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Book
New Trends in Lyotropic Liquid Crystals
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Year: 2020 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

Liquid crystals (LCs) were discovered more than a century ago, and were, for a long time, treated as a physical curiosity, until the development of flat panel screens and display devices caused a revolution in the information display industry, and in fact in society. There would be no mobile phones without liquid crystals, no flat screen TVs or computer monitors, no virtual reality, just to name a few of the applications that have changed our whole world of vision and perception. All of these inventions are based on liquid crystals that are formed through a change in temperature, thermotropic LCs. However, there is another form of liquid crystals, described even earlier, yet much less talked about; the lyotropic liquid crystals that occur through the change of concentration of some molecules in a solvent. These are found in abundance in nature, making up the cell membranes, and are used extensively in the food, detergents and cosmetics industries. In this collection of articles by experts in their respective research areas, we bring together some of the most recent and innovative aspects of lyotropic liquid crystals, which we believe will drive future research and set novel trends in this field.


Book
Advancements in Gel Science-A Special Issue in Memory of Toyoichi Tanaka
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ISBN: 303921344X 3039213431 9783039213443 Year: 2019 Publisher: Basel, Switzerland : MDPI,

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A gel is a state of matter that consists of a three-dimensional cross-linked polymer network and a large amount of solvent. Because of their structural characteristics, gels play important roles in science and technology. The science of gels has attracted much attention since the discovery of the volume phase transition by Professor Toyoichi Tanala at MIT in 1978. MDPI planned to publish a Special Issue in Gels to celebrate the 40th anniversary of this discovery, which received submissions of 13 original papers and one review from various areas of science. We believe that readers will find this Special Issue informative as to the recent advancements of gel research and the broad background of gel science.

Keywords

delamination --- n/a --- fractal analysis --- buckling --- artificial hydrogel cartilage --- frictional property --- kinetic coefficient --- paint coating --- scaling analysis --- moving boundary picture --- XRD --- volume phase transition --- fracture --- fatigue --- crack --- gelation temperature --- xerogel --- swelling of thermosensitive gels --- copolymerization --- phase transition dynamics --- wetting --- poly (acryl amide) gel --- swelling --- sucrose --- anisotropic shape --- ice crystallization during rewarming --- micropipette aspiration --- microgel --- crosslink density (density of crosslinks) --- hydrogel --- Sephadex® (crosslinked dextran) --- sol-gel transition --- thermoresponsive property --- compression --- Brunauer-Emmett-Teller theory --- monomer sequence --- microcrystallite --- swelling behavior --- micrometric confinement --- wear --- light scattering --- X-ray CT --- co-crosslinking --- electrophoresis --- gel --- hysteresis --- ice grain --- effects of electric charge --- phase separation --- acrylamide derivative --- Barrett-Joyner-Halenda analysis --- temperature --- xylitol --- agarose gel --- spinodal temperature --- glassy water --- chemical gel --- blood coagulation --- poly(vinyl alcohol) --- pulse field gradient spin echo method of nuclear magnetic resonance (PFG-NMR) --- time domain reflectometry (TDR) of dielectric spectroscopy --- site-bond correlated-percolation model for polymer gelation --- spinodal decomposition --- adhesion --- janus particle --- wrinkle --- friction --- cloud point temperature --- drying --- gamma ray sterilization --- solvent exchange --- solids content --- solvent transport --- heterogeneous gelation dynamics --- PVA gel --- hydrogen bond


Book
Advances in Food and By-Products Processing Towards a Sustainable Bioeconomy
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ISBN: 3039217534 3039217526 Year: 2019 Publisher: MDPI - Multidisciplinary Digital Publishing Institute

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The bioeconomy initially focused on resource substitution, including the production of biomass from various resources; its conversion, fractionation, and processing by means of biotechnology; and chemistry and process engineering towards the production and marketing of food, feed, fuel, and fibre. Nevertheless, although resource substitution is still considered important, the emphasis has been recently shifted to the biotechnological innovation perspective of the bioeconomy, in terms that ensure environmental sustainability. It is estimated that around one-third of the food produced for human consumption is wasted throughout the world, posing not only a sustainability problem related to food security but also a significant environmental problem. Food waste streams, mainly derived from fruits and vegetables, cereals, oilseeds, meat, dairy, and fish processing, have unavoidably attracted the interest of the scientific community as an abundant reservoir of complex carbohydrates, proteins, lipids, and functional compounds, which can be utilized as raw materials for added-value product formulations. This Special Issue focuses on innovative and emerging food and by-products processing methods for the sustainable transition to a bioeconomy era.


Book
Frontier Research on the Processing Quality of Cereal and Oil Food
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Year: 2022 Publisher: Basel MDPI Books

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As everyone knows, cereal and oil are still the main part of our diet and provide essential nutrients and energy every day. With the progress of food processing technology, the quality of cereal and oil food is also improved significantly. Behind this, major nutrients of grain and oil, including protein, carbohydrate, lipid, and functional components, have experienced a variety of physical, chemical, and biological reactions during food processing. Moreover, research in this field also covers the multi-scale structural changes of characteristic components, such as component interaction and formation of key domains, which is essential for the quality enhancement of cereal and oil food. Based on the increasing consumer demand for nourishing, healthy, and delicious cereal and oil food, it might be interesting to report the latest research on the application of novel technology in food processing, multi-scale structural changes of characteristic components in food processing, structure-activity mechanism of food functional components. This book aimed to provide useful reference and guidance for the processing and utilization of cereal and oil food so as to provide technical support for the healthy development of cereal a oil food processing industry worldwide.


Book
Biopolymers in Drug Delivery and Regenerative Medicine
Authors: --- ---
Year: 2021 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Biopolymers including natural (e.g., polysaccharides, proteins, gums, natural rubbers, bacterial polymers), synthetic (e.g., aliphatic polyesters and polyphosphoester), and biocomposites are of paramount interest in regenerative medicine, due to their availability, processability, and low toxicity. Moreover, the structuration of biopolymer-based materials at the nano- and microscale along with their chemical properties are crucial in the engineering of advanced carriers for drug products. Finally, combination products including or based on biopolymers for controlled drug release offer a powerful solution to improve the tissue integration and biological response of these materials. Understanding the drug delivery mechanisms, efficiency, and toxicity of such systems may be useful for regenerative medicine and pharmaceutical technology. The main aim of the Special Issue on “Biopolymers in Drug Delivery and Regenerative Medicine” is to gather recent findings and current advances on biopolymer research for biomedical applications, particularly in regenerative medicine, wound healing, and drug delivery. Contributions to this issue can be as original research or review articles and may cover all aspects of biopolymer research, ranging from the chemical synthesis and characterization of modified biopolymers, their processing in different morphologies and hierarchical structures, as well as their assessment for biomedical uses.


Book
Experimental and Numerical Studies in Biomedical Engineering
Authors: ---
ISBN: 3039212486 3039212478 9783039212484 Year: 2019 Publisher: Basel, Switzerland : MDPI,

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The term 'biomedical engineering' refers to the application of the principles and problem-solving techniques of engineering to biology and medicine. Biomedical engineering is an interdisciplinary branch, as many of the problems health professionals are confronted with have traditionally been of interest to engineers because they involve processes that are fundamental to engineering practice. Biomedical engineers employ common engineering methods to comprehend, modify, or control biological systems, and to design and manufacture devices that can assist in the diagnosis and therapy of human diseases. This Special Issue of Fluids aims to be a forum for scientists and engineers from academia and industry to present and discuss recent developments in the field of biomedical engineering. It contains papers that tackle, both numerically (Computational Fluid Dynamics studies) and experimentally, biomedical engineering problems, with a diverse range of studies focusing on the fundamental understanding of fluid flows in biological systems, modelling studies on complex rheological phenomena and molecular dynamics, design and improvement of lab-on-a-chip devices, modelling of processes inside the human body as well as drug delivery applications. Contributions have focused on problems associated with subjects that include hemodynamical flows, arterial wall shear stress, targeted drug delivery, FSI/CFD and Multiphysics simulations, molecular dynamics modelling and physiology-based biokinetic models.


Book
Polymer Clay Nano-composites
Author:
ISBN: 3039216538 303921652X 9783039216536 Year: 2019 Publisher: Basel, Switzerland : MDPI,

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This Special Issue focuses on the current state-of-the-art of "Polymer Clay Nano-Composites" for biomedical, anticorrosion, antibacterial, and other applications. Clay-polymer composite nanomaterials represent an emerging area of research. Loading polymers with clay particles essentially enhances the composite strength features. Of particular interest are different nano-assembly methods, such as silane mono and multilayers, polyelectrolyte layer-by-layer assembly, and others. An important development was reached for tubular and fibrous clay nanoparticles, such as halloysite, sepiolite, and imogolite. Polymer clay nanoparticles can be prepared as sheets with 1-nm thickness and width of a few hundred nm (e.g., kaolin and montmorillonite). Fibrous clays significantly reinforce the nano-composites in the assembly with biopolymers and other green polymers, leading to functional hybrid bio nano-composites. The scope of this Special Issue comprehensively includes the synthesis and characterization of polymer clay nano-composites used for several applications, including nano-clay polymer composites and hybrid nano-assemblies.

Keywords

graphene oxide --- n/a --- polysaccharide --- water resistance --- nanocomposites --- layered silicate --- polyimide --- intercalation --- barrier --- composite --- indentation recovery --- ionic network --- organically modified clays --- nanotechnology --- 2-polybutadiene --- doxorubicin --- sericite --- adsorption --- morphology --- phenyltrimethylammonium chloride --- supercritical CO2 --- blowing agent --- halloysite nanotubes --- mechanical properties --- glycerol --- ammonium persulfate --- TGA --- 1 --- interfacial interactions --- carbon fibers --- nanocomposite materials --- silica sol --- N?-methylenebisacrylamide --- intercalation stability --- polymer composites --- clay–polymer nanocomposites --- in-situ intercalation --- attapulgite/polypyrrole nanocomposite --- fish gelatin --- polyacrylic acid --- fuzzy optimization --- AFM --- variable cost --- organic montmorillonite --- positron annihilation --- whey protein isolate --- interface --- CTAB --- N --- hyaluronic acid --- swelling capacity --- water shutoff --- montmorillonite --- sol–gel transition --- in situ polymerization --- hexadecyltrimethylammonium bromide --- clay-amine interaction mechanisms --- gelation kinetics --- FTIR --- surface grafting --- Pareto set --- la uptake and release --- polyamines --- polystyrene foam --- CD44 receptor targeted --- tribological property --- polyethylene oxide --- structure effects --- catalytic composite --- polystyrene --- nanoclay --- thermal stability --- sacrificial bond --- Pd catalysis --- radical polymerization --- dental resins --- reinforcing --- montmorillonite clays --- coatings --- atrazine --- cellulose nanofibrils --- soap-free emulsion polymerization --- LAP --- doubly functionalized montmorillonite --- dispersion --- organo-clays --- clay-polymer nanocomposites --- sol-gel transition


Book
Environmentally Friendly Polymers and Polymer Composites
Authors: --- --- --- ---
Year: 2021 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Continuous research advances have been observed in the field of environmentally-friendly polymers and polymer composites due to the dependence of polymers on fossil fuels and the sustainability issues related to plastic wastes. This book compiles the most recent research works in biopolymers, their blends and composites, and the use of natural additives, such as vegetable oils and other renewable and waste-derived liquids, with their marked environmental efficiency devoted to developing novel sustainable materials. Therefore, Environmentally Friendly Polymers and Polymer Composites provides an overview to scientists of the potential of these environmentally friendly materials and helps engineers to apply these new materials for industrial purposes.

Keywords

PLA --- PCL --- TPS --- biopolymer blends --- mechanical properties --- compostable plastics --- green composites --- natural fillers --- poly(butylene succinate) (PBS) --- almond shell flour (ASF) --- poly (lactic acid) (PLA) --- poly(butylene succinate-co-adipate) (PBSA) --- binary blends --- shape memory behaviour --- polymer‒matrix composites (PMCs) --- thermomechanical --- electron microscopy --- compatibilizers --- poly(lactic acid) (PLA) --- natural fibre (NF) --- nano-hydroxyapatite (nHA) --- flammability --- crab shell --- chitin --- spherical microgels --- reverse micelle --- gelation --- chitosan (CS) --- anti-oxidant --- anti-apoptotic activity --- rotenone --- Parkinson’s disease (PD) --- composite materials --- hybrid resin --- natural reinforcement --- non-uniformities --- mechanical behavior --- antifungal activity --- dendrimer --- Origanum majorana L. essential oil --- Phytophthora infestans --- maleinized linseed oil MLO --- poly(lactic acid) --- diatomaceous earth --- biocomposites --- active containers --- polymer mixtures --- blends --- cashew nut shell liquid (CNSL) --- polypropylene --- high impact polystyrene --- compatibilization --- PHB --- PHBV --- rice husk --- biosustainability --- waste valorization --- bacterial cellulose --- natural rubber --- reinforcing --- biodegradable polymers --- Arboform --- epoxidized oil --- maleinized linseed oil --- toughness --- thermal stability --- pectin --- food packaging --- active compounds --- agro-waste residues --- circular economy --- graphene oxide --- size selection --- sodium alginate --- bio-based polymers --- biodegradable polyesters --- wood plastic composites --- natural additives and fillers --- composites characterization --- bioplastics manufacturing


Book
Natural Additives in Food
Authors: ---
Year: 2022 Publisher: Basel MDPI - Multidisciplinary Digital Publishing Institute

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In the search for a healthier diet and facing the uncertainties about the consumption of artificial additives, the scientific community has explored in the last years the potential of natural compounds, such as polyphenols, carotenoids, chlorophylls, essential oils, tocopherols, vitamins, polysaccharides, among others, obtained from the most diverse sources, such as plants and fungi, for the replacement of the artificial additives in food, which has made these compounds recognized as “natural additives”. In addition to being considered less harmful to health, and giving a certain functional property to a foodstuff, natural additives can also provide a beneficial synergistic effect in the food matrix. For the consumers, diverse studies have been showed that regular ingestion of bioactive compounds, that can be applied as natural additives, can be helpful for the prevention/treatment of several chronic and aging illnesses, such as cardiovascular diseases and neurological disorders. However, there is much to be researched on the viable use of bioactive compounds and to overcome their chemical limitations so that it can actually be used as natural additives in foods. This book addresses, through 18 scientific articles, some natural compounds with potential for use as preservatives, nutritional additives, coloring agents, flavorings, and various agents.

Keywords

trisodium citrate --- microbial transglutaminase --- casein gels --- textural properties --- microstructures --- Urtica spp. --- bioactive compounds --- antioxidant activity --- antimicrobial activity --- traditional medicine --- food industry --- animal breeding --- beta cyclodextrin --- ewe’s milk --- cheese --- Manchego --- lipids --- cholesterol --- anthocyanin --- natural extract --- tetraethyl orthosilicate --- black carrot --- black rice flour --- anthocyanins --- low gluten muffins --- added value products --- soymilk --- enzyme modified soymilk --- skim milk --- rennet induced gelation --- rheological properties --- egg yolk --- cholesterol extraction --- granules extraction --- anionic chelating biopolymers --- ADME --- absorption --- chlorophylls --- chlorophyllin --- green colorant --- zinc-chlorophylls --- copper-chlorophyll --- coloring foodstuff --- natural colorants --- food colors --- pomelo peel --- essential oil --- anti-oxidant --- anti-melanogenic --- B16 melanoma cell --- oxygen-containing sulfur flavor molecules --- β-carotene --- bis(2-methyl-3-furyl) disulfide (BMFDS) --- oxidation products --- beetroot --- betalains --- semi-preparative RP-HPLC --- in vitro human gastrointestinal digestion --- ex vivo colon fermentation --- antioxidant ability --- malonildialdehyde --- extra virgin olive oil --- leaf addition --- Tunisian varieties --- phenolics --- tocopherols --- Prunus spinosa L. fruit epicarp --- wild fruit valorization --- cyanidin 3-rutinoside --- peonidin 3-rutinoside --- heat and ultrasound assisted extraction --- response surface methodology --- Ocimum basilicum var. purpurascens leaves --- red rubin basil --- Heat-Assisted Extraction --- extraction optimization --- polyphenols --- tiger nut --- by-products --- solvent extraction --- horchata de chufa --- triple TOF-LC-MS-MS --- Caenorhabditis elegans --- antioxidants --- bergenin --- stress resistance --- lifespan --- Huntington --- uxi --- Endopleura uchi --- Allium cepa red cv. --- Citrus limon --- pickling --- volatiles --- SPME --- chemometrics --- byproducts --- food additives --- antimicrobial --- antioxidant --- colorants --- texturizing agents --- foaming capacity and emulsifiers


Book
Climate Change, Carbon Capture, Storage and CO2 Mineralisation Technologies
Authors: --- ---
Year: 2020 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

This Special Issue delivered 16 scientific papers, with the aim of exploring the application of carbon capture and storage technologies for mitigating the effects of climate change. Special emphasis has been placed on mineral carbonation techniques that combine innovative applications to emerging problems and needs. The aim of this Special Issue is to contribute to improved knowledge of the ongoing research regarding climate change and CCS technological applications, focusing on carbon capture and storage practices. Climate change is a global issue that is interrelated with the energy and petroleum industry.

Keywords

CO2 storage --- depleted gas field --- soil-gas monitoring --- baseline --- injection --- post-injection --- photocatalytic concrete pavement --- NO reduction --- SEM analysis --- carbon emissions --- emission coefficient --- agricultural land --- agricultural inputs --- agricultural policies --- Qinghai province --- carbon nanospheres --- nanocarbon spheres --- carbon dioxide uptake --- EDA --- CO2 sequestration --- physical simulation --- Numerical modelling --- dissolution --- precipitation --- kinetics --- solid–gas reactions --- carbonate looping --- calcium looping --- thermochemical energy storage --- carbon capture and storage --- CO2 capture --- Monte Carlo --- machine learning --- metal–organic framework --- adsorption --- diffusion --- climate change --- carbon emission --- carbon-capturing concrete --- carbon capture activator --- carbon reduction --- CO2 ocean geological storage --- multi-scale ocean model --- hydrostatic approximation --- Eulerian–Lagrangian two-phase model --- environmental impact --- calcium carbonate --- molecular dynamics --- carbon utilization --- gelation --- slag valorization --- metallurgical dusts --- slag cement --- CO2 emissions --- EAF slag --- zero waste --- utilization and storage --- mafic plutonic rocks --- mineral carbonation --- screening and ranking --- Sines massif --- Portugal --- CO2 adsorption --- nanopore --- coal structure deformation --- tectonically deformed coal --- supercritical CO2 --- experimental test --- CO2 capture process --- solvent-based absorption/desorption --- off-design operation --- phase-change solvents --- sensitivity analysis --- CCS --- carbonated water injection --- CO2-EOR --- pore network modelling --- relative permeability --- n/a --- solid-gas reactions --- metal-organic framework --- Eulerian-Lagrangian two-phase model

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