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The Jahn-Teller effect is one of the most fascinating phenomena in modern physics and chemistry, providing a general approach to understanding the properties of molecules and crystals and their origins. The effect inspired one of the most important recent scientific discoveries, the concept of high-temperature superconductivity. This comprehensive volume presents the background of the theory and its main applications in physics and chemistry, along with more recent achievements. Full descriptions are presented alongside thorough references to original material. The 2006 book contains over 200 figures to aid visual explanation and avoids bulky mathematical deductions and overly technical language. It is intended for graduate students and academic researchers working in solid state physics, quantum chemistry, crystallography, spectroscopy, and materials science.

Jahn-Teller effect.

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Electron configuration. --- Jahn-Teller effect. --- Molecular dynamics. --- Dipole moments --- Polarizability (electricity) --- Tautomerism

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541.49 --- Complex compounds. Complex chemistry --- Complex compounds. --- 541.49 Complex compounds. Complex chemistry --- Electron configuration. --- Jahn-Teller effect. --- Ketones. --- Organometallic compounds. --- Coordination compounds --- Copper compounds --- Stereochemistry

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This book provides a comprehensive discussion of the Jahn-Teller Effect (JTE), focusing on the boson-fermion interaction. While current research is concerned with measuring and calculating ever more sophisticated and complex manifestations of the JT effect, the present volume takes away the epicycles of the theory and focuses on the symmetry dilemma at its core. When fermions and bosons meet, they get entangled and form a new dynamic reality. According to the rules of Molecular Symmetry, this reality is limited to a small set of patterns, with degeneracy cardinalities: 2, 3, 4, 5, and 6. The novelty of the book is that it adopts a unique mathematical technique, known as the Bargmann-Fock representation, and treats all degeneracies in detail. So far, this method was only applied to the simplest doublet case therefore its extension to the entire range of cases offers a new unified perspective. This volume will help the reader acquire a clear understanding of the JT effect, discover its universal mechanism and it will be a great tool for researchers and graduates working on this topic.

Ordered algebraic structures --- Topological groups. Lie groups --- Quantum mechanics. Quantumfield theory --- Physicochemistry --- Chemical structure --- Qualitative chemical analysis --- Quantitative chemical analysis --- Molecular biology --- spectra (chemie) --- moleculaire structuur --- chemometrie --- quantumfysica --- wiskunde --- topologie --- fysicochemie --- atoomstructuur --- Interacting boson-fermion models. --- Jahn-Teller effect. --- Efecte Jahn-Teller --- Bosons --- Fermions

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The Jahn-Teller effect continues to be a paradigm for structural instabilities and dynamical processes in molecules and in the condensed phase. Among the many important newer developments in the field one should mention cooperative phenomena in crystals, the general importance of pseudo-Jahn-Teller couplings for symmetry-lowering phenomena in molecular systems, non-adiabatic processes at conical intersections of potential energy surfaces and extensions of the basic theory in relation to the discovery of fullerenes and other icosahedral systems. Written by leading international experts the aim of the present volume is to provide a survey of the state-of-the art in Jahn-Teller interactions at the interface of quantum chemistry and condensed matter physics, addressing both the non-expert scientist as well as those experts interested in expanding their knowledge into neighboring areas. Cast in form of a set of extensive and tutorial reviews – and thus suitable as a complement to available textbooks in the field – the following topics are dealt with in this book: - Jahn-Teller effect and vibronic interactions: General theory - Conical intersections and nonadiabatic dynamics in molecular processes - Impurities; Spectroscopy of transition metal complexes - Fullerenes and fullerides - Jahn-Teller effect and molecular magnetism - The cooperative Jahn-Teller effect and orbital ordering - Jahn-Teller effect and high-Tc Superconductivity.

Chemistry. --- Physical Chemistry. --- Solid State Physics. --- Spectroscopy and Microscopy. --- Theoretical and Computational Chemistry. --- Atomic/Molecular Structure and Spectra. --- Physical organic chemistry --- Chimie --- Chimie organique physique --- Jahn-Teller effect --- Jahn-Teller, Effet --- Jahn-Teller effect. --- Physics. --- Natural philosophy --- Philosophy, Natural --- Teller-Jahn effect --- Chemical structure --- Electronics and optics of solids --- Chemistry --- fysicochemie --- Molecular physics --- Physicochemistry --- Physics --- Physical chemistry. --- Chemistry, Physical and theoretical. --- Atomic structure. --- Molecular structure. --- Spectra. --- Solid state physics. --- Spectroscopy. --- Microscopy. --- Physical sciences --- Dynamics --- Coupled mode theory --- Crystal field theory --- Energy levels (Quantum mechanics) --- Chemistry, Physical organic. --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Jahn-Teller, Effet. --- Atomic structure  . --- Molecular structure . --- Structure, Molecular --- Structural bioinformatics --- Structure, Atomic --- Atomic theory --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Analysis, Microscopic --- Light microscopy --- Micrographic analysis --- Microscope and microscopy --- Microscopic analysis --- Optical microscopy --- Optics --- Analysis, Spectrum --- Spectra --- Spectrochemical analysis --- Spectrochemistry --- Spectrometry --- Spectroscopy --- Chemistry, Analytic --- Interferometry --- Radiation --- Wave-motion, Theory of --- Absorption spectra --- Light --- Spectroscope --- Solids --- Qualitative --- Analytical chemistry