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Table of Contents - Synthesis in the Key of Catellani: Norbornene-Mediated ortho C-H Functionalization - Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation - Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C-H and C-Hal Bonds - Pd-Catalyzed C-H Bond Functionalization on the Indole and Pyrrole Nucleus - Remote C-H Activation via Through-Space Palladium and Rhodium Migrations - Palladium-Catalyzed Aryl-Aryl Bond Formation Through Double C-H Activation - Palladium-Catalyzed Allylic C-H Bond Functionalization of Olefins - Ruthenium-Catalyzed Direct Arylations Through C-H Bond Cleavages - Rhodium-Catalyzed C-H Bond Arylationof Arenes - Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C-H Bonds - Functionalization of Carbon-Hydrogen Bonds Through Transition Metal Carbenoid Insertion - Metal-Catalyzed Oxidations of C-H to C-N Bonds
Chemistry. --- Organic Chemistry. --- Chemistry, Organic. --- Chimie --- Chimie organique --- Organometallic compounds --- Activation (Chemistry) --- Organometallic chemistry
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- Microporous Organic Polymers: Design, Synthesis, and Function By J.-X. Jiang and A. I. Cooper - Hydrogen, Methane and Carbon Dioxide Adsorption in Metal-Organic Framework Materials By X. Lin, N. R. Champness, and M. Schröder -Doping of Metal-Organic Frameworks with Functional Guest Molecules and Nanoparticles By F. Schröder and R. A. Fischer -Chiral Metal-Organic Porous Materials: Synthetic Strategies and Applications in Chiral Separation and Catalysis By K. Kim, M. Banerjee, M. Yoon, and S. Das -Controlled Polymerization by Incarceration of Monomers in Nanochannels By T. Uemura and S. Kitagawa -Designing Metal-Organic Frameworks for Catalytic Applications L. Ma and W. Lin -Magnetic and Porous Molecule-Based Materials By N. Roques, V. Mugnaini, and J. Veciana
Chemistry. --- Organic Chemistry. --- Chemistry, Organic. --- Chimie --- Chimie organique --- Organometallic polymers --- Porous materials --- Gases --- Storage --- Separation
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Based on courses for students of science, engineering, and systems science at the Zurich University of Applied Sciences at Winterthur, this text approaches the fundamentals of thermodynamics from the point of view of continuum physics. By describing physical processes in terms of the flow and balance of physical quantities, the author achieves a unified approach to hydraulics, electricity, mechanics and thermodynamics. In this way, it becomes clear that entropy is the fundamental property that is transported in thermal processes (i.e., heat), and that temperature is the corresponding potential. The resulting theory of the creation, flow, and balance of entropy provides the foundation of a dynamical theory of heat. This extensively revised and updated second edition includes new material on dynamical chemical processes, thermoelectricity, and explicit dynamical modeling of thermal and chemical processes. To make the book more useful for courses on thermodynamics and physical chemistry at different levels, coverage of topics is divided into introductory and more advanced and formal treatments. Previous knowledge of thermodynamics is not required, but the reader should be familiar with basic electricity, mechanics, and chemistry and should have some knowledge of elementary calculus. The special feature of the first edition - the integration of thermodynamics, heat transfer, and chemical processes - has been maintained and strengthened. Key Features: Presents a unified approach to thermodynamics and heat transport in fundamental physical and chemical processes First revised edition of a successful text/reference in fourteen years More than 25 percent new material Provides worked examples, questions, and problem sets for use as a teaching text or for self testing Includes many system dynamics models of laboratory experiments
Physics. --- Thermodynamics. --- Engineering Thermodynamics, Heat and Mass Transfer. --- Energy, general. --- Classical Continuum Physics. --- Physical Chemistry. --- Physical organic chemistry --- Engineering. --- Physique --- Chimie organique physique --- Thermodynamique --- Ingénierie --- Heat --- Transmission.
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The volumes of this classic series, now referred to simply as "Zechmeister" after its founder, L. Zechmeister, have appeared under the Springer Imprint ever since the series' inauguration in 1938. The volumes contain contributions on various topics related to the origin, distribution, chemistry, synthesis, biochemistry, function or use of various classes of naturally occurring substances ranging from small molecules to biopolymers. Each contribution is written by a recognized authority in his field and provides a comprehensive and up-to-date review of the topic in question. Addressed to biologists, technologists, and chemists alike, the series can be used by the expert as a source of information and literature citations and by the non-expert as a means of orientation in a rapidly developing discipline.
Chemistry. --- Organic Chemistry. --- Chemistry, Organic. --- Chimie --- Chimie organique --- Anticoagulants (Medicine). --- Coumarins. --- Biochemistry --- Chemistry --- Physical Sciences & Mathematics --- Organic compounds. --- Compounds, Organic --- Organic chemicals --- Organic chemistry --- Organic chemistry. --- Carbon compounds
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Since the first works introducing the aluminum intercalated clay family in the early 1970s, interest in the synthesis of pillared interlayered clays has increased tremendously, especially research into the properties and applications of new synthesis methods. The need for solids that could be used as cracking catalysts with larger pores than zeolitic materials has spurred the synthesis of new porous materials from clays. This book reviews the properties and applications of pillared clays and other layered materials used as catalysts, focusing on: - the acidity of pillared clays and the effect it has on catalytic performance - the use of pillared clays as supports for catalytically active phases, and the use of the resulting solids in environmentally friendly reactions - the comparison between the reactions of pillared clays and anionic clays.
Chemistry. --- Catalysis. --- Physical Chemistry. --- Inorganic Chemistry. --- Environmental Chemistry. --- Chemistry, inorganic. --- Physical organic chemistry --- Environmental chemistry. --- Chimie --- Chimie organique physique --- Catalyse --- Chimie de l'environnement --- Chemistry --- Chemistry, Inorganic --- Chemistry, Physical organic --- Catalysis --- Environmental chemistry
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Sucrose: A Prospering and Sustainable Organic Raw Material,By S. Peters, T. Rose, and M. Moser; Sucrose-Utilizing Transglucosidases for Biocatalysis, By I. André, G. Potocki-Véronèse, S. Morel, P. Monsan, and M. Remaud-Siméon; Difructose Dianhydrides DFAs) and DFA-Enriched Products as Functional Foods, By C. Ortiz Mellet and J. M. García Fernández; Development of Agriculture Left-Overs: Fine Organic Chemicals from Wheat Hemicellulose-Derived Pentoses, By F. Martel, B. Estrine, R. Plantier-Royon, N. Hoffmann, and C. Portella; Cellulose and Derivatives from Wood and Fibers as Renewable Sources of Raw-Materials, By J.A. Figueiredo, M.I. Ismael, C.M.S. Anjo, and A.P. Duarte; Olive Pomace, a Source for Valuable Arabinan-Rich Pectic Polysaccharides,By M. A. Coimbra, S. M. Cardoso, and J. A. Lopes-da-Silva; Oligomannuronates from Seaweeds as Renewable Sources for the Development of Green Surfactants,By T. Benvegnu and J.-F. Sassi; From Natural Polysaccharides to Materials for Catalysis, Adsorption, and Remediation, By F. Quignard, F. Di Renzo, and E. Guibal
Chemistry. --- Organic Chemistry. --- Chemistry, Organic. --- Chimie --- Chimie organique --- Glucides --- Développement durable --- Produits chimiques de la biomasse --- Carbohydrates --- Biomass chemicals --- Biotechnology --- Biotechnologie --- Glucides - Biotechnologie --- Carbohydrates - Congresses --- Biomass chemicals - Congresses --- Biotechnology - Congresses
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Gasphase synthesis of nanoparticles and nanostructured materials offers high chemical purity and crystalline quality as well as scalability up to industrial quantities. It is therefore highly attractive for both basic and applied science. This book gives a broad and coherent overview of the complete production and value chain from nanoparticle formation to integration into products and devices. Written by experts in the field - with backgrounds in electrical engineering, experimental and theoretical physics, materials science, and chemical engineering - the book offers a deep insight into the fabrication, characterization and application of nanoparticles from the gasphase. The first part of the book, Formation , covers chemical and growth kinetics, in-situ diagnostics, numerical simulation, process development and material deposition. In the second section, the reader is introduced to the structure and dynamics that lead to functional nanoscale systems and materials. The third section, Properties and Applications , provides a detailed discussion of the optical, electronic, magnetic and chemical characteristics of nanostructures and demonstrates how these can be used in tailored materials and devices.
Chemical structure --- nanotechniek --- atomen --- chemie --- Chemistry --- Biotechnology --- biotechnologie --- fysicochemie --- Electrical engineering --- Physicochemistry --- moleculen --- Physics. --- Physical organic chemistry --- Nanochemistry. --- Engineering. --- Nanotechnology. --- Physique --- Chimie organique physique --- Nanochimie --- Ingénierie --- Nanotechnologie --- EPUB-LIV-FT LIVCHIMI SPRINGER-B
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Biomolecules in nature exhibit overwhelming one-handedness, often called homochirality, such as L-amino acids and D-sugars. Since the discovery of molecular chirality by Pasteur, the origins of chirality and the process le- ing to enantiopure biomolecules have attracted broad attention from many researchers. Several theories have been proposed for the origin of chirality in organic compounds, for example, left and right-circularly polarized light, sp- taneous absolute asymmetric synthesis, and chiral inorganic crystals such as quartz. However, the enantioenrichments induced by these mechanisms have been very low or even below detection levels. Thus, the process of ampli?cation of enantioenrichment is inevitable to reach enantiopure compounds. In 1953, Frank proposed a mechanism of asymmetric autocatalysis without mentioning any chemical structure. However, it then took over 40 years for us to discover asymmetric autocatalysis with ampli?cation of chirality in 1995. This book illustrates the recent aspects of ampli?cation of chirality by as- metric autocatalysis and by forming helical structures. The ?rst four chapters summarize experimental asymmetric autocatalysis with ampli?cation of en- tiopurity, the mechanism of asymmetric autocatalysis examined by NMR and calculation, the computer simulation models of the reaction mechanism of asymmetric autocatalysis, and the theoretical models of ampli?cation of c- rality. The last chapter deals with the ampli?cation of chirality by the f- mation of helical structures. However, the ampli?cation of enantiopurity in non-autocatalytic asymmetric reaction and the ampli?cation by enantiomer separation involving crystallization or sublimation are beyond the scope of this book.
Chemistry. --- Organic Chemistry. --- Organometallic Chemistry. --- Physical Chemistry. --- Chemistry, Organic. --- Physical organic chemistry --- Chimie --- Chimie organique --- Chimie organique physique --- Circular Dichroism --- Stereoisomerism --- Isomerism --- Spectrum Analysis --- Chemistry Techniques, Analytical --- Organic Chemistry Phenomena --- Investigative Techniques --- Chemical Phenomena --- Phenomena and Processes --- Analytical, Diagnostic and Therapeutic Techniques and Equipment --- Biochemistry --- Physical & Theoretical Chemistry --- Chemistry --- Physical Sciences & Mathematics --- Autocatalysis. --- Chirality. --- Autocatalytic reaction --- Reaction, Autocatalytic --- Self-catalysis --- Organic chemistry. --- Organometallic chemistry. --- Physical chemistry. --- Stereochemistry --- Symmetry (Physics) --- Enantiomers --- Catalysis --- Chemistry, Physical organic. --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Organic chemistry --- Organometallic chemistry . --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry, Organometallic --- Metallo-organic chemistry --- Stereoisomerism.
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Molecular properties and reactions are controlled by electrons in the molecules. Electrons had been thought to be particles. Quantum mechanics showed that el- trons have properties not only as particles but also as waves. A chemical theory is required to think about the wave properties of electrons in molecules. These prop- ties are well represented by orbitals, which contain the amplitude and phase ch- acteristics of waves. This volume is a result of our attempt to establish a theory of chemistry in terms of orbitals — A Chemical Orbital Theory. The amplitude of orbitals represents a spatial extension of orbitals. An orbital strongly interacts with others at the position and in the direction of great extension. Orbital amplitude controls the reactivities and selectivities of chemical reactions. In the first paper on frontier orbital theory by Fukui the amplitude appeared in the form of its square, i.e., the density of frontier electrons in 1952 (Scheme 1). Orbital mixing rules were developed by Libit and Hoffmann and by Inagaki and Fukui in 1974 and Hirano and Imamura in 1975 to predict magnitudes of orbital amplitudes (Scheme 2) for understanding and designing stereoselective reactions.
Chemistry. --- Theoretical and Computational Chemistry. --- Atomic/Molecular Structure and Spectra. --- Organic Chemistry. --- Chemistry, Organic. --- Chimie --- Chimie organique --- Molecular orbitals --- Molecular orbitals. --- Molecular structure. --- Organic chemistry --- Chemistry --- Physical sciences --- Chemistry, Physical and theoretical. --- Atomic structure . --- Molecular structure . --- Organic chemistry. --- Structure, Molecular --- Chemical structure --- Structural bioinformatics --- Structure, Atomic --- Atomic theory --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry
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Zeolites are microporous, aluminosilicate minerals commonly used as commercial adsorbents. Zeolite-based catalysts are used by industrial chemical companies in the interconversion of hydrocarbons and the alkylation of aromatic compounds. The current book deals with the characterization of specific properties of Zeolites and calculations for the design of catalysts. Measurements and utilization of solid acidity, shape selectivity, and loading properties, that are three prominent properties of a Zeolite catalyst, are treated in detail. These features concern chemical vapor deposition of silica, shape selectivity, loading properties, solid activity, Brønsted or Lewis character, ammonia temperature programmed desorption, control of the pore-opening size by chemical vapor deposition of silica and XAFS analysis of metals being highly dispersed inside and outside a framework.
Chemistry. --- Physical Chemistry. --- Characterization and Evaluation of Materials. --- Condensed Matter Physics. --- Structural Materials. --- Physical organic chemistry --- Materials. --- Surfaces (Physics). --- Chimie --- Chimie organique physique --- Matériaux --- Surfaces (Physique) --- Catalysis. --- Zeolite catalysts. --- Zeolites. --- Acidität --- Heterogene Katalyse --- Palladium --- Porosität --- Regioselektivität --- Trägerkatalysator --- Zeolith --- Acidität. --- Heterogene Katalyse. --- Palladium. --- Porosität. --- Regioselektivität. --- Trägerkatalysator. --- Zeolith.
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