpler units which are generally chemically modified and re-bound to produce new polymers. The properties of these polymers are usually tailored by small chemical changes in their molecular structure, or by the polymerization of plant monomers with other molecules. Another interesting strategy for the formation of polymeric materials is the direct use of plant macromolecules in the form of blends, composites, grafted polymers, multilayer systems, etc. The interactions and assemblies of the different components allow the control of the final features of such materials. Traditionally, polysaccharides, with cellulose as the main protagonist, have been the most used substances. However, as consequence of a growing demand of functional plastics, other plant macromolecules, habitually considered wastes, have started to become valuable raw materials. Lignin and plant proteins (mainly, soy protein, wheat gluten, and zein) are classical examples. Also, suberin has been highlighted in this field. Other plant polymers such as the cutin and the sporopollenin are promising alternatives. Furthermore, other minority plant polymers, e.g. cutan or algaenan, could be potential sources of materials. The different chemistry, structure, intrinsic properties and functions of these macromolecules in the plants are a strong inspiration for the development of novel and interesting polymeric materials. Here, in this Research Topic, we welcome the submission of manuscripts related to the production, extraction, processability, synthesis, characterization and applications of non-polysaccharides plant materials.
Cutin --- Plant polymers --- CORK --- suberin --- Agro-waste --- Kerogen --- sporopollenin
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Lignin - Trends and Applications consists of 11 chapters related to the lignin structure, modification, depolymerization, degradation process, computational modeling, and applications. This is a useful book for readers from diverse areas, such as physics, chemistry, biology, materials science, and engineering. It is expected that this book may expand the reader's knowledge about this complex natural polymer.
Lignin. --- Lignins --- Crosslinked polymers --- Plant polymers --- Wood --- Chemistry --- Physical Sciences --- Engineering and Technology --- Materials Science --- Biochemistry --- Polymers
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Polyamines are small aliphatic polycations which have been involved in key stress and developmental processes in plants. In the recent years, compelling genetic and molecular evidences point to polyamines as essential metabolites required for resistance to drought, freezing, salinity, oxidative stress among other type of abiotic and biotic stresses. In addition to their role as stress-protective compounds, polyamines participate in key developmental processes mediated by specific signaling pathways or in cross-regulation with other plant hormones. Our Research Topic aims to integrate the multiple stress and developmental regulatory functions of polyamines in plants under a genetic, molecular and evolutionary perspective with special focus on signaling networks, mechanisms of action and metabolism regulation.
Polyamines. --- Plant polymers. --- stress --- Spermine --- Thermospermine --- Spermidine --- ROS --- Transglutaminase --- Putrescine --- Polyamines --- Biopolymers --- Phytochemicals --- Aliphatic compounds --- Amines --- Imines
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