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Benzamides --- Sulpiride --- pharmacology --- congresses.

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Benzamides --- Neoplasms --- Niacinamide --- Radiation-Sensitizing Agents --- therapeutic use --- radiography

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The Special Issue “Molecules from Side Reactions” is a collection of papers reporting on the synthesis and characterization of the molecules that come from unexpected synthetic routes. This is the first example of a Special Issue based on such a topic, notwithstanding that all synthetic chemists have isolated a side product during a chemical reaction. Instead of continuing to store the side products in the freezer, I have thought to give them the dignity of publication, making them available to the scientific community. The short manuscripts collected here respect the principle of “one compound per paper” and have the purpose of preserving the molecular diversity deriving from a chemical reaction. The molecular scaffolds are unexpected and intriguing, and could be useful starting points or intermediates for exploring novel reactions.

oxazole --- furan --- RORC reaction --- (E,Z)-isomerization --- nitration --- azaheterocycles --- N–C bond cleavage --- pyridine-imidazolium --- ribose --- psicose --- ketose --- rare sugar --- hydroxy methylation --- AICAR --- acadesine --- phosphorylation --- fluorination --- fluorinated nucleosides --- nucleoside analogues --- modified nucleosides --- chlorinated nucleosides --- AMPK --- organic synthesis --- bidentate directing groups --- benzamides --- chelation assistance --- bis-chelates --- C–H bond functionalization --- X-ray structure determination --- N′-acetylhydrazide --- 3-acetyl-2,3-dihydro-1,3,4-oxadiazole --- 1H-pyrazolo[3,4-b]pyridine --- heterocycle --- oxetane --- epoxide --- rearrangement --- carbohydrate --- C-glycosylation --- spiro-oxetane --- ester group migration --- glycosyl sulfoxide --- uronate --- thioglycoside oxidation --- mannose --- 8-Fluoro-2′-deoxyguanosine --- 19F NMR spectroscopy --- solid phase synthesis --- phosphoramidite --- muraymycins --- caprazamycins --- nucleosides --- uridine --- cyclization --- seven-membered rings --- conjugated diyne --- LAH reduction --- diacetal --- pent-1,2,3,4-tetraene intermediate --- ligand --- pyridine derivatives --- allenic compounds --- N-alkylation --- copper --- cyanide --- network --- guanidinium --- unexpected iminium cation --- n/a --- N-C bond cleavage --- C-H bond functionalization --- N'-acetylhydrazide --- 8-Fluoro-2'-deoxyguanosine

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A compilation of papers presenting original research results in the areas of organic, inorganic, organometallic, solid state and theoretical chemistry with a common theme of the use of X-ray diffraction to solve chemical problems.

Research & information: general --- Chemistry --- Organic chemistry --- molecular magnetism --- supramolecular chemistry --- heterometallic clusters --- magnetometry --- EPR spectroscopy --- N-Substituted Benzamides --- Woollins’ reagent --- selenation reagent --- reduction reagent --- single crystal X-ray structures --- DFT --- 3d metal complex --- benchmark --- hydricity --- 2D Cu-MOF --- square grid structure --- Click reaction --- Knoevenagel reaction --- green chemistry --- titanium(IV) oxo-clusters --- band gap modification --- multinuclear NMR --- ESI-MS studies --- photoluminescence --- perophoramidine --- natural product --- Claisen rearrangement --- indoloquinoline --- intramolecular cyclization --- X-ray structure --- isothiourea --- ammonium enolate --- aryloxide --- quinone methide --- ester functionalization --- 1,6-conjugate addition --- layered perovskite --- bandgap tuning --- azetidinium --- Ruddlesden–Popper --- structure-property relations --- amide groups --- isomers --- late-transition metals --- P-ligands --- phenols --- secondary interactions --- single crystal X-ray crystallography --- MOF --- calcium MOF --- electrochemistry --- scXRD --- VTXRD --- bioMOF --- bond activation --- low oxidation state complexes --- magnesium --- metallacycles --- ring system --- X-ray crystallography --- peri-substitution --- arsenic --- organophosphorus --- pnictine --- PDS --- PELDOR --- DEER --- nitroxide spin label --- Comparative DEER Analyzer --- mtsslSuite --- MMM --- oxazoline --- Wittig rearrangement --- thiophene --- thieno[2,3-c]pyrrolone

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A collection of essential research articles and scientific reviews covering some of the most pertinent and topical areas of study that currently constitute Inorganic Chemistry in the early 21st century.

Research & information: general --- Chemistry --- Inorganic chemistry --- cyanoguanidine --- silver --- crystal structure --- chemical bonding --- CuII --- pyridine amides --- pyrazine amide --- amino benzamides --- EPR spectroscopy --- lanthanides --- Schiff base --- synthetic strategies --- single-molecule magnets --- Atomic Layer Deposition --- Ni catalyst --- reforming catalyst --- thermodynamics --- metallopharmaceuticals --- cancer stem cells --- copper --- bioinorganic chemistry --- medicinal inorganic chemistry --- reactive oxygen species --- metal-carbonyl complexes --- [FeFe]-hydrogenases --- density functional theory --- time-dependent DFT --- organometallic photochemistry --- crystalline borosilicate --- actinides --- supercritical hydrothermal synthesis --- waste forms --- thorium --- rhenium --- ruthenium --- metal–metal bonds --- uranium --- ceria --- hydrothermal --- catalysis --- nanomaterials --- crystallisation --- 4,2′:6′,4″-terpyridine --- 3,2′:6′,3″-terpyridine --- coordination polymer --- isomers --- lithium --- potassium --- Nacnac --- β-diketiminate --- tricyclohexylphenyl --- steric bulk --- silver complexes --- permanganates --- perchlorates --- perrhenate --- pyridine --- structure --- spectroscopy --- thermal behavior --- heterogenous catalyst --- metal–organic framework (MOF) --- olefin epoxidation --- carbon dioxide cycloaddition --- f-element --- lanthanide --- actinide --- multidentate ligand --- macrocycle --- ammonothermal synthesis --- fluoride --- aluminum --- speciation --- equilibria --- thermodynamic stability --- peptides --- multivariate linear regression --- poisoning effect of polar monomers --- Brookhart-type catalysts --- Zintl clusters --- X-ray crystallography --- Density Functional Theory --- n/a --- metal-metal bonds --- 4,2':6',4"-terpyridine --- 3,2':6',3"-terpyridine --- metal-organic framework (MOF)